Carbon Dioxide Capture Chemistry of Amino Acid Functionalized Metal-Organic Frameworks in Humid Flue Gas

Lyu, Hao; Chen, Oscar Iu-Fan; Hanikel, Nikita; Hossain, Mohammad I; Flaig, Robinson W.; Pei, Xiaokun; Amin, Ameer; Doherty, Mark D; Impastato, Rebekah K; Glover, T. Grant; Moore, David R; Yaghi, Omar M

doi:10.1021/jacs.1c13368

Title: Carbon Dioxide Capture Chemistry of Amino Acid Functionalized Metal-Organic Frameworks in Humid Flue Gas

Journal Article · 25 January 2022 · Journal of the American Chemical Society

DOI: https://doi.org/10.1021/jacs.1c13368 · OSTI ID:1841534

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^[2]; Amin, Ameer ^[2];

^[4]; Impastato, Rebekah K ^[3];

^[3]; Moore, David R ^[4];

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Univ. of California, Berkeley, CA (United States); General Electric Company, GE Research Center
Univ. of California, Berkeley, CA (United States)
Univ. of South Alabama, Mobile, AL (United States)
General Electric Research Lab., Schenectady, NY (United States)

Here, metal-organic framework-808 has been functionalized with 11 amino acids (AA) to produce a series of MOF-808-AA structures. The adsorption of CO₂ under flue gas conditions revealed that glycine- and DL-lysine-functionalized MOF-808 (MOF-808-Gly and -DL-Lys) have the highest uptake capacities. Enhanced CO₂ capture performance in the presence of water was observed and studied using single-component sorption isotherms, CO₂/H₂O binary isotherm, and dynamic breakthrough measurements. The key to the favorable performance was uncovered by deciphering the mechanism of CO₂ capture in the pores and attributed to the formation of bicarbonate as evidenced by ¹³C and ¹⁵N solid-state nuclear magnetic resonance spectroscopy studies. Based on these results, we examined the performance of MOF-808-Gly in simulated coal flue gas conditions and found that it is possible to capture and release CO₂ by vacuum swing adsorption. MOF-808-Gly was cycled at least 80 times with full retention of performance. This study significantly advances our understanding of CO₂ chemistry in MOFs by revealing how strongly bound amine moieties to the MOF backbone create the chemistry and environment within the pores, leading to the binding and release of CO₂ under mild conditions without application of heat.

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Research Organization:: Univ. of California, Berkeley, CA (United States); General Electric Co., Boston, MA (United States)

Sponsoring Organization:: USDOE Office of Fossil Energy (FE); USDOE Office of Science (SC); National Aeronautics and Space Administration (NASA); National Institutes of Health (NIH)

Grant/Contract Number:: FE0031956; AC02-05CH11231

OSTI ID:: 1841534

Journal Information:: Journal of the American Chemical Society, Journal Name: Journal of the American Chemical Society Journal Issue: 5 Vol. 144; ISSN 0002-7863

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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