Water-gas shift reaction over supported Au nanoparticles

Shekhar, Mayank; Lee, Wen-Sheng; Akatay, M. Cem; Maciel, Leonardo; Tang, Wenjie; Miller, Jeffrey T.; Stach, Eric A.; Neurock, Matthew; Delgass, W. Nicholas; Ribeiro, Fabio H.

doi:10.1016/j.jcat.2021.12.021

Title: Water-gas shift reaction over supported Au nanoparticles

Journal Article · 31 December 2021 · Journal of Catalysis

DOI: https://doi.org/10.1016/j.jcat.2021.12.021 · OSTI ID:1841290

Shekhar, Mayank; Lee, Wen-Sheng; Akatay, M. Cem; Maciel, Leonardo; Tang, Wenjie; Miller, Jeffrey T.; Stach, Eric A.; Neurock, Matthew; Delgass, W. Nicholas; Ribeiro, Fabio H.

Not Available

View Accepted Manuscript (Publisher)

Cite

Export

Save

Sponsoring Organization:: USDOE

OSTI ID:: 1841290

Journal Information:: Journal of Catalysis, Journal Name: Journal of Catalysis Journal Issue: C Vol. 405; ISSN 0021-9517

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

References (76)

Vital Role of Moisture in the Catalytic Activity of Supported Gold Nanoparticles Daté, Masakazu; Okumura, Mitsutaka; Tsubota, Susumu Angewandte Chemie International Edition, Vol. 43, Issue 16 https://doi.org/10.1002/anie.200453796	journal	April 2004
Water Gas Shift Reaction on Cu and Au Nanoparticles Supported on CeO2(111) and ZnO(000): Intrinsic Activity and Importance of Support Interactions Rodriguez, José A.; Liu, Ping; Hrbek, Jan Angewandte Chemie International Edition, Vol. 46, Issue 8 https://doi.org/10.1002/anie.200603931	journal	February 2007
Hydrogen Dissociation by Gold Clusters Fujitani, Tadahiro; Nakamura, Isao; Akita, Tomoki Angewandte Chemie International Edition, Vol. 48, Issue 50 https://doi.org/10.1002/anie.200905380	journal	November 2009
Low-Temperature Catalytic H2 Oxidation over Au Nanoparticle/TiO2 Dual Perimeter Sites Green, Isabel Xiaoye; Tang, Wenjie; Neurock, Matthew Angewandte Chemie International Edition, Vol. 50, Issue 43 https://doi.org/10.1002/anie.201101612	journal	May 2011
Electrostatic Origins of Linear Scaling Relationships at Bifunctional Metal/Oxide Interfaces: A Case Study of Au Nanoparticles on Doped MgO Substrates Choksi, Tej; Majumdar, Paulami; Greeley, Jeffrey P. Angewandte Chemie International Edition, Vol. 57, Issue 47 https://doi.org/10.1002/anie.201808246	journal	October 2018
FTIR Study of the Low-Temperature Water–Gas Shift Reaction on Au/Fe2O3 and Au/TiO2 Catalysts Boccuzzi, F.; Chiorino, A.; Manzoli, M. Journal of Catalysis, Vol. 188, Issue 1 https://doi.org/10.1006/jcat.1999.2636	journal	November 1999
CO Oxidation over Supported Gold Catalysts—“Inert” and “Active” Support Materials and Their Role for the Oxygen Supply during Reaction Schubert, Markus M.; Hackenberg, Stefan; van Veen, Andre C. Journal of Catalysis, Vol. 197, Issue 1 https://doi.org/10.1006/jcat.2000.3069	journal	January 2001
Low temperature water gas shift over gold catalysts Andreeva, Donka Gold Bulletin, Vol. 35, Issue 3 https://doi.org/10.1007/BF03214843	journal	September 2002
Properties of TiO2 support and the performance of Au/TiO2 Catalyst for CO oxidation reaction Ho, K. Y.; Yeung, K. L. Gold Bulletin, Vol. 40, Issue 1 https://doi.org/10.1007/BF03215288	journal	March 2007
Water-gas shift: steady state isotope switching study of the water-gas shift reaction over Pt/ceria using in-situ DRIFTS Jacobs, Gary; Crawford, Adam C.; Davis, Burtron H. Catalysis Letters, Vol. 100, Issue 3-4 https://doi.org/10.1007/s10562-004-3447-4	journal	April 2005
Comparison of gold supported catalysts obtained by using different allotropic forms of titanium dioxide Comotti, Massimiliano; Weidenthaler, Claudia; Li, Wen-Cui Topics in Catalysis, Vol. 44, Issue 1-2 https://doi.org/10.1007/s11244-007-0300-1	journal	June 2007
Insights into the reactivity of supported Au nanoparticles: combining theory and experiments Janssens, Ton V. W.; Clausen, Bjerne S.; Hvolbæk, Britt Topics in Catalysis, Vol. 44, Issue 1-2 https://doi.org/10.1007/s11244-007-0335-3	journal	June 2007
Catalysis at Metal/Oxide Interfaces: Density Functional Theory and Microkinetic Modeling of Water Gas Shift at Pt/MgO Boundaries Ghanekar, Pushkar; Kubal, Joseph; Cui, Yanran Topics in Catalysis, Vol. 63, Issue 7-8 https://doi.org/10.1007/s11244-020-01257-4	journal	April 2020
Regulation of reaction intermediate by reactant in the water-gas shift reaction on CeO2, in relation to reactant-promoted mechanism Shido, T.; Iwasawa, Y. Journal of Catalysis, Vol. 136, Issue 2 https://doi.org/10.1016/0021-9517(92)90079-W	journal	August 1992
Photocatalytic decomposition of water at semiconductor electrodes Maruska, H. Paul; Ghosh, Amal K. Solar Energy, Vol. 20, Issue 6 https://doi.org/10.1016/0038-092X(78)90061-0	journal	January 1978
Acid-base bifunctional catalysis by ZrO2 and its mixed oxides Tanabe, K.; Yamaguchi, T. Catalysis Today, Vol. 20, Issue 2 https://doi.org/10.1016/0920-5861(94)80002-2	journal	June 1994
First-principles study of the adsorption of atomic H on Ni (111), (100) and (110) Kresse, G.; Hafner, J. Surface Science, Vol. 459, Issue 3 https://doi.org/10.1016/S0039-6028(00)00457-X	journal	July 2000
Comparison of optical and electrochemical properties of anatase and brookite TiO2 synthesized by the sol–gel method Koelsch, M.; Cassaignon, S.; Guillemoles, J. F. Thin Solid Films, Vol. 403-404 https://doi.org/10.1016/S0040-6090(01)01509-7	journal	February 2002
The interaction of water with solid surfaces: fundamental aspects revisited Henderson, M. Surface Science Reports, Vol. 46, Issue 1-8 https://doi.org/10.1016/S0167-5729(01)00020-6	journal	May 2002
Nature of the active site for CO oxidation on highly active Au/γ-Al2O3 Costello, C. K.; Kung, M. C.; Oh, H. -S. Applied Catalysis A: General, Vol. 232, Issue 1-2 https://doi.org/10.1016/S0926-860X(02)00092-3	journal	June 2002
Characterization of a Pt/TiO (rutile) catalyst for water gas shift reaction at low-temperature Iida, H.; Igarashi, A. Applied Catalysis A: General, Vol. 298 https://doi.org/10.1016/j.apcata.2005.09.032	journal	January 2006
Activity and stability of low-content gold–cerium oxide catalysts for the water–gas shift reaction Fu, Qi; Deng, Weiling; Saltsburg, Howard Applied Catalysis B: Environmental, Vol. 56, Issue 1-2, p. 57-68 https://doi.org/10.1016/j.apcatb.2004.07.015	journal	March 2005
Influence of the crystalline phase and surface area of the TiO2 support on the CO oxidation activity of mesoporous Au/TiO2 catalysts Denkwitz, Y.; Makosch, M.; Geserick, J. Applied Catalysis B: Environmental, Vol. 91, Issue 1-2 https://doi.org/10.1016/j.apcatb.2009.06.016	journal	September 2009
Effect of the nature of the support on the catalytic performance of noble metal catalysts for the water–gas shift reaction Panagiotopoulou, Paraskevi; Kondarides, Dimitris I. Catalysis Today, Vol. 112, Issue 1-4 https://doi.org/10.1016/j.cattod.2005.11.026	journal	March 2006
Kinetics of the water–gas shift reaction on Pt catalysts supported on alumina and ceria Phatak, A. A.; Koryabkina, N.; Rai, S. Catalysis Today, Vol. 123, Issue 1-4, p. 224-234 https://doi.org/10.1016/j.cattod.2007.02.031	journal	May 2007
Gold-based catalysts for the water–gas shift reaction: Active sites and reaction mechanism☆ Rodriguez, José A. Catalysis Today, Vol. 160, Issue 1 https://doi.org/10.1016/j.cattod.2010.06.030	journal	February 2011
Specific role of polymorphs of supporting titania in catalytic CO oxidation on gold Beck, A.; Magesh, G.; Kuppan, B. Catalysis Today, Vol. 164, Issue 1 https://doi.org/10.1016/j.cattod.2010.12.006	journal	April 2011
Relation between nanoscale Au particle structure and activity for CO oxidation on supported gold catalysts Janssens, Ton V. W.; Carlsson, Anna; Puig-Molina, Anna Journal of Catalysis, Vol. 240, Issue 2 https://doi.org/10.1016/j.jcat.2006.03.008	journal	June 2006
Evaluation of the Au size effect: CO oxidation catalyzed by Au/TiO2 Overbury, S.; Schwartz, V.; Mullins, D. Journal of Catalysis, Vol. 241, Issue 1 https://doi.org/10.1016/j.jcat.2006.04.018	journal	July 2006
Effect of Zn addition on the water–gas shift reaction over supported palladium catalysts Bollmann, L.; Ratts, J.; Joshi, A. Journal of Catalysis, Vol. 257, Issue 1 https://doi.org/10.1016/j.jcat.2008.04.005	journal	July 2008
The effect of reaction conditions on the stability of Au/CeZrO4 catalysts in the low-temperature water–gas shift reaction Daly, H.; Goguet, A.; Hardacre, C. Journal of Catalysis, Vol. 273, Issue 2 https://doi.org/10.1016/j.jcat.2010.05.021	journal	July 2010
Support effects in the Au-catalyzed CO oxidation – Correlation between activity, oxygen storage capacity, and support reducibility Widmann, D.; Liu, Y.; Schüth, F. Journal of Catalysis, Vol. 276, Issue 2 https://doi.org/10.1016/j.jcat.2010.09.023	journal	December 2010
Reproducible preparation of Au/TS-1 with high reaction rate for gas phase epoxidation of propylene Lee, Wen-Sheng; Cem Akatay, M.; Stach, Eric A. Journal of Catalysis, Vol. 287 https://doi.org/10.1016/j.jcat.2011.12.019	journal	March 2012
Determination of the Au active site and surface active species via operando transmission FTIR and isotopic transient experiments on 2.3wt.% Au/TiO2 for the WGS reaction Wang, Jun; Kispersky, Vincent F.; Nicholas Delgass, W. Journal of Catalysis, Vol. 289 https://doi.org/10.1016/j.jcat.2012.02.008	journal	May 2012
Importance of metal-oxide interfaces in heterogeneous catalysis: A combined DFT, microkinetic, and experimental study of water-gas shift on Au/MgO Zhao, Zhi-Jian; Li, Zhenglong; Cui, Yanran Journal of Catalysis, Vol. 345 https://doi.org/10.1016/j.jcat.2016.11.008	journal	January 2017
Gold nanoparticles: Support effects for the WGS reaction Sandoval, Alberto; Gómez-Cortés, Antonio; Zanella, Rodolfo Journal of Molecular Catalysis A: Chemical, Vol. 278, Issue 1-2 https://doi.org/10.1016/j.molcata.2007.09.014	journal	December 2007
Thermally-driven processes on rutile TiO2(110)-(1×1): A direct view at the atomic scale Dohnálek, Zdenek; Lyubinetsky, Igor; Rousseau, Roger Progress in Surface Science, Vol. 85, Issue 5-8 https://doi.org/10.1016/j.progsurf.2010.03.001	journal	May 2010
Alumina surfaces and interfaces under non-ultrahigh vacuum conditions Kelber, J. Surface Science Reports, Vol. 62, Issue 7 https://doi.org/10.1016/j.surfrep.2006.12.003	journal	July 2007
A DFT+U description of oxygen vacancies at the TiO2 rutile (110) surface Morgan, Benjamin J.; Watson, Graeme W. Surface Science, Vol. 601, Issue 21 https://doi.org/10.1016/j.susc.2007.08.025	journal	November 2007
Adsorption Energy Correlations at the Metal–Support Boundary Mehta, Prateek; Greeley, Jeffrey; Delgass, W. Nicholas ACS Catalysis, Vol. 7, Issue 7 https://doi.org/10.1021/acscatal.7b00979	journal	June 2017
The Influence of Metal Cluster Size on Adsorption Energies: CO Adsorbed on Au Clusters Supported on TiO ₂ Meier, Douglas C.; Goodman, D. Wayne Journal of the American Chemical Society, Vol. 126, Issue 6 https://doi.org/10.1021/ja030359y	journal	February 2004
Identifying an O ₂ Supply Pathway in CO Oxidation on Au/TiO ₂ (110): A Density Functional Theory Study on the Intrinsic Role of Water Liu, L. M.; McAllister, B.; Ye, H. Q. Journal of the American Chemical Society, Vol. 128, Issue 12 https://doi.org/10.1021/ja056801p	journal	March 2006
On the Mechanism of Low-Temperature Water Gas Shift Reaction on Copper Gokhale, Amit A.; Dumesic, James A.; Mavrikakis, Manos Journal of the American Chemical Society, Vol. 130, Issue 4 https://doi.org/10.1021/ja0768237	journal	January 2008
Metallic Corner Atoms in Gold Clusters Supported on Rutile Are the Dominant Active Site during Water−Gas Shift Catalysis Williams, W. Damion; Shekhar, Mayank; Lee, Wen-Sheng Journal of the American Chemical Society, Vol. 132, Issue 40 https://doi.org/10.1021/ja1064262	journal	October 2010
Size and Support Effects for the Water–Gas Shift Catalysis over Gold Nanoparticles Supported on Model Al ₂ O ₃ and TiO ₂ Shekhar, Mayank; Wang, Jun; Lee, Wen-Sheng Journal of the American Chemical Society, Vol. 134, Issue 10 https://doi.org/10.1021/ja210083d	journal	February 2012
γ-Alumina: The Essential and Unexpected Role of Water for the Structure, Stability, and Reactivity of “Defect” Sites Wischert, Raphael; Laurent, Pierre; Copéret, Christophe Journal of the American Chemical Society, Vol. 134, Issue 35 https://doi.org/10.1021/ja3042383	journal	August 2012
Inhibition at Perimeter Sites of Au/TiO ₂ Oxidation Catalyst by Reactant Oxygen Green, Isabel Xiaoye; Tang, Wenjie; McEntee, Monica Journal of the American Chemical Society, Vol. 134, Issue 30 https://doi.org/10.1021/ja304426b	journal	July 2012
Solvothermal Synthesis and Photoreactivity of Anatase TiO ₂ Nanosheets with Dominant {001} Facets Yang, Hua Gui; Liu, Gang; Qiao, Shi Zhang Journal of the American Chemical Society, Vol. 131, Issue 11 https://doi.org/10.1021/ja808790p	journal	March 2009
Preparation and Comparison of Supported Gold Nanocatalysts on Anatase, Brookite, Rutile, and P25 Polymorphs of TiO ₂ for Catalytic Oxidation of CO Yan, Wenfu; Chen, Bei; Mahurin, S. M. The Journal of Physical Chemistry B, Vol. 109, Issue 21 https://doi.org/10.1021/jp044091o	journal	June 2005
Reactivity of Anatase TiO ₂ Nanoparticles: The Role of the Minority (001) Surface Gong, Xue-Qing; Selloni, Annabella The Journal of Physical Chemistry B, Vol. 109, Issue 42 https://doi.org/10.1021/jp055311g	journal	October 2005
High Water−Gas Shift Activity in TiO ₂ (110) Supported Cu and Au Nanoparticles: Role of the Oxide and Metal Particle Size Rodríguez, José A.; Evans, Jaime; Graciani, Jesús The Journal of Physical Chemistry C, Vol. 113, Issue 17 https://doi.org/10.1021/jp900483u	journal	April 2009
Highly Active Photocatalytic TiO ₂ Powders Obtained by Thermohydrolysis of TiCl ₄ in Water Di Paola, Agatino; Bellardita, Marianna; Ceccato, Riccardo The Journal of Physical Chemistry C, Vol. 113, Issue 34 https://doi.org/10.1021/jp904673e	journal	July 2009
When Gold Is Not Noble: Nanoscale Gold Catalysts Sanchez, A.; Abbet, S.; Heiz, U. The Journal of Physical Chemistry A, Vol. 103, Issue 48 https://doi.org/10.1021/jp9935992	journal	December 1999
Anatase TiO2 single crystals with a large percentage of reactive facets Yang, Hua Gui; Sun, Cheng Hua; Qiao, Shi Zhang Nature, Vol. 453, Issue 7195 https://doi.org/10.1038/nature06964	journal	May 2008
Low-temperature water–gas shift reaction over gold deposited on TiO2 Sakurai, Hiroaki; Ueda, Atsushi; Kobayashi, Tetsuhiko Chemical Communications, Issue 3 https://doi.org/10.1039/a606192c	journal	January 1997
Geometric and electronic characteristics of active sites on TiO2-supported Au nano-catalysts: insights from first principles Laursen, Siris; Linic, Suljo Physical Chemistry Chemical Physics, Vol. 11, Issue 46 https://doi.org/10.1039/b912641d	journal	January 2009
A climbing image nudged elastic band method for finding saddle points and minimum energy paths Henkelman, Graeme; Uberuaga, Blas P.; Jónsson, Hannes The Journal of Chemical Physics, Vol. 113, Issue 22, p. 9901-9904 https://doi.org/10.1063/1.1329672	journal	December 2000
Adsorption of O2 and oxidation of CO at Au nanoparticles supported by TiO2(110) Molina, L. M.; Rasmussen, M. D.; Hammer, B. The Journal of Chemical Physics, Vol. 120, Issue 16 https://doi.org/10.1063/1.1687337	journal	April 2004
A dimer method for finding saddle points on high dimensional potential surfaces using only first derivatives Henkelman, Graeme; Jónsson, Hannes The Journal of Chemical Physics, Vol. 111, Issue 15 https://doi.org/10.1063/1.480097	journal	October 1999
Energetics of nanocrystalline TiO2 Ranade, M. R.; Navrotsky, A.; Zhang, H. Z. Proceedings of the National Academy of Sciences, Vol. 99, Issue Supplement 2 https://doi.org/10.1073/pnas.251534898	journal	March 2002
The Use of Kinetics in Evaluating Mechanisms in Heterogeneous Catalysis Bond, Geoffrey C. Catalysis Reviews, Vol. 50, Issue 4 https://doi.org/10.1080/01614940802480338	journal	December 2008
Special points for Brillouin-zone integrations Monkhorst, Hendrik J.; Pack, James D. Physical Review B, Vol. 13, Issue 12, p. 5188-5192 https://doi.org/10.1103/PhysRevB.13.5188	journal	June 1976
Accurate and simple analytic representation of the electron-gas correlation energy Perdew, John P.; Wang, Yue Physical Review B, Vol. 45, Issue 23, p. 13244-13249 https://doi.org/10.1103/PhysRevB.45.13244	journal	June 1992
Electron-energy-loss spectra and the structural stability of nickel oxide: An LSDA+U study Dudarev, S. L.; Botton, G. A.; Savrasov, S. Y. Physical Review B, Vol. 57, Issue 3, p. 1505-1509 https://doi.org/10.1103/PhysRevB.57.1505	journal	January 1998
From ultrasoft pseudopotentials to the projector augmented-wave method Kresse, G.; Joubert, D. Physical Review B, Vol. 59, Issue 3, p. 1758-1775 https://doi.org/10.1103/PhysRevB.59.1758	journal	January 1999
Structure and Energetics of Water Adsorbed at TiO 2 Anatase \(101\) and \(001\) Surfaces Vittadini, A.; Selloni, A.; Rotzinger, F. P. Physical Review Letters, Vol. 81, Issue 14 https://doi.org/10.1103/PhysRevLett.81.2954	journal	October 1998
Catalytic Role of Metal Oxides in Gold-Based Catalysts: A First Principles Study of CO Oxidation on T i O 2 Supported Au Liu, Zhi-Pan; Gong, Xue-Qing; Kohanoff, Jorge Physical Review Letters, Vol. 91, Issue 26 https://doi.org/10.1103/PhysRevLett.91.266102	journal	December 2003
Active Nonmetallic Au and Pt Species on Ceria-Based Water-Gas Shift Catalysts Fu, Q. Science, Vol. 301, Issue 5635 https://doi.org/10.1126/science.1085721	journal	August 2003
Activity of CeOx and TiOx Nanoparticles Grown on Au(111) in the Water-Gas Shift Reaction Rodriguez, J. A.; Ma, S.; Liu, P. Science, Vol. 318, Issue 5857 https://doi.org/10.1126/science.1150038	journal	December 2007
Identification of Active Gold Nanoclusters on Iron Oxide Supports for CO Oxidation Herzing, A. A.; Kiely, C. J.; Carley, A. F. Science, Vol. 321, Issue 5894 https://doi.org/10.1126/science.1159639	journal	September 2008
Alkali-Stabilized Pt-OHx Species Catalyze Low-Temperature Water-Gas Shift Reactions Zhai, Y.; Pierre, D.; Si, R. Science, Vol. 329, Issue 5999 https://doi.org/10.1126/science.1192449	journal	September 2010
Reactivity of the Gold/Water Interface During Selective Oxidation Catalysis Zope, B. N.; Hibbitts, D. D.; Neurock, M. Science, Vol. 330, Issue 6000 https://doi.org/10.1126/science.1195055	journal	September 2010
Spectroscopic Observation of Dual Catalytic Sites During Oxidation of CO on a Au/TiO2 Catalyst Green, I. X.; Tang, W.; Neurock, M. Science, Vol. 333, Issue 6043 https://doi.org/10.1126/science.1207272	journal	August 2011
Onset of Catalytic Activity of Gold Clusters on Titania with the Appearance of Nonmetallic Properties Valden, M. Science, Vol. 281, Issue 5383 https://doi.org/10.1126/science.281.5383.1647	journal	September 1998
Selective oxidation of propylene over gold deposited on titanium-based oxides Haruta, M.; Uphade, B. S.; Tsubota, S. Research on Chemical Intermediates, Vol. 24, Issue 3 https://doi.org/10.1163/156856798X00276	journal	March 1998
Novel Gold Catalysts for the Oxidation of Carbon Monoxide at a Temperature far Below 0 °C Haruta, Masatake; Kobayashi, Tetsuhiko; Sano, Hiroshi Chemistry Letters, Vol. 16, Issue 2 https://doi.org/10.1246/cl.1987.405	journal	February 1987

Similar Records

Water-gas shift reaction over supported Au nanoparticles

Journal Article · 2021 · J. Catal. · OSTI ID:1866461

Shekhar, Mayank; Lee, Wen-Sheng; Akatay, M. Cem; +7 more

Plasmon-enhanced reverse water gas shift reaction over oxide supported Au catalysts

Journal Article · 2014 · Catalysis Science and Technology · OSTI ID:1211276

Upadhye, AA; Ro, I; Zeng, X; +5 more

A Study of Support Effects for the Water-Gas-Shift Reaction over Cu

Journal Article · 2022 · Catalysts · OSTI ID:2419573

Chang, Jian; Feng, Zhuoming; Vohs, John M.; +1 more

Title: Water-gas shift reaction over supported Au nanoparticles

Citation Formats

References (76)

Similar Records

Related Subjects