Ferromagnetic Double Perovskite Semiconductors with Tunable Properties

Jin, Lun; Ni, Danrui; Gui, Xin; Straus, Daniel B.; Zhang, Qiang; Cava, Robert J.

doi:10.1002/advs.202104319

Title: Ferromagnetic Double Perovskite Semiconductors with Tunable Properties

Journal Article · 20 January 2022 · Advanced Science

DOI: https://doi.org/10.1002/advs.202104319 · OSTI ID:1841284

^[1]; Ni, Danrui ^[1]; Gui, Xin ^[1]; Straus, Daniel B. ^[1]; Zhang, Qiang ^[2]; Cava, Robert J. ^[1]

Department of Chemistry Princeton University Princeton NJ 08544 USA
Neutron Scattering Division Oak Ridge National Laboratory Oak Ridge TN 37831 USA

Abstract The authors successfully dope the magnetically silent double perovskite semiconductor Sr ₂ GaSbO ₆ to induce ferromagnetism and tune its bandgap, with Ga ³⁺ partially substituted by the magnetic trivalent cation Mn ³⁺ , in a rigid cation ordering with Sb ⁵⁺ . The new ferromagnetic semiconducting Sr ₂ Ga ₁₋ _x Mn _x SbO ₆ double perovskite, which crystallizes in tetragonal symmetry (space group I 4/ m ) and has tunable ferromagnetic ordering temperature and bandgap, suggests that magnetic ion doping of double perovskites is a productive avenue toward obtaining materials for application in next‐generation oxide‐based spintronic devices.

View Journal Article

Cite

Export

Save

Sponsoring Organization:: USDOE

Grant/Contract Number:: FG02-98ER45706

OSTI ID:: 1841284

Journal Information:: Advanced Science, Journal Name: Advanced Science Journal Issue: 8 Vol. 9; ISSN 2198-3844

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

References (53)

Magnetocapacitance and Magnetoresistance Near Room Temperature in a Ferromagnetic Semiconductor: La2NiMnO6 Rogado, N. S.; Li, J.; Sleight, A. W. Advanced Materials, Vol. 17, Issue 18 https://doi.org/10.1002/adma.200500737	journal	September 2005
NiFe2O4: A Versatile Spinel Material Brings New Opportunities for Spintronics Lüders, U.; Barthélémy, A.; Bibes, M. Advanced Materials, Vol. 18, Issue 13 https://doi.org/10.1002/adma.200500972	journal	July 2006
VI ₃ —a New Layered Ferromagnetic Semiconductor Kong, Tai; Stolze, Karoline; Timmons, Erik I. Advanced Materials, Vol. 31, Issue 17 https://doi.org/10.1002/adma.201808074	journal	March 2019
Spin‐Ladder Iron Oxide: Sr ₃ Fe ₂ O ₅ Kageyama, Hiroshi; Watanabe, Takashi; Tsujimoto, Yoshihiro Angewandte Chemie International Edition, Vol. 47, Issue 31 https://doi.org/10.1002/anie.200801146	journal	July 2008
Strontium Vanadium Oxide-Hydrides: “Square-Planar” Two-Electron Phases Denis Romero, Fabio; Leach, Alice; Möller, Johannes S. Angewandte Chemie International Edition, Vol. 53, Issue 29 https://doi.org/10.1002/anie.201403536	journal	June 2014
Giant Magnetoresistance in the Half-Metallic Double-Perovskite Ferrimagnet Mn ₂ FeReO ₆ Li, Man-Rong; Retuerto, Maria; Deng, Zheng Angewandte Chemie International Edition, Vol. 54, Issue 41 https://doi.org/10.1002/anie.201506456	journal	July 2015
Ferromagnetism and Electronic Structure in ManganeseDoped YCrO3 Perovskite Oxide: Ab Initio Study El hachimi, A. G.; OuldNE, M. L.; Zaari, H. Journal of Superconductivity and Novel Magnetism, Vol. 30, Issue 2 https://doi.org/10.1007/s10948-016-3716-7	journal	September 2016
The magnetic, optical, and transport properties of representatives of a class of magnetic semiconductors: The europium chalcogenides Mauger, A.; Godart, C. Physics Reports, Vol. 141, Issue 2-3 https://doi.org/10.1016/0370-1573(86)90139-0	journal	August 1986
Magnetic properties of Ga-doped lanthanum manganite with controlled oxygen stoichometry Vertruyen, B.; Hébert, S.; Maignan, A. Crystal Engineering, Vol. 5, Issue 3-4 https://doi.org/10.1016/S1463-0184(02)00041-2	journal	September 2002
Theoretical analysis of the structural, electronic and optical properties of tetragonal Sr2GaSbO6 Berri, Saadi Chinese Journal of Physics, Vol. 55, Issue 6 https://doi.org/10.1016/j.cjph.2017.11.001	journal	December 2017
Review on spintronics: Principles and device applications Hirohata, Atsufumi; Yamada, Keisuke; Nakatani, Yoshinobu Journal of Magnetism and Magnetic Materials, Vol. 509 https://doi.org/10.1016/j.jmmm.2020.166711	journal	September 2020
Electronic structure and fundamental absorption edges of KPb2Br5, K0.5Rb0.5Pb2Br5, and RbPb2Br5 single crystals Tarasova, A. Yu.; Isaenko, L. I.; Kesler, V. G. Journal of Physics and Chemistry of Solids, Vol. 73, Issue 5 https://doi.org/10.1016/j.jpcs.2012.01.014	journal	May 2012
Crystal structures of disordered A2Mn3+M5+O6 (A=Sr, Ca; M=Sb, Nb, Ru) perovskites Lufaso, Michael W.; Woodward, Patrick M.; Goldberger, Joshua Journal of Solid State Chemistry, Vol. 177, Issue 4-5 https://doi.org/10.1016/j.jssc.2003.12.020	journal	April 2004
Synthesis, structure and magnetic properties of A2MnB′O6 (A=Ca, Sr; B′=Sb, Ta) double perovskites Mandal, Tapas Kumar; Poltavets, Viktor V.; Croft, Mark Journal of Solid State Chemistry, Vol. 181, Issue 9 https://doi.org/10.1016/j.jssc.2008.04.038	journal	September 2008
Temperature evolution of structure and magnetic properties in the perovskite Sr2MnSbO6 Ivanov, S. A.; Nordblad, P.; Tellgren, R. Materials Research Bulletin, Vol. 44, Issue 4 https://doi.org/10.1016/j.materresbull.2008.09.017	journal	April 2009
Perovskite oxides applications in high temperature oxygen separation, solid oxide fuel cell and membrane reactor: A review Sunarso, Jaka; Hashim, Siti Salwa; Zhu, Na Progress in Energy and Combustion Science, Vol. 61 https://doi.org/10.1016/j.pecs.2017.03.003	journal	July 2017
Hole and Electron Doping of Topochemically Reduced Ni(I)/Ru(II) Insulating Ferromagnetic Oxides Xu, Zheying; Jin, Lun; Backhaus, Julius-Konstantin Inorganic Chemistry, Vol. 60, Issue 19 https://doi.org/10.1021/acs.inorgchem.1c02265	journal	September 2021
Chemical Structures and Performance of Perovskite Oxides Pena, M.; Fierro, J. Chemical Reviews, Vol. 101, Issue 7, p. 1981-2018 https://doi.org/10.1021/cr980129f	journal	July 2001
Data Mined Ionic Substitutions for the Discovery of New Compounds Hautier, Geoffroy; Fischer, Chris; Ehrlacher, Virginie Inorganic Chemistry, Vol. 50, Issue 2 https://doi.org/10.1021/ic102031h	journal	January 2011
Infinite-layer iron oxide with a square-planar coordination Tsujimoto, Y.; Tassel, C.; Hayashi, N. Nature, Vol. 450, Issue 7172, p. 1062-1065 https://doi.org/10.1038/nature06382	journal	December 2007
All-solid-state dye-sensitized solar cells with high efficiency Chung, In; Lee, Byunghong; He, Jiaqing Nature, Vol. 485, Issue 7399, p. 486-489 https://doi.org/10.1038/nature11067	journal	May 2012
Discovery of intrinsic ferromagnetism in two-dimensional van der Waals crystals Gong, Cheng; Li, Lin; Li, Zhenglu Nature, Vol. 546, Issue 7657 https://doi.org/10.1038/nature22060	journal	April 2017
Layer-dependent ferromagnetism in a van der Waals crystal down to the monolayer limit Huang, Bevin; Clark, Genevieve; Navarro-Moratalla, Efrén Nature, Vol. 546, Issue 7657 https://doi.org/10.1038/nature22391	journal	June 2017
Optically switched magnetism in photovoltaic perovskite CH3NH3(Mn:Pb)I3 Náfrádi, B.; Szirmai, P.; Spina, M. Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms13406	journal	November 2016
High-temperature ferromagnetic semiconductor with a field-tunable green fluorescent effect Zhou, Bowen; Zhao, Qing; Liu, Zhehong NPG Asia Materials, Vol. 12, Issue 1 https://doi.org/10.1038/s41427-020-00250-3	journal	October 2020
CrXTe ₃ (X = Si, Ge) nanosheets: two dimensional intrinsic ferromagnetic semiconductors Li, Xingxing; Yang, Jinlong Journal of Materials Chemistry C, Vol. 2, Issue 34 https://doi.org/10.1039/C4TC01193G	journal	January 2014
Robust intrinsic ferromagnetism and half semiconductivity in stable two-dimensional single-layer chromium trihalides Zhang, Wei-Bing; Qu, Qian; Zhu, Peng Journal of Materials Chemistry C, Vol. 3, Issue 48 https://doi.org/10.1039/C5TC02840J	journal	January 2015
A class of Pb-free double perovskite halide semiconductors with intrinsic ferromagnetism, large spin splitting and high Curie temperature Cai, Bo; Chen, Xi; Xie, Meiqiu Materials Horizons, Vol. 5, Issue 5 https://doi.org/10.1039/C8MH00590G	journal	January 2018
(Ga,Mn)As: A new diluted magnetic semiconductor based on GaAs Ohno, H.; Shen, A.; Matsukura, F. Applied Physics Letters, Vol. 69, Issue 3 https://doi.org/10.1063/1.118061	journal	July 1996
Spin filtering through ferrimagnetic NiFe2O4 tunnel barriers Lüders, U.; Bibes, M.; Bouzehouane, K. Applied Physics Letters, Vol. 88, Issue 8 https://doi.org/10.1063/1.2172647	journal	February 2006
Diluted magnetic semiconductors Furdyna, J. K. Journal of Applied Physics, Vol. 64, Issue 4 https://doi.org/10.1063/1.341700	journal	August 1988
Electronic structure of ferromagnetic semiconductor material on the monoclinic and rhombohedral ordered double perovskites La ₂ FeCoO ₆ Fuh, Huei-Ru; Weng, Ke-Chuan; Chang, Ching-Ray Journal of Applied Physics, Vol. 117, Issue 17 https://doi.org/10.1063/1.4907327	journal	May 2015
Structural studies of Sr ₂ GaSbO ₆ , Sr ₂ NiMoO ₆ , and Sr ₂ FeNbO ₆ using pressure and temperature Lufaso, Michael W.; Macquart, René B.; Lee, Yongjae Journal of Physics: Condensed Matter, Vol. 18, Issue 39 https://doi.org/10.1088/0953-8984/18/39/008	journal	September 2006
Interplay between magnetism and lattice distortions in LaMn _{1 x} Ga _x O ₃ Farrell, J.; Gehring, G. A. New Journal of Physics, Vol. 6 https://doi.org/10.1088/1367-2630/6/1/168	journal	January 2004
First-principles design of spintronics materials Li, Xingxing; Yang, Jinlong National Science Review, Vol. 3, Issue 3 https://doi.org/10.1093/nsr/nww026	journal	April 2016
Full-potential self-consistent linearized-augmented-plane-wave method for calculating the electronic structure of molecules and surfaces: O 2 molecule Wimmer, E.; Krakauer, H.; Weinert, M. Physical Review B, Vol. 24, Issue 2 https://doi.org/10.1103/PhysRevB.24.864	journal	July 1981
Spin-filter effect of ferromagnetic europium sulfide tunnel barriers Hao, X.; Moodera, J. S.; Meservey, R. Physical Review B, Vol. 42, Issue 13 https://doi.org/10.1103/PhysRevB.42.8235	journal	November 1990
Accurate and simple analytic representation of the electron-gas correlation energy Perdew, John P.; Wang, Yue Physical Review B, Vol. 45, Issue 23, p. 13244-13249 https://doi.org/10.1103/PhysRevB.45.13244	journal	June 1992
Theory of polarization of crystalline solids King-Smith, R. D.; Vanderbilt, David Physical Review B, Vol. 47, Issue 3 https://doi.org/10.1103/PhysRevB.47.1651	journal	January 1993
Carrier-induced ferromagnetism in p − Zn 1 − x Mn x Te Ferrand, D.; Cibert, J.; Wasiela, A. Physical Review B, Vol. 63, Issue 8 https://doi.org/10.1103/PhysRevB.63.085201	journal	February 2001
Vibronic superexchange in single-crystal LaMn 1 − x Ga x O 3 Zhou, J. -S.; Yin, H. Q.; Goodenough, J. B. Physical Review B, Vol. 63, Issue 18 https://doi.org/10.1103/PhysRevB.63.184423	journal	April 2001
Orbital mixing and ferromagnetism in LaMn 1 − x Ga x O 3 Zhou, J. -S.; Goodenough, J. B. Physical Review B, Vol. 77, Issue 17 https://doi.org/10.1103/PhysRevB.77.172409	journal	May 2008
Carrier-concentration – induced ferromagnetism in PbSnMnTe Story, T.; Gała̧zka, R. R.; Frankel, R. B. Physical Review Letters, Vol. 56, Issue 7 https://doi.org/10.1103/PhysRevLett.56.777	journal	February 1986
Electron-Spin Polarization in Tunnel Junctions in Zero Applied Field with Ferromagnetic EuS Barriers Moodera, J. S.; Hao, X.; Gibson, G. A. Physical Review Letters, Vol. 61, Issue 5 https://doi.org/10.1103/PhysRevLett.61.637	journal	August 1988
Diluted magnetic III-V semiconductors Munekata, H.; Ohno, H.; von Molnar, S. Physical Review Letters, Vol. 63, Issue 17 https://doi.org/10.1103/PhysRevLett.63.1849	journal	October 1989
Magnetotransport properties of p -type (In,Mn)As diluted magnetic III-V semiconductors Ohno, H.; Munekata, H.; Penney, T. Physical Review Letters, Vol. 68, Issue 17 https://doi.org/10.1103/PhysRevLett.68.2664	journal	April 1992
Observation of a Ferromagnetic Transition Induced by Two-Dimensional Hole Gas in Modulation-Doped CdMnTe Quantum Wells Haury, A.; Wasiela, A.; Arnoult, A. Physical Review Letters, Vol. 79, Issue 3 https://doi.org/10.1103/PhysRevLett.79.511	journal	July 1997
Anomalous Transport Phenomena in Eu-Chalcogenide Alloys Kasuya, T.; Yanase, A. Reviews of Modern Physics, Vol. 40, Issue 4 https://doi.org/10.1103/RevModPhys.40.684	journal	October 1968
A profile refinement method for nuclear and magnetic structures Rietveld, H. M. Journal of Applied Crystallography, Vol. 2, Issue 2, p. 65-71 https://doi.org/10.1107/S0021889869006558	journal	June 1969
Making Nonmagnetic Semiconductors Ferromagnetic Ohno, H. Science, Vol. 281, Issue 5379 https://doi.org/10.1126/science.281.5379.951	journal	August 1998
Zener Model Description of Ferromagnetism in Zinc-Blende Magnetic Semiconductors Dietl, T. Science, Vol. 287, Issue 5455 https://doi.org/10.1126/science.287.5455.1019	journal	February 2000
Correlations between Electronic and Magnetic Properties in Semimagnetic Semiconductors Story, T. Acta Physica Polonica A, Vol. 91, Issue 1 https://doi.org/10.12693/APhysPolA.91.173	journal	January 1997
Recent progress in ferromagnetic semiconductors and spintronics devices Tanaka, Masaaki Japanese Journal of Applied Physics, Vol. 60, Issue 1 https://doi.org/10.35848/1347-4065/abcadc	journal	December 2020

Similar Records

Magnetic cations doped into a double perovskite semiconductor

Journal Article · 2022 · Journal of Materials Chemistry C · OSTI ID:1845755

Jin, Lun; Ni, Danrui; Gui, Xin; +3 more

B a_{2} NiOs O_{6}

: A Dirac-Mott insulator with ferromagnetism near 100 K

Journal Article · 2016 · Physical Review B · OSTI ID:1338555

Feng, Hai L.; Calder, Stuart; Ghimire, Madhav Prasad; +14 more

Room-Temperature Ferromagnetic Insulating State in Cation-Ordered Double-Perovskite Sr₂Fe₁₊_xRe_1–_xO₆ Films

Journal Article · 2018 · Advanced Materials · OSTI ID:1484996

Sohn, Changhee; Skoropata, Elizabeth M.; Choi, Yongseong; +9 more

Title: Ferromagnetic Double Perovskite Semiconductors with Tunable Properties

Citation Formats

References (53)

Similar Records

Related Subjects