Identifying Support Effects in Au-Catalyzed CO Oxidation

Mansley, Zachary R.; Paull, Ryan J.; Savereide, Louisa; Tatro, Scott; Greenstein, Emily P.; Gosavi, Abha; Cheng, Emily; Wen, Jianguo; Poeppelmeier, Kenneth R.; Notestein, Justin M.; Marks, Laurence D.

doi:10.1021/acscatal.1c03156

Title: Identifying Support Effects in Au-Catalyzed CO Oxidation

Journal Article · 13 September 2021 · ACS Catalysis

DOI: https://doi.org/10.1021/acscatal.1c03156 · OSTI ID:1840601

^[1];

^[1]; Savereide, Louisa ^[1]; Tatro, Scott ^[1]; Greenstein, Emily P. ^[1];

^[1]; Cheng, Emily ^[1];

^[2];

^[1];

^[1]

Northwestern Univ., Evanston, IL (United States)
Argonne National Lab. (ANL), Lemont, IL (United States)

Some catalytic oxide supports are more equal than others, with numerous variable properties ranging from crystal symmetry to surface chemistry and electronic structure. As a consequence, it is often very difficult to determine which of these act as the driver of performance changes observed in catalysis. In this work, we hold many of these variable properties constant with structurally similar LnScO₃ (Ln = La, Sm, and Nd) nanoparticle supports with cuboidal shapes and a common Sc-rich surface termination. Using CO oxidation over supported Au nanoparticles as a probe reaction, we observe higher activation energy and a slower rate using NdScO₃ as the support material. This change is found to correlate to the strength of CO₂ binding to the support surface, identified by temperature-programmed desorption measurements. Furthermore, the change is due to differences in the 4f electrons of the lanthanide cations, the cations’ Lewis acidity, and the inductive effect they impose.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1840601

Journal Information:: ACS Catalysis, Journal Name: ACS Catalysis Journal Issue: 19 Vol. 11; ISSN 2155-5435

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
DFT
catalysts
electron microscopy
electronic structure
gold
metal nanoparticles
nanoparticles
oxidation
support effects
surfaces
thermodynamics

Title: Identifying Support Effects in Au-Catalyzed CO Oxidation

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