Title: Observation of a New Polyhalide Phase in Ag-Cl2 System at High Pressure

Journal Article · · Crystals
ORCiD logo [1];  [1]; ORCiD logo [2];  [3];  [4]; ORCiD logo [1]
  1. Univ. of Warsaw (Poland). Center of New Technologies
  2. Slovak Univ. of Technology in Bratislava, Trnava (Slovakia)
  3. Center for High Pressure Science and Technology Advanced Research, Shanghai (China)
  4. Argonne National Lab. (ANL), Lemont, IL (United States); Carnegie Inst. of Science, Argonne, IL (United States). High Pressure Collaborative Access Team (HPCAT)
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In this short contribution, we examine Raman spectroscopic data from high-pressure and high-temperature experiments with an Ag-Cl2 system, and find that they are in good agreement with previously observed and calculated spectra of polychloride species. Our results imply the formation of a hitherto unknown AgClx compound, which warrants further study.

Research Organization:
Argonne National Laboratory (ANL), Argonne, IL (United States)
Sponsoring Organization:
European Regional Development Fund (ERDF); Polish National Science Centre; Slovak Research and Development Agency (SRDA); USDOE
Grant/Contract Number:
AC02-06CH11357
OSTI ID:
1840525
Journal Information:
Crystals, Journal Name: Crystals Journal Issue: 12 Vol. 11; ISSN 2073-4352
Publisher:
MDPICopyright Statement
Country of Publication:
United States
Language:
English

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36 MATERIALS SCIENCE
high pressure
polyhalides
silver