Glass-fiber-reinforced polymeric film as an efficient protecting layer for stable Li metal electrodes

Gao, Shilun; Cannon, Andrew; Sun, Feiyuan; Pan, Yiyang; Yang, Dandan; Ge, Sirui; Liu, Nian; Sokolov, Alexei P.; Ryan, Emily; Yang, Huabin; Cao, Peng-Fei

doi:10.1016/j.xcrp.2021.100534

Title: Glass-fiber-reinforced polymeric film as an efficient protecting layer for stable Li metal electrodes

Journal Article · 05 August 2021 · Cell Reports Physical Science

DOI: https://doi.org/10.1016/j.xcrp.2021.100534 · OSTI ID:1840165

Gao, Shilun ^[1]; Cannon, Andrew ^[2]; Sun, Feiyuan ^[1]; Pan, Yiyang ^[1]; Yang, Dandan ^[1]; Ge, Sirui ^[3]; Liu, Nian ^[4];

^[5]; Ryan, Emily ^[2]; Yang, Huabin ^[1];

^[6]

Nankai Univ., Tianjin (China)
Boston Univ., MA (United States)
Univ. of Tennessee, Knoxville, TN (United States)
Georgia Inst. of Technology, Atlanta, GA (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Univ. of Tennessee, Knoxville, TN (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

With numerous reports on protecting films for stable lithium (Li) metal electrodes, the key attributes for how to construct these efficient layers have rarely been fully investigated. Here, we report a rationally designed hybrid protective layer (HPL) with each component aligning with one key attribute; i.e., cross-linked poly(dimethylsiloxane) (PDMS) enhances flexibility, polyethylene glycol (PEG) provides homogeneous ion-conducting channels, and glass fiber (GF) affords mechanical robustness. A significant improvement of the electrochemical performance of HPL-modified electrodes can be achieved in Li/HPL@Cu half cells, HPL@Li/HPL@Li symmetric cells, and HPL@Li/LiFePO₄ full cells. Even with an industrial standard LiFePO₄ cathode (96.8 wt % active material), the assembled cell still exhibits a capacity retention of 90% after 100 cycles at 1 C. More importantly, the functionality of each component has been studied comprehensively via electrochemical and physical experiments and simulations, which will provide useful guidance on how to construct efficient protective layers for next-generation energy storage devices.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1840165

Journal Information:: Cell Reports Physical Science, Journal Name: Cell Reports Physical Science Journal Issue: 8 Vol. 2; ISSN 2666-3864

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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25 ENERGY STORAGE
artificial solid electrolyte interphase
glass fiber
lithium metal batteries
poly(dimethylsiloxane)
polymer
protective layer

Title: Glass-fiber-reinforced polymeric film as an efficient protecting layer for stable Li metal electrodes

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