DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Synthesis of LaWN3 nitride perovskite with polar symmetry

Abstract

Perovskite structured materials have a variety of uses as photovoltaics, capacitors, and micromechanical actuators, along with other applications. Oxides, halides, and chalcogenides all have large numbers of perovskite structured materials. Examples of perovskite nitrides are conspicuously absent, but Talley et al managed to synthesize one (see the Perspective by Hong). Lanthanum tungsten nitride in the perovskite structure turns out to be piezoelectric, which is ideal for a variety of applications. Perovskite structured nitrides are very attractive because they could easily integrate with the large number of nitride-based semiconducting devices already in use.

Authors:
ORCiD logo [1]; ORCiD logo [2]; ORCiD logo [3]; ORCiD logo [3]; ORCiD logo [2]
  1. National Renewable Energy Lab. (NREL), Golden, CO (United States); Colorado School of Mines, Golden, CO (United States)
  2. National Renewable Energy Lab. (NREL), Golden, CO (United States)
  3. Colorado School of Mines, Golden, CO (United States)
Publication Date:
Research Org.:
National Renewable Energy Lab. (NREL), Golden, CO (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1839229
Report Number(s):
NREL/JA-5K00-75605
Journal ID: ISSN 0036-8075; MainId:6044;UUID:22db7143-ac1a-ea11-9c2a-ac162d87dfe5;MainAdminID:63301
Grant/Contract Number:  
AC36-08GO28308
Resource Type:
Accepted Manuscript
Journal Name:
Science
Additional Journal Information:
Journal Volume: 374; Journal Issue: 6574; Journal ID: ISSN 0036-8075
Publisher:
AAAS
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; ferroelectric; LaWN3; nitride; perovskite

Citation Formats

Talley, Kevin R., Perkins, Craig L., Diercks, David R., Brennecka, Geoff L., and Zakutayev, Andriy. Synthesis of LaWN3 nitride perovskite with polar symmetry. United States: N. p., 2021. Web. doi:10.1126/science.abm3466.
Talley, Kevin R., Perkins, Craig L., Diercks, David R., Brennecka, Geoff L., & Zakutayev, Andriy. Synthesis of LaWN3 nitride perovskite with polar symmetry. United States. https://doi.org/10.1126/science.abm3466
Talley, Kevin R., Perkins, Craig L., Diercks, David R., Brennecka, Geoff L., and Zakutayev, Andriy. Thu . "Synthesis of LaWN3 nitride perovskite with polar symmetry". United States. https://doi.org/10.1126/science.abm3466. https://www.osti.gov/servlets/purl/1839229.
@article{osti_1839229,
title = {Synthesis of LaWN3 nitride perovskite with polar symmetry},
author = {Talley, Kevin R. and Perkins, Craig L. and Diercks, David R. and Brennecka, Geoff L. and Zakutayev, Andriy},
abstractNote = {Perovskite structured materials have a variety of uses as photovoltaics, capacitors, and micromechanical actuators, along with other applications. Oxides, halides, and chalcogenides all have large numbers of perovskite structured materials. Examples of perovskite nitrides are conspicuously absent, but Talley et al managed to synthesize one (see the Perspective by Hong). Lanthanum tungsten nitride in the perovskite structure turns out to be piezoelectric, which is ideal for a variety of applications. Perovskite structured nitrides are very attractive because they could easily integrate with the large number of nitride-based semiconducting devices already in use.},
doi = {10.1126/science.abm3466},
journal = {Science},
number = 6574,
volume = 374,
place = {United States},
year = {Thu Dec 16 00:00:00 EST 2021},
month = {Thu Dec 16 00:00:00 EST 2021}
}

Works referenced in this record:

Giant optical anisotropy in a quasi-one-dimensional crystal
journal, June 2018


Metal-Rich Ternary Perovskite Nitrides: Metal-Rich Ternary Perovskite Nitrides
journal, August 2019


Perovskite ThTaN 3 : A large-thermopower topological crystalline insulator
journal, March 2018


Nika : software for two-dimensional data reduction
journal, March 2012


Dimensionality Control of Electronic Phase Transitions in Nickel-Oxide Superlattices
journal, May 2011


Terahertz field–induced ferroelectricity in quantum paraelectric SrTiO 3
journal, June 2019


Prediction of Stable Nitride Perovskites
journal, August 2015


Solid-State Chemistry: A A Rediscovered Chemical Frontier
journal, February 1990


Crystalline Oxides on Silicon: The First Five Monolayers
journal, October 1998


Flexo-photovoltaic effect
journal, April 2018


Large spin splittings due to the orbital degree of freedom and spin textures in a ferroelectric nitride perovskite
journal, July 2020


Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides
journal, September 1976


Reduced coercive field in epitaxial thin film of ferroelectric wurtzite Al 0.7 Sc 0.3 N
journal, April 2021

  • Yazawa, Keisuke; Drury, Daniel; Zakutayev, Andriy
  • Applied Physics Letters, Vol. 118, Issue 16
  • DOI: 10.1063/5.0043613

AlScN: A III-V semiconductor based ferroelectric
journal, March 2019

  • Fichtner, Simon; Wolff, Niklas; Lofink, Fabian
  • Journal of Applied Physics, Vol. 125, Issue 11
  • DOI: 10.1063/1.5084945

Dual-frequency resonance-tracking atomic force microscopy
journal, October 2007


ImageJ2: ImageJ for the next generation of scientific image data
journal, November 2017

  • Rueden, Curtis T.; Schindelin, Johannes; Hiner, Mark C.
  • BMC Bioinformatics, Vol. 18, Issue 1
  • DOI: 10.1186/s12859-017-1934-z

GSAS-II : the genesis of a modern open-source all purpose crystallography software package
journal, March 2013


Preparation of Bulk‐Phase Nitride Perovskite LaReN 3 and Topotactic Reduction to LaNiO 2 ‐Type LaReN 2
journal, September 2021

  • Kloß, Simon D.; Weidemann, Martin L.; Attfield, J. Paul
  • Angewandte Chemie International Edition, Vol. 60, Issue 41
  • DOI: 10.1002/anie.202108759

The perovskite structure—a review of its role in ceramic science and technology
journal, November 2000

  • Bhalla, A. S.; Guo, Ruyan; Roy, Rustum
  • Materials Research Innovations, Vol. 4, Issue 1
  • DOI: 10.1007/s100190000062

GaN/NbN epitaxial semiconductor/superconductor heterostructures
journal, March 2018

  • Yan, Rusen; Khalsa, Guru; Vishwanath, Suresh
  • Nature, Vol. 555, Issue 7695
  • DOI: 10.1038/nature25768

Perovskite thin Films for High-Frequency Capacitor Applications
journal, August 1998


The new nitrides: layered, ferroelectric, magnetic, metallic and superconducting nitrides to boost the GaN photonics and electronics eco-system
journal, May 2019

  • Jena, Debdeep; Page, Ryan; Casamento, Joseph
  • Japanese Journal of Applied Physics, Vol. 58, Issue SC
  • DOI: 10.7567/1347-4065/ab147b

The high-throughput highway to computational materials design
journal, February 2013

  • Curtarolo, Stefano; Hart, Gus L. W.; Nardelli, Marco Buongiorno
  • Nature Materials, Vol. 12, Issue 3
  • DOI: 10.1038/nmat3568

COMBIgor: Data-Analysis Package for Combinatorial Materials Science
journal, May 2019

  • Talley, Kevin R.; Bauers, Sage R.; Melamed, Celeste L.
  • ACS Combinatorial Science, Vol. 21, Issue 7
  • DOI: 10.1021/acscombsci.9b00077

Crystallography Open Database – an open-access collection of crystal structures
journal, May 2009

  • Gražulis, Saulius; Chateigner, Daniel; Downs, Robert T.
  • Journal of Applied Crystallography, Vol. 42, Issue 4
  • DOI: 10.1107/S0021889809016690

Lattice dynamics and ferroelectric properties of the nitride perovskite LaWN 3
journal, January 2017


Efficient Hybrid Solar Cells Based on Meso-Superstructured Organometal Halide Perovskites
journal, October 2012


Piezoelectric Thin Films for Sensors, Actuators, and Energy Harvesting
journal, September 2009

  • Muralt, P.; Polcawich, R. G.; Trolier-McKinstry, S.
  • MRS Bulletin, Vol. 34, Issue 9
  • DOI: 10.1557/mrs2009.177

Triple ionic–electronic conducting oxides for next-generation electrochemical devices
journal, December 2020


Synthesis of the First Thorium-Containing Nitride Perovskite, TaThN3
journal, December 1995

  • Brese, Nathaniel E.; DiSalvo, F. J.
  • Journal of Solid State Chemistry, Vol. 120, Issue 2
  • DOI: 10.1006/jssc.1995.1423

Sr-doped LaMoN 3 and LaWN 3 : New degenerate p-type nitrides
journal, August 2018

  • Singh, Santosh; Tripathi, Madhvendra Nath
  • Journal of Applied Physics, Vol. 124, Issue 6
  • DOI: 10.1063/1.5035135

Rare-earth magnetic nitride perovskites
journal, March 2019

  • Flores-Livas, José A.; Sarmiento-Pérez, R.; Botti, Silvana
  • Journal of Physics: Materials, Vol. 2, Issue 2
  • DOI: 10.1088/2515-7639/ab083e

Time-of-flight neutron diffraction study of the structure of the perovskite-type oxynitride LaWO0.6N2.4
journal, November 1988


Ferroelectric or non-ferroelectric: Why so many materials exhibit “ferroelectricity” on the nanoscale
journal, June 2017

  • Vasudevan, Rama K.; Balke, Nina; Maksymovych, Peter
  • Applied Physics Reviews, Vol. 4, Issue 2
  • DOI: 10.1063/1.4979015

A map of the inorganic ternary metal nitrides
journal, June 2019