Electron diffraction radial distribution function analysis of amorphous boron carbide synthesized by ion beam irradiation and chemical vapor deposition

Ishimaru, Manabu; Nakamura, Ryusuke; Zhang, Yanwen; Weber, William J.; Peterson, George G.; Ianno, Natale J.; Nastasi, Michael

doi:10.1016/j.jeurceramsoc.2021.10.020

Title: Electron diffraction radial distribution function analysis of amorphous boron carbide synthesized by ion beam irradiation and chemical vapor deposition

Journal Article · 17 October 2021 · Journal of the European Ceramic Society

DOI: https://doi.org/10.1016/j.jeurceramsoc.2021.10.020 · OSTI ID:1837850

Ishimaru, Manabu ^[1];

^[2]; Zhang, Yanwen ^[3];

^[3];

^[4]; Ianno, Natale J. ^[5];

^[6]

Kyushu Institute of Technology, Fukaoka (Japan)
Osaka Prefecture Univ., Sakai (Japan)
Univ. of Tennessee, Knoxville, TN (United States); Air Force Institute of Technology, Wright-Patterson AFB, OH (United States)
Air Force Institute of Technology, Wright-Patterson AFB, OH (United States)
Univ. of Nebraska, Lincoln, NE (United States)
Texas A & M Univ., College Station, TX (United States)

Amorphous boron carbide (a-BxC) networks consist of light elements, and their low atomic scattering factors makes structural analysis by x-ray diffraction difficult. Electron diffraction has an advantage of detecting the light elements, because of the strong interaction between the matter and electrons. In this work, we prepared a-BxC by ion beam technologies and plasma-enhanced chemical vapor deposition, and characterized their structures via atomic pair-distribution functions derived from electron diffraction intensity profiles. It was found that a pentagonal pyramid is the most favorable cluster in a-B4C generated by ion irradiation, while C—C homonuclear bonds were formed in the deposited a-B_xC thin film. X-ray photoemission spectroscopy revealed that the a-BxC thin film possesses more carbon than B₄C, which is responsible for the formation of the homonuclear bonds.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); MEXT

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1837850

Journal Information:: Journal of the European Ceramic Society, Journal Name: Journal of the European Ceramic Society Journal Issue: 2 Vol. 42; ISSN 0955-2219

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Title: Electron diffraction radial distribution function analysis of amorphous boron carbide synthesized by ion beam irradiation and chemical vapor deposition

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