Two-dimensional titanium carbonitride MXene as a highly efficient electrocatalyst for hydrogen evolution reaction

Liang, Kun; Tabassum, Anika; Kothakonda, Manish; Zhang, Xiaodong; Zhang, Ruiqi; Kenney, Brianna; Koplitz, Brent D.; Sun, Jianwei; Naguib, Michael

doi:10.1016/j.matre.2021.100075

Title: Two-dimensional titanium carbonitride MXene as a highly efficient electrocatalyst for hydrogen evolution reaction

Journal Article · 01 February 2022 · Materials Reports: Energy

DOI: https://doi.org/10.1016/j.matre.2021.100075 · OSTI ID:1837337

Liang, Kun; Tabassum, Anika; Kothakonda, Manish; Zhang, Xiaodong; Zhang, Ruiqi; Kenney, Brianna; Koplitz, Brent D.; Sun, Jianwei; Naguib, Michael

Not Available

View Journal Article

Cite

Export

Save

Sponsoring Organization:: USDOE

Grant/Contract Number:: SC0012432

OSTI ID:: 1837337

Journal Information:: Materials Reports: Energy, Journal Name: Materials Reports: Energy Journal Issue: 1 Vol. 2; ISSN 2666-9358

Publisher:: ElsevierCopyright Statement

Country of Publication:: Country unknown/Code not available

Language:: English

References (60)

Vertically Aligned WS ₂ Nanosheets for Water Splitting Yang, Yang; Fei, Huilong; Ruan, Gedeng Advanced Functional Materials, Vol. 25, Issue 39 https://doi.org/10.1002/adfm.201502479	journal	September 2015
Synthesis and Characterization of 2D Molybdenum Carbide (MXene) Halim, Joseph; Kota, Sankalp; Lukatskaya, Maria R. Advanced Functional Materials, Vol. 26, Issue 18 https://doi.org/10.1002/adfm.201505328	journal	February 2016
Two-Dimensional Nanocrystals Produced by Exfoliation of Ti₃AlC₂ Naguib, Michael; Kurtoglu, Murat; Presser, Volker Advanced Materials, Vol. 23, Issue 37, p. 4248-4253 https://doi.org/10.1002/adma.201102306	journal	August 2011
25th Anniversary Article: MXenes: A New Family of Two-Dimensional Materials Naguib, Michael; Mochalin, Vadym N.; Barsoum, Michel W. Advanced Materials, Vol. 26, Issue 7, p. 992-1005 https://doi.org/10.1002/adma.201304138	journal	December 2013
W-Based Atomic Laminates and Their 2D Derivative W _1.33 C MXene with Vacancy Ordering Meshkian, Rahele; Dahlqvist, Martin; Lu, Jun Advanced Materials, Vol. 30, Issue 21 https://doi.org/10.1002/adma.201706409	journal	April 2018
Heteroatom‐Mediated Interactions between Ruthenium Single Atoms and an MXene Support for Efficient Hydrogen Evolution Ramalingam, Vinoth; Varadhan, Purushothaman; Fu, Hui‐Chun Advanced Materials, Vol. 31, Issue 48 https://doi.org/10.1002/adma.201903841	journal	October 2019
Enhanced Electrocatalysis for Hydrogen Evolution Reactions from WS ₂ Nanoribbons Lin, Jian; Peng, Zhiwei; Wang, Gunuk Advanced Energy Materials, Vol. 4, Issue 10 https://doi.org/10.1002/aenm.201301875	journal	March 2014
Sulfur Cathodes Based on Conductive MXene Nanosheets for High-Performance Lithium-Sulfur Batteries Liang, Xiao; Garsuch, Arnd; Nazar, Linda F. Angewandte Chemie, Vol. 127, Issue 13 https://doi.org/10.1002/ange.201410174	journal	February 2015
A Two-Dimensional Lamellar Membrane: MXene Nanosheet Stacks Ding, Li; Wei, Yanying; Wang, Yanjie Angewandte Chemie International Edition, Vol. 56, Issue 7 https://doi.org/10.1002/anie.201609306	journal	January 2017
Tuning the Electrochemical Performance of Titanium Carbide MXene by Controllable In Situ Anodic Oxidation Tang, Jun; Mathis, Tyler S.; Kurra, Narendra Angewandte Chemie International Edition, Vol. 58, Issue 49 https://doi.org/10.1002/anie.201911604	journal	December 2019
Ultrafine V ₂ O ₅ Nanowires in 3D Current Collector for High-Performance Supercapacitor Liang, Kun; Tang, Xianzhong; Hu, Wencheng ChemElectroChem, Vol. 3, Issue 5 https://doi.org/10.1002/celc.201500541	journal	February 2016
Oxygen‐Functionalized Ultrathin Ti ₃ C ₂ T _x MXene for Enhanced Electrocatalytic Hydrogen Evolution Jiang, Yanan; Sun, Tao; Xie, Xi ChemSusChem, Vol. 12, Issue 7 https://doi.org/10.1002/cssc.201803032	journal	April 2019
Coupling PtNi Ultrathin Nanowires with MXenes for Boosting Electrocatalytic Hydrogen Evolution in Both Acidic and Alkaline Solutions Jiang, Yi; Wu, Xingqiao; Yan, Yucong Small, Vol. 15, Issue 12 https://doi.org/10.1002/smll.201805474	journal	February 2019
Hydrogen: A clean energy source Peraldobicelli, L. International Journal of Hydrogen Energy, Vol. 11, Issue 9 https://doi.org/10.1016/0360-3199(86)90121-7	journal	January 1986
Edge-oriented, high-percentage 1T′-phase MoS2 nanosheets stabilize Ti3C2 MXene for efficient electrocatalytic hydrogen evolution Li, Xitao; Lv, Xinding; Sun, Xiangnan Applied Catalysis B: Environmental, Vol. 284 https://doi.org/10.1016/j.apcatb.2020.119708	journal	May 2021
X-ray photoelectron spectroscopy of select multi-layered transition metal carbides (MXenes) Halim, Joseph; Cook, Kevin M.; Naguib, Michael Applied Surface Science, Vol. 362 https://doi.org/10.1016/j.apsusc.2015.11.089	journal	January 2016
Effects of surface functionalization of mxene-based nanocatalysts on hydrogen evolution reaction performance Zhang, Shijie; Zhuo, Han; Li, Suiqin Catalysis Today, Vol. 368 https://doi.org/10.1016/j.cattod.2020.02.002	journal	May 2021
MXenes (two-dimensional metal carbides) as emerging nanomaterials for water purification: Progress, challenges and prospects Ihsanullah, Ihsanullah Chemical Engineering Journal, Vol. 388 https://doi.org/10.1016/j.cej.2020.124340	journal	May 2020
The properties of hydrogen as fuel tomorrow in sustainable energy system for a cleaner planet Momirlan, M.; Veziroglu, T. International Journal of Hydrogen Energy, Vol. 30, Issue 7 https://doi.org/10.1016/j.ijhydene.2004.10.011	journal	July 2005
Nb4C3Tx (MXene) as a new stable catalyst for the hydrogen evolution reaction Tan, Yuanbo; Zhu, Zhenye; Zhang, Xueting International Journal of Hydrogen Energy, Vol. 46, Issue 2 https://doi.org/10.1016/j.ijhydene.2020.10.046	journal	January 2021
Efficient tuning the electronic structure of N-doped Ti-based MXene to enhance hydrogen evolution reaction Han, Meina; Yang, Jun; Jiang, Jintian Journal of Colloid and Interface Science, Vol. 582 https://doi.org/10.1016/j.jcis.2020.09.001	journal	January 2021
Iron, rhodium-codoped Ni2P nanosheets arrays supported on nickel foam as an efficient bifunctional electrocatalyst for overall water splitting Chen, Meng-Ting; Duan, Jiao-Jiao; Feng, Jiu-Ju Journal of Colloid and Interface Science, Vol. 605 https://doi.org/10.1016/j.jcis.2021.07.101	journal	January 2022
A facile one-pot room-temperature growth of self-supported ultrathin rhodium-iridium nanosheets as high-efficiency electrocatalysts for hydrogen evolution reaction Chen, Meng-Ting; Zhang, Ru-Lan; Feng, Jiu-Ju Journal of Colloid and Interface Science, Vol. 606 https://doi.org/10.1016/j.jcis.2021.08.144	journal	January 2022
Recent development of two-dimensional transition metal dichalcogenides and their applications Choi, Wonbong; Choudhary, Nitin; Han, Gang Hee Materials Today, Vol. 20, Issue 3 https://doi.org/10.1016/j.mattod.2016.10.002	journal	April 2017
Nitrogen-doping induced oxygen divacancies in freestanding molybdenum trioxide single-layers boosting electrocatalytic hydrogen evolution Liu, Katong; Zhang, Wenshuai; Lei, Fengcai Nano Energy, Vol. 30 https://doi.org/10.1016/j.nanoen.2016.09.015	journal	December 2016
Effects of Synthesis and Processing on Optoelectronic Properties of Titanium Carbonitride MXene Hantanasirisakul, Kanit; Alhabeb, Mohamed; Lipatov, Alexey Chemistry of Materials, Vol. 31, Issue 8 https://doi.org/10.1021/acs.chemmater.9b00401	journal	March 2019
Ternary Fe _x Co _{1– x} P Nanowire Array as a Robust Hydrogen Evolution Reaction Electrocatalyst with Pt-like Activity: Experimental and Theoretical Insight Tang, Chun; Gan, Linfeng; Zhang, Rong Nano Letters, Vol. 16, Issue 10 https://doi.org/10.1021/acs.nanolett.6b03332	journal	September 2016
One-Step Synthesis of Modified Ti ₃ C ₂ MXene-Supported Amorphous Molybdenum Sulfide Electrocatalysts by a Facile Gamma Radiation Strategy for Efficient Hydrogen Evolution Reaction Li, Shuangxiao; Que, Xueyan; Chen, Xibang ACS Applied Energy Materials, Vol. 3, Issue 11 https://doi.org/10.1021/acsaem.0c01900	journal	October 2020
Adding a New Member to the MXene Family: Synthesis, Structure, and Electrocatalytic Activity for the Hydrogen Evolution Reaction of V ₄ C ₃ T _x Tran, Minh H.; Schäfer, Timo; Shahraei, Ali ACS Applied Energy Materials, Vol. 1, Issue 8 https://doi.org/10.1021/acsaem.8b00652	journal	July 2018
Impact of Cation Intercalation on the Electronic Structure of Ti ₃ C ₂ T _x MXenes in Sulfuric Acid Al-Temimy, Ameer; Prenger, Kaitlyn; Golnak, Ronny ACS Applied Materials & Interfaces, Vol. 12, Issue 13 https://doi.org/10.1021/acsami.9b22122	journal	March 2020
Overall Water Splitting with Room-Temperature Synthesized NiFe Oxyfluoride Nanoporous Films Liang, Kun; Guo, Limin; Marcus, Kyle ACS Catalysis, Vol. 7, Issue 12 https://doi.org/10.1021/acscatal.7b02991	journal	November 2017
S-Doped MoP Nanoporous Layer Toward High-Efficiency Hydrogen Evolution in pH-Universal Electrolyte Liang, Kun; Pakhira, Srimanta; Yang, Zhenzhong ACS Catalysis, Vol. 9, Issue 1 https://doi.org/10.1021/acscatal.8b04291	journal	November 2018
Two-Dimensional Molybdenum Carbide (MXene) as an Efficient Electrocatalyst for Hydrogen Evolution Seh, Zhi Wei; Fredrickson, Kurt D.; Anasori, Babak ACS Energy Letters, Vol. 1, Issue 3 https://doi.org/10.1021/acsenergylett.6b00247	journal	August 2016
Strained W(Se _x S _{1– x} ) ₂ Nanoporous Films for Highly Efficient Hydrogen Evolution Liang, Kun; Yan, Yong; Guo, Limin ACS Energy Letters, Vol. 2, Issue 6 https://doi.org/10.1021/acsenergylett.7b00326	journal	May 2017
Understanding Chemistry of Two-Dimensional Transition Metal Carbides and Carbonitrides (MXenes) with Gas Analysis Huang, Shuohan; Mochalin, Vadym N. ACS Nano, Vol. 14, Issue 8 https://doi.org/10.1021/acsnano.0c03602	journal	July 2020
Scalable Ti ₃ C ₂ T _x MXene Interlayered Forward Osmosis Membranes for Enhanced Water Purification and Organic Solvent Recovery Wu, Xing; Ding, Mingmei; Xu, Hang ACS Nano, Vol. 14, Issue 7 https://doi.org/10.1021/acsnano.0c04471	journal	June 2020
Wireless Ti ₃ C ₂ T _x MXene Strain Sensor with Ultrahigh Sensitivity and Designated Working Windows for Soft Exoskeletons Yang, Haitao; Xiao, Xiao; Li, Zhipeng ACS Nano, Vol. 14, Issue 9 https://doi.org/10.1021/acsnano.0c04730	journal	August 2020
Pre-Sodiated Ti ₃ C ₂ T _x MXene Structure and Behavior as Electrode for Sodium-Ion Capacitors Brady, Alexander; Liang, Kun; Vuong, Van Quan ACS Nano, Vol. 15, Issue 2 https://doi.org/10.1021/acsnano.0c09301	journal	January 2021
Metallic Ti ₃ C ₂ T _x MXene Gas Sensors with Ultrahigh Signal-to-Noise Ratio Kim, Seon Joon; Koh, Hyeong-Jun; Ren, Chang E. ACS Nano, Vol. 12, Issue 2 https://doi.org/10.1021/acsnano.7b07460	journal	January 2018
Synthesis of Mo 4 VAlC 4 MAX Phase and Two-Dimensional Mo 4 VC 4 MXene with Five Atomic Layers of Transition Metals Deysher, Grayson; Shuck, Christopher Eugene; Hantanasirisakul, Kanit ACS Nano, Vol. 14, Issue 1 https://doi.org/10.1021/acsnano.9b07708	journal	December 2019
Bioinspired Microspines for a High-Performance Spray Ti ₃ C ₂ T _x MXene-Based Piezoresistive Sensor Cheng, Yongfa; Ma, Yanan; Li, Luying ACS Nano, Vol. 14, Issue 2 https://doi.org/10.1021/acsnano.9b08952	journal	February 2020
Periodically Patterned Au-TiO ₂ Heterostructures for Photoelectrochemical Sensor Guo, Limin; Li, Zhao; Marcus, Kyle ACS Sensors, Vol. 2, Issue 5 https://doi.org/10.1021/acssensors.7b00251	journal	April 2017
Synergistic Effects of Nitrogen Doping on MXene for Enhancement of Hydrogen Evolution Reaction Le, Thi Anh; Bui, Quoc Viet; Tran, Ngoc Quang ACS Sustainable Chemistry & Engineering, Vol. 7, Issue 19 https://doi.org/10.1021/acssuschemeng.9b04470	journal	September 2019
Element Replacement Approach by Reaction with Lewis Acidic Molten Salts to Synthesize Nanolaminated MAX Phases and MXenes Li, Mian; Lu, Jun; Luo, Kan Journal of the American Chemical Society, Vol. 141, Issue 11 https://doi.org/10.1021/jacs.9b00574	journal	March 2019
Understanding the Reactivity of Layered Transition-Metal Sulfides: A Single Electronic Descriptor for Structure and Adsorption Tsai, Charlie; Chan, Karen; Nørskov, Jens K. The Journal of Physical Chemistry Letters, Vol. 5, Issue 21 https://doi.org/10.1021/jz5020532	journal	October 2014
Two-Dimensional Transition Metal Carbides Naguib, Michael; Mashtalir, Olha; Carle, Joshua ACS Nano, Vol. 6, Issue 2 https://doi.org/10.1021/nn204153h	journal	January 2012
2D metal carbides and nitrides (MXenes) for energy storage Anasori, Babak; Lukatskaya, Maria R.; Gogotsi, Yury Nature Reviews Materials, Vol. 2, Issue 2 https://doi.org/10.1038/natrevmats.2016.98	journal	January 2017
Hydrogen evolution by a metal-free electrocatalyst Zheng, Yao; Jiao, Yan; Zhu, Yihan Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms4783	journal	April 2014
Ultra-high-rate pseudocapacitive energy storage in two-dimensional transition metal carbides Lukatskaya, Maria R.; Kota, Sankalp; Lin, Zifeng Nature Energy, Vol. 2, Issue 8 https://doi.org/10.1038/nenergy.2017.105	journal	July 2017
Recent advances in transition metal phosphide nanomaterials: synthesis and applications in hydrogen evolution reaction Shi, Yanmei; Zhang, Bin Chemical Society Reviews, Vol. 45, Issue 6, p. 1529-1541 https://doi.org/10.1039/C5CS00434A	journal	January 2016
Large-scale delamination of multi-layers transition metal carbides and carbonitrides “MXenes” Naguib, Michael; Unocic, Raymond R.; Armstrong, Beth L. Dalton Transactions, Vol. 44, Issue 20 https://doi.org/10.1039/C5DT01247C	journal	January 2015
Electrochemical performance of MXenes as K-ion battery anodes Naguib, Michael; Adams, Ryan A.; Zhao, Yunpu Chemical Communications, Vol. 53, Issue 51 https://doi.org/10.1039/C7CC02026K	journal	January 2017
Electronic properties and applications of MXenes: a theoretical review Khazaei, Mohammad; Ranjbar, Ahmad; Arai, Masao Journal of Materials Chemistry C, Vol. 5, Issue 10 https://doi.org/10.1039/C7TC00140A	journal	January 2017
Emergence of high ORR activity through controlling local density-of-states by alloying immiscible Au and Ir Kusada, Kohei; Wu, Dongshuang; Yamamoto, Tomokazu Chemical Science, Vol. 10, Issue 3 https://doi.org/10.1039/C8SC04135K	journal	January 2019
High-throughput theoretical optimization of the hydrogen evolution reaction on MXenes by transition metal modification Li, Pengkun; Zhu, Jinguo; Handoko, Albertus D. Journal of Materials Chemistry A, Vol. 6, Issue 10 https://doi.org/10.1039/C8TA00173A	journal	January 2018
A comparative study on the oxidation of two-dimensional Ti ₃ C ₂ MXene structures in different environments Lotfi, Roghayyeh; Naguib, Michael; Yilmaz, Dundar E. Journal of Materials Chemistry A, Vol. 6, Issue 26 https://doi.org/10.1039/C8TA01468J	journal	January 2018
2D organ-like molybdenum carbide (MXene) coupled with MoS ₂ nanoflowers enhances the catalytic activity in the hydrogen evolution reaction Ren, Jie; Zong, Hui; Sun, Yuyun CrystEngComm, Vol. 22, Issue 8 https://doi.org/10.1039/C9CE01777A	journal	January 2020
Synthesis and compressibility of Ti3(Al,Sn0.2)C2 and Ti3Al(C0.5,N0.5)2 Manoun, Bouchaib; Saxena, S. K.; Hug, Gilles Journal of Applied Physics, Vol. 101, Issue 11 https://doi.org/10.1063/1.2733644	journal	June 2007
Synthesis and Characterization of Ti3AlC2 Tzenov, Nikolay V.; Barsoum, Michel W. Journal of the American Ceramic Society, Vol. 83, Issue 4 https://doi.org/10.1111/j.1151-2916.2000.tb01281.x	journal	April 2000
Identification of Active Edge Sites for Electrochemical H₂ Evolution from MoS₂ Nanocatalysts Jaramillo, T. F.; Jorgensen, K. P.; Bonde, J. Science, Vol. 317, Issue 5834, p. 100-102 https://doi.org/10.1126/science.1141483	journal	July 2007

Similar Records

Two-Dimensional Molybdenum Carbide (MXene) as an Efficient Electrocatalyst for Hydrogen Evolution

Journal Article · 2016 · ACS Energy Letters · OSTI ID:1349401

Seh, Zhi Wei; Fredrickson, Kurt D.; Anasori, Babak; +6 more

Two-dimensional ruthenium boride: a Dirac nodal loop quantum electrocatalyst for efficient hydrogen evolution reaction

Journal Article · 2023 · Journal of Materials Chemistry. A · OSTI ID:2350582

Gao, Zhen; Ma, Fengxian; Wu, Hongbo; +5 more

Mechanisms of Hydrogen Evolution Reaction in Two-Dimensional Nitride MXenes Using In Situ X-Ray Absorption Spectroelectrochemistry

Journal Article · 2021 · ACS Catalysis · OSTI ID:1972246

Djire, Abdoulaye; Zhang, Hanyu; Reinhart, Benjamin J.; +2 more

Title: Two-dimensional titanium carbonitride MXene as a highly efficient electrocatalyst for hydrogen evolution reaction

Citation Formats

References (60)

Similar Records

Related Subjects