Controlling toughness of polymer-grafted nanoparticle composites for impact mitigation

Chen, Shawn H.; Souna, Amanda J.; Stranick, Stephan J.; Jhalaria, Mayank; Kumar, Sanat K.; Soles, Christopher L.; Chan, Edwin P.

doi:10.1039/D1SM01432C

Title: Controlling toughness of polymer-grafted nanoparticle composites for impact mitigation

Journal Article · 05 January 2022 · Soft Matter

DOI: https://doi.org/10.1039/D1SM01432C · OSTI ID:1836841

^[1]; Souna, Amanda J. ^[2]; Stranick, Stephan J. ^[1]; Jhalaria, Mayank ^[3];

^[3]; Soles, Christopher L. ^[2];

^[2]

Materials Measurement Sciences Division, National Institute of Standards and Technology, 100 Bureau Dr, Gaithersburg, MD 20899, USA
Materials Science and Engineering Division, National Institute of Standards and Technology, 100 Bureau Dr, Gaithersburg, MD 20899, USA
Department of Chemical Engineering, Columbia University, 801 SW Mudd, New York, NY 10027, USA

Polymer toughness is typically dictated by the entanglement density. Here we demonstrate a new paradigm via polymer-grafted nanocomposites that couples segmental dynamics with the entanglement concept for enhanced toughness at high deformation rates.

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Sponsoring Organization:: USDOE

Grant/Contract Number:: SC0021272; AC02-06CH11357

OSTI ID:: 1836841

Journal Information:: Soft Matter, Journal Name: Soft Matter Journal Issue: 2 Vol. 18; ISSN SMOABF; ISSN 1744-683X

Publisher:: Royal Society of Chemistry (RSC)Copyright Statement

Country of Publication:: United Kingdom

Language:: English

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