Re-entrance to a ferromagnetic insulator with oxygen-vacancy ordering in the La0.7Sr0.3MnO3/SrTiO3 superlattice
Abstract
The charge-density wave is correlated with the properties in transition metal oxides, and regulating this state is important to explore the potential of oxides. Defects could modulate the local environment, in which the effect is subject to the concentration and arrangement, and an artificial arrangement of defect-ordering is highly expected to design the material properties. In this work, the ordering of oxygen vacancies with a preferred location on the (001) La/SrO plane by self-structural optimization was induced in La0.7Sr0.3MnO3/SrTiO3 superlattices with medium oxygen pressure during SrTiO3 deposition, and then the ferromagnetic charge-ordering (CO)/charge-density-wave (CDW) state was formed in La0.7Sr0.3MnO3 with susceptibility to magnetic field, temperature, and superlattice configuration. In addition, re-entrance to the ferromagnetic insulator CO/CDW could be induced by a high magnetic field. The selective occupancy of oxygen vacancies on the (001) La/SrO plane and the phase fluctuation around the CO/CDW-to-ferromagnetic metal phase transition were critical to the above properties. The interfacial diffusion with atomic-level resolution to control oxygen vacancies could be used in other magnetoelectric systems and corresponding device applications.
- Authors:
-
[1];
[4];
[4];
[3];
- Sun Yat-Sen University, Guangzhou (China)
- Brookhaven National Lab. (BNL), Upton, NY (United States)
- National Univ. of Singapore (Singapore)
- Tianjin Univ. of Technology, Tianjin (China)
- National University of Singapore (Singapore). Singapore Synchrotron Light Source (SSLS)
- Lanzhou Univ. (China)
- Publication Date:
- Research Org.:
- Brookhaven National Lab. (BNL), Upton, NY (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1836807
- Report Number(s):
- BNL-222495-2021-JAAM
Journal ID: ISSN 2050-7488; TRN: US2300378
- Grant/Contract Number:
- SC0012704
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of Materials Chemistry. A
- Additional Journal Information:
- Journal Volume: 9; Journal Issue: 47; Journal ID: ISSN 2050-7488
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY
Citation Formats
Zhang, Bangmin, Wu, Lijun, Feng, Xin, Wang, Dongyang, Chi, Xiao, Chai, Guozhi, Yang, Ping, Ding, Jun, Han, Jiaguang, Chen, Jingsheng, Zhu, Yimei, and Chow, Gan Moog. Re-entrance to a ferromagnetic insulator with oxygen-vacancy ordering in the La0.7Sr0.3MnO3/SrTiO3 superlattice. United States: N. p., 2021.
Web. doi:10.1039/d1ta04137a.
Zhang, Bangmin, Wu, Lijun, Feng, Xin, Wang, Dongyang, Chi, Xiao, Chai, Guozhi, Yang, Ping, Ding, Jun, Han, Jiaguang, Chen, Jingsheng, Zhu, Yimei, & Chow, Gan Moog. Re-entrance to a ferromagnetic insulator with oxygen-vacancy ordering in the La0.7Sr0.3MnO3/SrTiO3 superlattice. United States. https://doi.org/10.1039/d1ta04137a
Zhang, Bangmin, Wu, Lijun, Feng, Xin, Wang, Dongyang, Chi, Xiao, Chai, Guozhi, Yang, Ping, Ding, Jun, Han, Jiaguang, Chen, Jingsheng, Zhu, Yimei, and Chow, Gan Moog. Fri .
"Re-entrance to a ferromagnetic insulator with oxygen-vacancy ordering in the La0.7Sr0.3MnO3/SrTiO3 superlattice". United States. https://doi.org/10.1039/d1ta04137a. https://www.osti.gov/servlets/purl/1836807.
@article{osti_1836807,
title = {Re-entrance to a ferromagnetic insulator with oxygen-vacancy ordering in the La0.7Sr0.3MnO3/SrTiO3 superlattice},
author = {Zhang, Bangmin and Wu, Lijun and Feng, Xin and Wang, Dongyang and Chi, Xiao and Chai, Guozhi and Yang, Ping and Ding, Jun and Han, Jiaguang and Chen, Jingsheng and Zhu, Yimei and Chow, Gan Moog},
abstractNote = {The charge-density wave is correlated with the properties in transition metal oxides, and regulating this state is important to explore the potential of oxides. Defects could modulate the local environment, in which the effect is subject to the concentration and arrangement, and an artificial arrangement of defect-ordering is highly expected to design the material properties. In this work, the ordering of oxygen vacancies with a preferred location on the (001) La/SrO plane by self-structural optimization was induced in La0.7Sr0.3MnO3/SrTiO3 superlattices with medium oxygen pressure during SrTiO3 deposition, and then the ferromagnetic charge-ordering (CO)/charge-density-wave (CDW) state was formed in La0.7Sr0.3MnO3 with susceptibility to magnetic field, temperature, and superlattice configuration. In addition, re-entrance to the ferromagnetic insulator CO/CDW could be induced by a high magnetic field. The selective occupancy of oxygen vacancies on the (001) La/SrO plane and the phase fluctuation around the CO/CDW-to-ferromagnetic metal phase transition were critical to the above properties. The interfacial diffusion with atomic-level resolution to control oxygen vacancies could be used in other magnetoelectric systems and corresponding device applications.},
doi = {10.1039/d1ta04137a},
journal = {Journal of Materials Chemistry. A},
number = 47,
volume = 9,
place = {United States},
year = {Fri Jan 01 00:00:00 EST 2021},
month = {Fri Jan 01 00:00:00 EST 2021}
}
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