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Title: Molecular Design Strategies toward Improvement of Charge Injection and Ionic Conduction in Organic Mixed Ionic–Electronic Conductors for Organic Electrochemical Transistors

Journal Article · · Chemical Reviews
 [1]; ORCiD logo [2]; ORCiD logo [3]
  1. Materials Science and Engineering Department, University of Washington, Seattle, Washington 98195, United States
  2. Department of Chemistry, University of Oxford, Oxford OX1 3TA, United Kingdom
  3. Materials Science and Engineering Department, University of Washington, Seattle, Washington 98195, United States, Department of Chemistry, University of Washington, Seattle, Washington 98195, United States, Molecular Engineering & Sciences Institute, University of Washington, Seattle, Washington 98195, United States

Not Available

Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Grant/Contract Number:
SC0020046
OSTI ID:
1835614
Journal Information:
Chemical Reviews, Journal Name: Chemical Reviews Journal Issue: 4 Vol. 122; ISSN 0009-2665
Publisher:
American Chemical SocietyCopyright Statement
Country of Publication:
United States
Language:
English

References (213)

The Discovery of Polyacetylene Film: The Dawning of an Era of Conducting Polymers (Nobel Lecture) journal July 2001
Highly Sensitive Glucose Biosensors Based on Organic Electrochemical Transistors Using Platinum Gate Electrodes Modified with Enzyme and Nanomaterials journal April 2011
High-Mobility Air-Stable Naphthalene Diimide-Based Copolymer Containing Extended π-Conjugation for n-Channel Organic Field Effect Transistors journal June 2013
Sodium and Potassium Ion Selective Conjugated Polymers for Optical Ion Detection in Solution and Solid State journal December 2015
Supported Lipid Bilayer Assembly on PEDOT:PSS Films and Transistors journal September 2016
Organic Electrodes and Communications with Excitable Cells journal July 2017
The Effects of Crystallinity on Charge Transport and the Structure of Sequentially Processed F 4 TCNQ-Doped Conjugated Polymer Films journal September 2017
Redox-Stability of Alkoxy-BDT Copolymers and their Use for Organic Bioelectronic Devices journal February 2018
X-Ray Scattering Reveals Ion-Induced Microstructural Changes During Electrochemical Gating of Poly(3-Hexylthiophene) journal September 2018
Materials in Organic Electrochemical Transistors for Bioelectronic Applications: Past, Present, and Future journal December 2018
Role of the Anion on the Transport and Structure of Organic Mixed Conductors journal December 2018
Balancing Ionic and Electronic Conduction for High‐Performance Organic Electrochemical Transistors journal January 2020
The Effect of Alkyl Spacers on the Mixed Ionic‐Electronic Conduction Properties of N‐Type Polymers journal January 2021
Polydiketopyrrolopyrroles Carrying Ethylene Glycol Substituents as Efficient Mixed Ion‐Electron Conductors for Biocompatible Organic Electrochemical Transistors journal March 2021
Mixed Conduction in an N‐Type Organic Semiconductor in the Absence of Hydrophilic Side‐Chains journal March 2021
Organic Electrochemical Transistors for Clinical Applications journal September 2014
16-Channel Organic Electrochemical Transistor Array for In Vitro Conduction Mapping of Cardiac Action Potential journal July 2016
Organic Transistor Arrays Integrated with Finger-Powered Microfluidics for Multianalyte Saliva Testing journal July 2016
Poly(alkylenedioxythiophene)s—new, very stable conducting polymers journal February 1992
Rylene and Related Diimides for Organic Electronics journal December 2010
Organic Electrochemical Transistors Integrated in Flexible Microfluidic Systems and Used for Label-Free DNA Sensing journal July 2011
Recent Advances in the Development of Semiconducting DPP-Containing Polymers for Transistor Applications journal September 2012
Electrolyte-Gated Transistors for Organic and Printed Electronics journal December 2012
Direct Measurement of Ion Mobility in a Conducting Polymer journal June 2013
Electrocardiographic Recording with Conformable Organic Electrochemical Transistor Fabricated on Resorbable Bioscaffold journal March 2014
Ion-Selective Organic Electrochemical Transistors journal May 2014
A High Transconductance Accumulation Mode Electrochemical Transistor journal October 2014
Localized Neuron Stimulation with Organic Electrochemical Transistors on Delaminating Depth Probes journal June 2015
Neuromorphic Functions in PEDOT:PSS Organic Electrochemical Transistors journal October 2015
Integration of Organic Electrochemical and Field-Effect Transistors for Ultraflexible, High Temporal Resolution Electrophysiology Arrays journal September 2016
Lactate Detection in Tumor Cell Cultures Using Organic Transistor Circuits journal January 2017
Polar Side Chains Enhance Processability, Electrical Conductivity, and Thermal Stability of a Molecularly p-Doped Polythiophene journal April 2017
Complementary Logic Circuits Based on High-Performance n-Type Organic Electrochemical Transistors journal January 2018
Active Materials for Organic Electrochemical Transistors journal July 2018
Macroscale Biomolecular Electronics and Ionics journal September 2018
Ion Electron–Coupled Functionality in Materials and Devices Based on Conjugated Polymers journal January 2019
Developments of Diketopyrrolopyrrole‐Dye‐Based Organic Semiconductors for a Wide Range of Applications in Electronics journal December 2019
Energetic Control of Redox‐Active Polymers toward Safe Organic Bioelectronic Materials journal March 2020
Bioinspired Ionic Sensory Systems: The Successor of Electronics journal June 2020
Side Chain Redistribution as a Strategy to Boost Organic Electrochemical Transistor Performance and Stability journal August 2020
Time‐Resolved Structural Kinetics of an Organic Mixed Ionic–Electronic Conductor journal August 2020
A Low‐Swelling Polymeric Mixed Conductor Operating in Aqueous Electrolytes journal November 2020
A Decade of Iontronic Delivery Devices journal March 2018
Stability of PEDOT:PSS‐Coated Gold Electrodes in Cell Culture Conditions journal October 2019
Voltage Amplifier Based on Organic Electrochemical Transistor journal September 2016
An Evolvable Organic Electrochemical Transistor for Neuromorphic Applications journal February 2019
Effective Approaches to Improve the Electrical Conductivity of PEDOT:PSS: A Review journal March 2015
Chemiresistive and Chemicapacitive Devices Formed via Morphology Control of Electroconductive Bio-nanocomposites journal December 2017
Enhancing the Electrochemical Doping Efficiency in Diketopyrrolopyrrole‐Based Polymer for Organic Electrochemical Transistors journal November 2020
Batch-to-Batch Variation of Polymeric Photovoltaic Materials: its Origin and Impacts on Charge Carrier Transport and Device Performances journal July 2014
Polaron Delocalization in Donor–Acceptor Polymers and its Impact on Organic Electrochemical Transistor Performance journal February 2021
Printable Bioelectronics To Investigate Functional Biological Interfaces journal September 2015
Diketopyrrolopyrrole-based Conjugated Polymers Bearing Branched Oligo(Ethylene Glycol) Side Chains for Photovoltaic Devices journal June 2016
n ‐Type Rigid Semiconducting Polymers Bearing Oligo(Ethylene Glycol) Side Chains for High‐Performance Organic Electrochemical Transistors journal March 2021
Multimodality imaging‐guided local injection of eccentric magnetic microcapsules with electromagnetically controlled drug release journal December 2018
Glycolated Thiophene‐Tetrafluorophenylene Copolymers for Bioelectronic Applications: Synthesis by Direct Heteroarylation Polymerisation journal June 2019
Designing Polymeric Mixed Conductors and Their Application to Electrochemical‐Transistor‐Based Biosensors journal August 2020
Molecular Engineering of the Band Gap of π-Conjugated Systems: Facing Technological Applications journal September 2007
Organic electrochemical transistors based on PEDOT with different anionic polyelectrolyte dopants journal October 2015
Ion Flow Crossing Over a Polyelectrolyte Diode on a Microfluidic Chip journal July 2011
Ionic conduction in the solid state journal January 2006
Polycarbazole-based electrochemical transistor journal March 1998
Diketopyrrolopyrrole: A versatile building block for organic photovoltaic materials journal March 2013
Field-effect transistor with polythiophene thin film journal February 1987
Structural effects in alkyl and alkoxy-substituted polythiophenes journal April 1991
Advances in conductive polymers journal August 1998
Electronic structure of conjugated polymers: consequences of electron–lattice coupling journal October 1999
Influence of thermal treatment on the conductivity and morphology of PEDOT/PSS films journal October 2003
Stability of n-type doped conducting polymers and consequences for polymeric microelectronic devices journal February 1997
Polyaniline and polypyrrole: Where are we headed? journal January 1997
Electrically conductive nanomaterials for cardiac tissue engineering journal April 2019
Conducting polymers for neural interfaces: Challenges in developing an effective long-term implant journal August 2008
The design, fabrication, and applications of flexible biosensing devices journal January 2019
Organic electrochemical transistors in bioelectronic circuits journal October 2021
Stretchable and transparent ionic diode and logic gates journal April 2019
Flexible bioelectronics for physiological signals sensing and disease treatment journal June 2020
A conceptual review on polymer electrolytes and ion transport models journal March 2018
Tailoring PEDOT properties for applications in bioelectronics journal April 2020
Efficiency improvement of fluorescent OLEDs by tuning the working function of PEDOT:PSS using UV–ozone exposure journal May 2010
On the mechanism of conductivity enhancement in poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate) film through solvent treatment journal November 2004
Organic electrochemical transistors for signal amplification in fast scan cyclic voltammetry journal May 2014
Organic Electronics for Point-of-Care Metabolite Monitoring journal January 2018
Conjugated Polymer Zwitterions: Efficient Interlayer Materials in Organic Electronics journal October 2016
Molecular Approach to Conjugated Polymers with Biomimetic Properties journal June 2018
Conjugated Polymers in Bioelectronics journal May 2018
The Role of the Side Chain on the Performance of N-type Conjugated Polymers in Aqueous Electrolytes journal April 2018
Every Atom Counts: Elucidating the Fundamental Impact of Structural Change in Conjugated Polymers for Organic Photovoltaics journal April 2018
Anion-Dependent Doping and Charge Transport in Organic Electrochemical Transistors journal July 2018
Influence of Water on the Performance of Organic Electrochemical Transistors journal January 2019
Influence of Side-Chain Chemistry on Structure and Ionic Conduction Characteristics of Polythiophene Derivatives: A Computational and Experimental Study journal February 2019
High-Performance Organic Electrochemical Transistors Based on Conjugated Polyelectrolyte Copolymers journal June 2019
Hybrid Alkyl–Ethylene Glycol Side Chains Enhance Substrate Adhesion and Operational Stability in Accumulation Mode Organic Electrochemical Transistors journal November 2019
Organic Bioelectronics: Bridging the Signaling Gap between Biology and Technology journal July 2016
Molecular Dynamics Study of Morphology of Doped PEDOT: From Solution to Dry Phase journal April 2017
Replacing Alkyl with Oligo(ethylene glycol) as Side Chains of Conjugated Polymers for Close π–π Stacking journal June 2015
Influence of Side Chains on the n-Type Organic Electrochemical Transistor Performance journal January 2021
All Polymer Solution Processed Electrochromic Devices: A Future without Indium Tin Oxide? journal September 2018
The Key Role of Side Chain Linkage in Structure Formation and Mixed Conduction of Ethylene Glycol Substituted Polythiophenes journal February 2020
Enhanced n-Doping Efficiency of a Naphthalenediimide-Based Copolymer through Polar Side Chains for Organic Thermoelectrics journal January 2018
100th Anniversary of Macromolecular Science Viewpoint: Recent Advances and Opportunities for Mixed Ion and Charge Conducting Polymers journal April 2020
Carboxylic Acid Functionalization Yields Solvent-Resistant Organic Electrochemical Transistors journal October 2019
P-Type Electrochemical Doping Can Occur by Cation Expulsion in a High-Performing Polymer for Organic Electrochemical Transistors journal February 2020
Recent Electrochemical/Electrical Microfabricated Sensor Devices for Ionic and Polyionic Analytes journal March 2020
π-Conjugated Polymers for Organic Electronics and Photovoltaic Cell Applications journal February 2011
Roles of Flexible Chains in Organic Semiconducting Materials journal July 2013
Side Chain Engineering in Solution-Processable Conjugated Polymers journal September 2013
The Rise of Organic Bioelectronics journal September 2013
Isoindigo, a Versatile Electron-Deficient Unit For High-Performance Organic Electronics journal September 2013
Advances in Charge Carrier Mobilities of Semiconducting Polymers Used in Organic Transistors journal September 2013
Charge Transport in Organic Semiconductors journal April 2007
Semiconducting π-Conjugated Systems in Field-Effect Transistors: A Material Odyssey of Organic Electronics journal November 2011
Synthesis of Conjugated Polymers for Organic Solar Cell Applications journal November 2009
Synthetic Principles for Bandgap Control in Linear π-Conjugated Systems journal February 1997
Ion transport in polypyrrole and a polypyrrole/polyanion composite journal May 1993
Resistance of polyaniline films as a function of electrochemical potential and the fabrication of polyaniline-based microelectronic devices journal April 1985
Poly(3-methylthiophene)-coated electrodes: optical and electrical properties as a function of redox potential and amplification of electrical and chemical signals using poly(3-methylthiophene)-based microelectrochemical transistors journal November 1985
Chemical derivatization of an array of three gold microelectrodes with polypyrrole: fabrication of a molecule-based transistor journal September 1984
Chemical derivatization of microelectrode arrays by oxidation of pyrrole and N-methylpyrrole: fabrication of molecule-based electronic devices journal November 1984
High Electron Mobility in Ladder Polymer Field-Effect Transistors journal November 2003
Tuning Orbital Energetics in Arylene Diimide Semiconductors. Materials Design for Ambient Stability of n-Type Charge Transport journal December 2007
Naphthalenedicarboximide- vs Perylenedicarboximide-Based Copolymers. Synthesis and Semiconducting Properties in Bottom-Gate N-Channel Organic Transistors journal January 2009
The Critical Role of Dopant Cations in Electrical Conductivity and Thermoelectric Performance of n-Doped Polymers journal August 2020
Side-Chain-Induced Rigid Backbone Organization of Polymer Semiconductors through Semifluoroalkyl Side Chains journal January 2016
Molecular Design of Semiconducting Polymers for High-Performance Organic Electrochemical Transistors journal August 2016
A Reversible Structural Phase Transition by Electrochemically-Driven Ion Injection into a Conjugated Polymer journal March 2020
Dependence of Conductivity on Charge Density and Electrochemical Potential in Polymer Semiconductors Gated with Ionic Liquids journal January 2012
Electronic and Vibrational Spectra of Positive Polarons and Bipolarons in Regioregular Poly(3-hexylthiophene) Doped with Ferric Chloride journal March 2015
Low-Band-Gap Polymers That Utilize Quinoid Resonance Structure Stabilization by Thienothiophene: Fine-Tuning of HOMO Level journal January 2011
How Does Nanoscale Crystalline Structure Affect Ion Transport in Solid Polymer Electrolytes? journal June 2014
Direct (Hetero)arylation Polymerization: An Effective Route to 3,4-Propylenedioxythiophene-Based Polymers with Low Residual Metal Content journal September 2013
Nanoscale Memristor Device as Synapse in Neuromorphic Systems journal April 2010
Two-dimensional charge transport in self-organized, high-mobility conjugated polymers journal October 1999
Organic electrochemical transistors journal January 2018
General observation of n-type field-effect behaviour in organic semiconductors journal March 2005
Structural control of mixed ionic and electronic transport in conducting polymers journal April 2016
N-type organic electrochemical transistors with stability in water journal October 2016
Ionic thermoelectric gating organic transistors journal January 2017
Neuromorphic device architectures with global connectivity through electrolyte gating journal May 2017
Hopping transport and the Hall effect near the insulator–metal transition in electrochemically gated poly(3-hexylthiophene) transistors journal January 2012
In vivo recordings of brain activity using organic transistors journal March 2013
High transconductance organic electrochemical transistors journal July 2013
Liquid-crystalline semiconducting polymers with high charge-carrier mobility journal March 2006
Complex thermoelectric materials journal February 2008
The targeted delivery of multicomponent cargos to cancer cells by nanoporous particle-supported lipid bilayers journal April 2011
A general relationship between disorder, aggregation and charge transport in conjugated polymers journal August 2013
2D coherent charge transport in highly ordered conducting polymers doped by solid state diffusion journal May 2016
A non-volatile organic electrochemical device as a low-voltage artificial synapse for neuromorphic computing journal February 2017
Electrochemical strain microscopy probes morphology-induced variations in ion uptake and performance in organic electrochemical transistors journal June 2017
Multi-electrode array technologies for neuroscience and cardiology journal February 2013
π-Conjugated polymer nanowires: advances and perspectives toward effective commercial implementation journal May 2018
Benchmarking organic mixed conductors for transistors journal November 2017
Water stable molecular n-doping produces organic electrochemical transistors with high transconductance and record stability journal June 2020
Wireless organic electronic ion pumps driven by photovoltaics journal July 2019
Rapid single-molecule detection of COVID-19 and MERS antigens via nanobody-functionalized organic electrochemical transistors journal May 2021
Organic mixed ionic–electronic conductors journal August 2019
Ionic Circuits Powered by Reverse Electrodialysis for an Ultimate Iontronic System journal October 2017
Air and temperature sensitivity of n-type polymer materials to meet and exceed the standard of N2200 journal March 2020
A Disposable paper breathalyzer with an alcohol sensing organic electrochemical transistor journal June 2016
Selective detection of dopamine with an all PEDOT:PSS Organic Electrochemical Transistor journal October 2016
Donor–acceptor type low band gap polymers: polysquaraines and related systems journal January 2003
Electrochemical bandgaps of substituted polythiophenes journal January 2003
Enzymatic sensing with organic electrochemical transistors journal January 2008
Conjugated polymers based on naphthalene diimide for organic electronics journal January 2014
Poly(ethylene oxide)-based electrolytes for lithium-ion batteries journal January 2015
Monitoring of cell layer coverage and differentiation with the organic electrochemical transistor journal January 2015
Polyaniline nanofibers: broadening applications for conducting polymers journal January 2017
Synthesis of oligoarylacetylenes with defined conjugated sequences using tailor-made soluble polymer supports journal January 2017
Critical review of the molecular design progress in non-fullerene electron acceptors towards commercially viable organic solar cells journal January 2019
Highly stable and conductive PEDOT:PSS/graphene nanocomposites for biosensor applications in aqueous medium journal January 2017
Fully conjugated ladder polymers journal January 2017
Recent progress in the development of n-type organic semiconductors for organic field effect transistors journal January 2017
Design and evaluation of conjugated polymers with polar side chains as electrode materials for electrochemical energy storage in aqueous electrolytes journal January 2019
Morphological effects on polymeric mixed ionic/electronic conductors journal January 2019
Ionic-to-electronic coupling efficiency in PEDOT:PSS films operated in aqueous electrolytes journal January 2018
n-Type organic electrochemical transistors: materials and challenges journal January 2018
The damaging effects of the acidity in PEDOT:PSS on semiconductor device performance and solutions based on non-acidic alternatives journal January 2020
An adaptive ionic skin with multiple stimulus responses and moist-electric generation ability journal January 2020
Monitoring supported lipid bilayers with n-type organic electrochemical transistors journal January 2020
n-Type organic semiconducting polymers: stability limitations, design considerations and applications journal January 2021
Charge transport in a regioregular poly(3-octylthiophene) film journal January 2000
Spectroelectrochemistry: the best of two worlds journal January 2009
n-Channel polymer thin film transistors with long-term air-stability and durability and their use in complementary inverters journal January 2011
Towards polymer-based organic thermoelectric generators journal January 2012
New opportunities for organic electronics and bioelectronics: ions in action journal January 2013
Effect of molecular weight of additives on the conductivity of PEDOT:PSS and efficiency for ITO-free organic solar cells journal January 2013
Determination of the electronic conductivity of polybithiophene films at different doping levels using in situ electrochemical impedance measurements journal September 2003
Increasing the work function of poly(3,4-ethylenedioxythiophene) doped with poly(4-styrenesulfonate) by ultraviolet irradiation journal August 2007
A sensor circuit using reference-based conductance switching in organic electrochemical transistors journal November 2008
Influence of disorder on transfer characteristics of organic electrochemical transistors journal July 2017
Tutorial: Organic field-effect transistors: Materials, structure and operation journal August 2018
Bioelectronic neural pixel: Chemical stimulation and electrical sensing at the same site journal August 2016
Controlling the mode of operation of organic transistors through side-chain engineering journal October 2016
Solid polymer electrolytes: materials designing and all-solid-state battery applications: an overview journal October 2008
Label free urea biosensor based on organic electrochemical transistors journal June 2018
Large-area printed organic electronic ion pumps journal April 2019
Relative importance of polaron activation and disorder on charge transport in high-mobility conjugated polymer field-effect transistors journal November 2007
High-performance transistors for bioelectronics through tuning of channel thickness journal May 2015
Organic core-sheath nanowire artificial synapses with femtojoule energy consumption journal June 2016
Direct metabolite detection with an n-type accumulation mode organic electrochemical transistor journal June 2018
Origin and hysteresis of lithium compositional spatiodynamics within battery primary particles journal August 2016
How conducting polymer electrodes operate journal April 2019
Materials Strategies for Organic Neuromorphic Devices journal July 2021
Factors Affecting Acid-Base Stability of the Interface Between Polyaniline Emeraldine Salt and Oxide Covered Metal journal January 2005
Stability of Conducting Polythiophene and Derivatives journal October 1983
Effect of Anion Size on Conductivity and Transference Number of Perfluoroether Electrolytes with Lithium Salts journal January 2017
Pedot book January 2010
Organic electrochemical transistors as impedance biosensors journal December 2014
Emulating homeoplasticity phenomena with organic electrochemical devices journal April 2018
Organic neuromorphic devices: Past, present, and future challenges journal August 2020
Synthesis of Poly(3-hexylthiophene)-b-poly(ethylene oxide) for Application to Photovoltaic Device journal January 2010
Fabrication and Use of Organic Electrochemical Transistors for Sensing of Metabolites in Aqueous Media journal June 2018
Organic Bioelectronic Tools for Biomedical Applications journal November 2015
Organic Bioelectronics: Materials and Biocompatibility journal August 2018