Title: Activation of dislocations in Mg with solute Y

Journal Article · · Journal of Magnesium and Alloys

Mg-Y cast alloy shows excellent ductility (elongation to failure > 15%) compared with pure Mg and commercial Mg cast alloys. By monitoring the microstructure evolution during an in situ tensile test of a Mg-2.5 wt%Y alloy, we identify the activation of prismatic slip, which is rare in Mg. Synchrotron X-ray micro-beam Laue diffraction (μ-Laue) and transmission electron microscopy revealed the morphology of prismatic slip bands and individual dislocations. Density functional theory and molecular dynamics calculations indicate that solute Y can significantly reduce the stacking fault energy (SFE) along direction on prismatic plane in Mg lattice and thus facilitate the nucleation of dislocations during deformation. The presence of free dislocations in the Mg lattice can also lead to nucleation of {10–12} twins even under unfavorable geometric conditions.

Research Organization:
Argonne National Laboratory (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
Sponsoring Organization:
National Natural Science Foundation of China (NSFC); USDOE Office of Science (SC), Basic Energy Sciences (BES)
Grant/Contract Number:
AC02-06CH11357
OSTI ID:
1835179
Journal Information:
Journal of Magnesium and Alloys, Journal Name: Journal of Magnesium and Alloys Journal Issue: 3 Vol. 12; ISSN 2213-9567
Publisher:
National Engineering Research Center for Magnesium Alloys of ChinaCopyright Statement
Country of Publication:
United States
Language:
English

References (44)

Microstructure, Deformation, and Property of Wrought Magnesium Alloys journal October 2020
Microstructural characterization of polycrystalline materials by synchrotron X-rays journal May 2013
Deformation twinning journal January 1995
On the role of non-basal deformation mechanisms for the ductility of Mg and Mg–Y alloys journal January 2011
Prediction of thermal cross-slip stress in magnesium alloys from direct first-principles data journal August 2011
Ductility improvement of Mg alloys by solid solution: Ab initio modeling, synthesis and mechanical properties journal May 2014
The effect of high yttrium solute concentration on the twinning behaviour of magnesium alloys journal January 2015
Yield symmetry and reduced strength differential in Mg-2.5Y alloy journal November 2016
On the origin and behavior of irradiation-induced c-component dislocation loops in magnesium journal June 2017
Origins and dissociation of pyramidal dislocations in magnesium and its alloys journal March 2018
Designing high ductility in magnesium alloys journal June 2019
Modified embedded-atom method interatomic potentials for Mg–X (X=Y, Sn, Ca) binary systems journal March 2015
Improving ductility of a Mg alloy via non-basal slip induced by Ca addition journal September 2019
Tension-compression asymmetry and the underlying slip/twinning activity in extruded Mg–Y sheets journal January 2021
Investigation of the alloying effect on deformation behavior in Mg by Visco-Plastic Self-Consistent modeling journal March 2020
Enhancing the strain hardening and ductility of Mg-Y alloy by introducing stacking faults journal December 2020
Recent developments and applications on high-performance cast magnesium rare-earth alloys journal January 2021
Effect of 1Al addition on deformation behavior of Mg journal March 2021
The role of Ca, Al and Zn on room temperature ductility and grain boundary cohesion of magnesium journal September 2021
Basal-plane stacking-fault energies of Mg alloys: A first-principles study of metallic alloying effects journal October 2018
Grain-scale deformation in a Mg−0.8 wt% Y alloy using crystal plasticity finite element method journal October 2019
Study of the dislocation activity in a Mg–Y alloy by differential aperture X-ray microscopy journal October 2019
Microcompression of single-crystal magnesium journal April 2010
First-principles core structures of edge and screw dislocations in Mg journal March 2014
Role of yttrium in activation of 〈 c + a 〉 slip in magnesium: An atomistic approach journal November 2015
Pyramidal I slip in c-axis compressed Mg single crystals journal February 2016
Core structures and mobility of ⟨c⟩ dislocations in magnesium journal July 2017
Observation of non-basal slip in Mg-Y by in situ three-dimensional X-ray diffraction journal January 2018
Three-dimensional X-ray structural microscopy with submicrometre resolution journal February 2002
The origins of high hardening and low ductility in magnesium journal September 2015
Effect of solute atoms on dislocation motion in Mg: An electronic structure perspective journal March 2015
Improved tangent estimate in the nudged elastic band method for finding minimum energy paths and saddle points journal December 2000
Quantitative microdiffraction from deformed crystals with unpaired dislocations and dislocation walls journal February 2003
Reducing deformation anisotropy to achieve ultrahigh strength and ductility in Mg at the nanoscale journal July 2013
TEM study on relationship between stacking faults and non-basal dislocations in Mg journal October 2015
Analysis of dissociation of 〈 c 〉 and 〈 c + a 〉 dislocations to nucleate $(1\,0\,\bar{1}\,2)$ twins in Mg journal May 2013
Accurate and simple analytic representation of the electron-gas correlation energy journal June 1992
Projector augmented-wave method journal December 1994
Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set journal October 1996
From ultrasoft pseudopotentials to the projector augmented-wave method journal January 1999
The Race to X-ray Microbeam and Nanobeam Science journal December 2011
Mechanistic origin and prediction of enhanced ductility in magnesium alloys journal January 2018
Large plasticity in magnesium mediated by pyramidal dislocations journal July 2019
Revealing deformation mechanisms in Mg–Y alloy by in situ deformation of nano-pillars with mediated lateral stiffness journal May 2019