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Title: Near total reflection x-ray photoelectron spectroscopy: quantifying chemistry at solid/liquid and solid/solid interfaces

Abstract

Near total reflection regime has been widely used in x-ray science, specifically in grazing incidence small angle x-ray scattering and in hard x-ray photoelectron spectroscopy (XPS). In this work, we introduce some practical aspects of using near total reflection (NTR) in ambient pressure XPS and apply this technique to study chemical concentration gradients in a substrate/photoresist system. Experimental data are accompanied by x-ray optical and photoemission simulations to quantitatively probe the photoresist and the interface with the depth accuracy of ~1 nm. Together, our calculations and experiments confirm that NTR XPS is a suitable method to extract information from buried interfaces with highest depth-resolution, which can help address open research questions regarding our understanding of concentration profiles, electrical gradients, and charge transfer phenomena at such interfaces. Furthermore, the presented methodology is especially attractive for solid/liquid interface studies, since it provides all the strengths of a Bragg-reflection standing-wave spectroscopy without the need of an artificial multilayer mirror serving as a standing wave generator, thus dramatically simplifying the sample synthesis.

Authors:
ORCiD logo [1]; ORCiD logo [2];  [3]; ORCiD logo [3]; ORCiD logo [3];  [3];  [3]; ORCiD logo [4]; ORCiD logo [5];  [3]; ORCiD logo [6]; ORCiD logo [3]
  1. Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Carnegie Mellon Univ., Pittsburgh, PA (United States)
  2. Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Univ. of California, Davis, CA (United States)
  3. Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
  4. Univ. of California, Davis, CA (United States)
  5. Univ. of Twente (The Netherlands)
  6. Univ. of California, Davis, CA (United States); Forschungszentrum Juelich (Germany)
Publication Date:
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Univ. of California, Davis, CA (United States)
Sponsoring Org.:
USDOE Office of Science (SC)
OSTI Identifier:
1834590
Alternate Identifier(s):
OSTI ID: 1866267
Grant/Contract Number:  
AC02-05CH11231; SC0014697
Resource Type:
Accepted Manuscript
Journal Name:
Journal of Physics. D, Applied Physics
Additional Journal Information:
Journal Volume: 54; Journal Issue: 46; Journal ID: ISSN 0022-3727
Publisher:
IOP Publishing
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; X-ray photoelectron spectroscopy; near total reflection; solid/liquid interface; solid/solid interface; photoresist

Citation Formats

Martins, H. P., Conti, G., Cordova, I., Falling, L., Kersell, H., Salmassi, F., Gullikson, E., Vishik, I., Baeumer, C., Naulleau, P., Schneider, C. M., and Nemsak, S. Near total reflection x-ray photoelectron spectroscopy: quantifying chemistry at solid/liquid and solid/solid interfaces. United States: N. p., 2021. Web. doi:10.1088/1361-6463/ac2067.
Martins, H. P., Conti, G., Cordova, I., Falling, L., Kersell, H., Salmassi, F., Gullikson, E., Vishik, I., Baeumer, C., Naulleau, P., Schneider, C. M., & Nemsak, S. Near total reflection x-ray photoelectron spectroscopy: quantifying chemistry at solid/liquid and solid/solid interfaces. United States. https://doi.org/10.1088/1361-6463/ac2067
Martins, H. P., Conti, G., Cordova, I., Falling, L., Kersell, H., Salmassi, F., Gullikson, E., Vishik, I., Baeumer, C., Naulleau, P., Schneider, C. M., and Nemsak, S. Wed . "Near total reflection x-ray photoelectron spectroscopy: quantifying chemistry at solid/liquid and solid/solid interfaces". United States. https://doi.org/10.1088/1361-6463/ac2067. https://www.osti.gov/servlets/purl/1834590.
@article{osti_1834590,
title = {Near total reflection x-ray photoelectron spectroscopy: quantifying chemistry at solid/liquid and solid/solid interfaces},
author = {Martins, H. P. and Conti, G. and Cordova, I. and Falling, L. and Kersell, H. and Salmassi, F. and Gullikson, E. and Vishik, I. and Baeumer, C. and Naulleau, P. and Schneider, C. M. and Nemsak, S.},
abstractNote = {Near total reflection regime has been widely used in x-ray science, specifically in grazing incidence small angle x-ray scattering and in hard x-ray photoelectron spectroscopy (XPS). In this work, we introduce some practical aspects of using near total reflection (NTR) in ambient pressure XPS and apply this technique to study chemical concentration gradients in a substrate/photoresist system. Experimental data are accompanied by x-ray optical and photoemission simulations to quantitatively probe the photoresist and the interface with the depth accuracy of ~1 nm. Together, our calculations and experiments confirm that NTR XPS is a suitable method to extract information from buried interfaces with highest depth-resolution, which can help address open research questions regarding our understanding of concentration profiles, electrical gradients, and charge transfer phenomena at such interfaces. Furthermore, the presented methodology is especially attractive for solid/liquid interface studies, since it provides all the strengths of a Bragg-reflection standing-wave spectroscopy without the need of an artificial multilayer mirror serving as a standing wave generator, thus dramatically simplifying the sample synthesis.},
doi = {10.1088/1361-6463/ac2067},
journal = {Journal of Physics. D, Applied Physics},
number = 46,
volume = 54,
place = {United States},
year = {Wed Sep 08 00:00:00 EDT 2021},
month = {Wed Sep 08 00:00:00 EDT 2021}
}

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