Magnetothermal properties of Ho1-xDyxAl2 (x = 0, 0.05, 0.10, 0.15, 0.25 and 0.50) compounds

Ribeiro, P. O.; Alho, B. P.; Oliveira, R.S. De; Nóbrega, E. P.; de Sousa, V. S.R.; von Ranke, P. J.; Biswas, Anis; Khan, Mahmud; Mudryk, Y.; Pecharsky, V. K.

doi:10.1016/j.jmmm.2021.168705

Title: Magnetothermal properties of Ho_1-xDy_xAl₂ (x = 0, 0.05, 0.10, 0.15, 0.25 and 0.50) compounds

Journal Article · 14 February 2022 · Journal of Magnetism and Magnetic Materials

DOI: https://doi.org/10.1016/j.jmmm.2021.168705 · OSTI ID:1833545

Ribeiro, P. O. ^[1]; Alho, B. P. ^[2]; Oliveira, R.S. De ^[3]; Nóbrega, E. P. ^[3]; de Sousa, V. S.R. ^[3]; von Ranke, P. J. ^[3]; Biswas, Anis ^[4]; Khan, Mahmud ^[5]; Mudryk, Y. ^[4]; Pecharsky, V. K. ^[4]

Universidade do Estado do Rio de Janeiro (Brazil); Ames Lab., Ames, IA (United States)
Iowa State Univ., Ames, IA (United States); Universidade do Estado do Rio de Janeiro (Brazil)
Universidade do Estado do Rio de Janeiro (Brazil)
Ames Lab., and Iowa State Univ., Ames, IA (United States)
Miami Univ., Oxford, OH (United States)

Magnetic and magnetocaloric properties of ${H o}_{1 - x} {D y}_{x} {A l}_{2}$ compounds with $x = 0, 0.05, 0.10, 0.15, 0.25$ and $0.50$ , modelled using a Hamiltonian that includes the exchange interactions between Ho-Dy, Ho-Ho and Dy-Dy ions in addition to the crystalline electric field and the Zeeman effects, have been compared with those determined experimentally. In order to reproduce experimentally observed global ferromagnetic ordering temperatures and spin reorientation transition temperatures as x_Dy varies, the exchange interactions between Ho-Dy and Ho-Ho were set as free parameters and adjusted to match the experimental results. We demonstrate that heat capacity of polycrystalline materials in non-zero magnetic fields can be satisfactory reproduced by using the average of multiple magnetic field directions with respect to the crystallographic coordinate system, while reasonably good agreement between experimentally determined and theoretically predicted magnetocaloric effects can be achieved considering an average of only three field directions.

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Research Organization:: Ames Laboratory (AMES), Ames, IA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-07CH11358

OSTI ID:: 1833545

Report Number(s):: IS-J--10,648; DE-AC02-07CH11358

Journal Information:: Journal of Magnetism and Magnetic Materials, Journal Name: Journal of Magnetism and Magnetic Materials Vol. 544; ISSN 0304-8853

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

References (38)

The raising of angular momentum degeneracy of f-Electron terms by cubic crystal fields Lea, K. R.; Leask, M. J. M.; Wolf, W. P. Journal of Physics and Chemistry of Solids, Vol. 23, Issue 10 https://doi.org/10.1016/0022-3697(62)90192-0	journal	October 1962
Crystal field effects on the magnetocrystalline anisotropy in HoAl2 Sankar, S. G.; Malik, S. K.; Rao, V. U. S. Journal of Solid State Chemistry, Vol. 18, Issue 3 https://doi.org/10.1016/0022-4596(76)90110-9	journal	July 1976
Point-Charge Calculations of Energy Levels of Magnetic Ions in Crystalline Electric Fields Hutchings, Michael T. Solid State Physics https://doi.org/10.1016/S0081-1947(08)60517-2	book	January 1964
Magnetocaloric and barocaloric effects of metal complexes for solid state cooling: Review, trends and perspectives Reis, Mario S. Coordination Chemistry Reviews, Vol. 417 https://doi.org/10.1016/j.ccr.2020.213357	journal	August 2020
Magnetic refrigerator for hydrogen liquefaction Numazawa, T.; Kamiya, K.; Utaki, T. Cryogenics, Vol. 62 https://doi.org/10.1016/j.cryogenics.2014.03.016	journal	July 2014
Development of the active magnetic regenerative refrigerator operating between 77 K and 20 K with the conduction cooled high temperature superconducting magnet Park, Inmyong; Jeong, Sangkwon Cryogenics, Vol. 88 https://doi.org/10.1016/j.cryogenics.2017.09.008	journal	December 2017
Air conditioning and electricity expenditure: The role of climate in temperate countries Randazzo, Teresa; De Cian, Enrica; Mistry, Malcolm N. Economic Modelling, Vol. 90 https://doi.org/10.1016/j.econmod.2020.05.001	journal	August 2020
CaloriSMART: Small-scale test-stand for rapid evaluation of active magnetic regenerator performance Griffith, Lucas; Czernuszewicz, Agata; Slaughter, Julie Energy Conversion and Management, Vol. 199 https://doi.org/10.1016/j.enconman.2019.111948	journal	November 2019
Magnetocaloric effect in Gd(1−y)DyyAl2 Alho, B. P.; Ribeiro, P. O.; Alvarenga, T. S. T. International Journal of Refrigeration, Vol. 37 https://doi.org/10.1016/j.ijrefrig.2013.07.012	journal	January 2014
Theoretical investigations on the magnetocaloric and barocaloric effects in TbyGd(1−y)Al2 series Ribeiro, P. O.; Alho, B. P.; Alvarenga, T. S. T. Journal of Alloys and Compounds, Vol. 563 https://doi.org/10.1016/j.jallcom.2013.02.068	journal	June 2013
Spin reorientations and crystal field modification in Ho 1−y Gd y Al 2 compounds de Sousa, V. S. R.; Silva, L. E. L.; Gomes, A. M. Journal of Alloys and Compounds, Vol. 686 https://doi.org/10.1016/j.jallcom.2016.06.036	journal	November 2016
Recent progresses in exploring the rare earth based intermetallic compounds for cryogenic magnetic refrigeration Li, Lingwei; Yan, Mi Journal of Alloys and Compounds, Vol. 823 https://doi.org/10.1016/j.jallcom.2020.153810	journal	May 2020
Magnetothermal properties of T m x D y 1 − x A l 2 ( x = 0.25, 0.50 and 0.75) Ribeiro, P. O.; Alho, B. P.; de Oliveira, R. S. Journal of Alloys and Compounds, Vol. 858 https://doi.org/10.1016/j.jallcom.2020.157682	journal	March 2021
Magnetocaloric effect in the Laves phase pseudobinaries ( and Ho) de Oliveira, N. A.; von Ranke, P. J. Journal of Magnetism and Magnetic Materials, Vol. 320, Issue 3-4 https://doi.org/10.1016/j.jmmm.2007.06.014	journal	February 2008
A discussion on the magnetization calculation in polycrystalline antiferromagnetic system: Application to EuTiO3 Alho, B. P.; Carvalho, A. Magnus G.; von Ranke, P. J. Journal of Magnetism and Magnetic Materials, Vol. 324, Issue 2 https://doi.org/10.1016/j.jmmm.2011.08.014	journal	January 2012
Theoretical investigations on magnetocaloric effect in Er1−Tb Al2 series Ribeiro, P. O.; Alho, B. P.; Alvarenga, T. S. T. Journal of Magnetism and Magnetic Materials, Vol. 379 https://doi.org/10.1016/j.jmmm.2014.12.023	journal	April 2015
Conventional and anisotropic magnetic entropy change in HoAl2 ferromagnetic compound Gil, L. A.; Campoy, J. C. P.; Plaza, E. J. R. Journal of Magnetism and Magnetic Materials, Vol. 409 https://doi.org/10.1016/j.jmmm.2016.02.085	journal	July 2016
The influence of crystalline electrical field on magnetic and magnetocaloric properties in Er1−yTbyAl2 compounds Ribeiro, P. O.; Alho, B. P.; Alvarenga, T. S. T. Journal of Magnetism and Magnetic Materials, Vol. 442 https://doi.org/10.1016/j.jmmm.2017.06.120	journal	November 2017
Influence of magnetic field on a spin-crossover material Ribeiro, P. O.; Alho, B. P.; Ribas, R. M. Journal of Magnetism and Magnetic Materials, Vol. 489 https://doi.org/10.1016/j.jmmm.2019.165340	journal	November 2019
Theoretical aspects of the magnetocaloric effect de Oliveira, N. A.; von Ranke, P. J. Physics Reports, Vol. 489, Issue 4-5 https://doi.org/10.1016/j.physrep.2009.12.006	journal	April 2010
Magnetocaloric effect: From materials research to refrigeration devices Franco, V.; Blázquez, J. S.; Ipus, J. J. Progress in Materials Science, Vol. 93 https://doi.org/10.1016/j.pmatsci.2017.10.005	journal	April 2018
A ferromagnet having no net magnetic moment Adachi, H.; Ino, H. Nature, Vol. 401, Issue 6749 https://doi.org/10.1038/43634	journal	September 1999
Clear signs of global warming will hit poorer countries first Schiermeier, Quirin Nature, Vol. 556, Issue 7702 https://doi.org/10.1038/d41586-018-04854-2	journal	April 2018
Balancing structural distortions via competing 4f and itinerant interactions: a case of polymorphism in magnetocaloric HoCo ₂ Mudryk, Y.; Paudyal, D.; Pathak, A. K. Journal of Materials Chemistry C, Vol. 4, Issue 20 https://doi.org/10.1039/C6TC00867D	journal	January 2016
Anisotropy induced anomalies in Dy _1−x Tb _x Al ₂ Khan, M.; Pathak, A. K.; Mudryk, Y. Journal of Materials Chemistry C, Vol. 5, Issue 4 https://doi.org/10.1039/C6TC05384J	journal	January 2017
Magnetic heat pumping near room temperature Brown, G. V. Journal of Applied Physics, Vol. 47, Issue 8 https://doi.org/10.1063/1.323176	journal	August 1976
Spin reorientation transitions in Ho _1-x Dy _x Al ₂ alloys Khan, Mahmud; Gschneidner, K. A.; Pecharsky, V. K. Journal of Applied Physics, Vol. 110, Issue 10 https://doi.org/10.1063/1.3662949	journal	November 2011
Magnetic refrigeration materials (invited) Gschneidner, K. A.; Pecharsky, V. K. Journal of Applied Physics, Vol. 85, Issue 8 https://doi.org/10.1063/1.369979	journal	April 1999
Magnetic properties of (rare earth)Al ₂ intermetallic compounds Purwins, H. -G.; Leson, A. Advances in Physics, Vol. 39, Issue 4 https://doi.org/10.1080/00018739000101511	journal	August 1990
Matrix Elements and Operator Equivalents Connected with the Magnetic Properties of Rare Earth Ions Stevens, K. W. H. Proceedings of the Physical Society. Section A, Vol. 65, Issue 3 https://doi.org/10.1088/0370-1298/65/3/308	journal	March 1952
Magnetic, magnetocaloric and magnetoresistive properties of cubic Laves phase HoAl ₂ single crystal Patra, M.; Majumdar, S.; Giri, S. Journal of Physics: Condensed Matter, Vol. 26, Issue 4 https://doi.org/10.1088/0953-8984/26/4/046004	journal	January 2014
(Magneto)caloric refrigeration: is there light at the end of the tunnel? Pecharsky, Vitalij K.; Cui, Jun; Johnson, Duane D. Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences, Vol. 374, Issue 2074 https://doi.org/10.1098/rsta.2015.0305	journal	August 2016
First-order ferromagnetic transitions of lanthanide local moments in divalent compounds: An itinerant electron positive feedback mechanism and Fermi surface topological change Mendive-Tapia, Eduardo; Paudyal, Durga; Petit, Leon Physical Review B, Vol. 101, Issue 17 https://doi.org/10.1103/PhysRevB.101.174437	journal	May 2020
Free-energy analysis of the nonhysteretic first-order phase transition of Eu 2 In Alho, B. P.; Ribeiro, P. O.; von Ranke, P. J. Physical Review B, Vol. 102, Issue 13 https://doi.org/10.1103/PhysRevB.102.134425	journal	October 2020
Magnetic properties of disordered Heisenberg binary spin system with long-range exchange Tang, G. X.; Nolting, W. Physical Review B, Vol. 73, Issue 2 https://doi.org/10.1103/PhysRevB.73.024415	journal	January 2006
Magnetic anisotropy of S m 2 F e 17 single crystals Diop, L. V. B.; Kuz'min, M. D.; Skokov, K. P. Physical Review B, Vol. 94, Issue 14 https://doi.org/10.1103/PhysRevB.94.144413	journal	October 2016
Development and the Impact of Climate Change on Energy Demand: Evidence from Brazil Depaula, Guilherme; Mendelsohn, Robert Climate Change Economics, Vol. 01, Issue 03 https://doi.org/10.1142/S2010007810000157	journal	December 2010
Will AC Put a Chill on the Global Energy Supply? Sivak, Michael American Scientist, Vol. 101, Issue 5 https://doi.org/10.1511/2013.104.330	journal	January 2013

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Title: Magnetothermal properties of Ho1-xDyxAl2 (x = 0, 0.05, 0.10, 0.15, 0.25 and 0.50) compounds

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Title: Magnetothermal properties of Ho_1-xDy_xAl₂ (x = 0, 0.05, 0.10, 0.15, 0.25 and 0.50) compounds