Expeditious synthesis of covalent organic frameworks: a review

Li, Xinle; Yang, Chongqing; Sun, Bing; Cai, Songliang; Chen, Ziman; Lv, Yongqin; Zhang, Jian; Liu, Yi

doi:10.1039/d0ta05894g

Title: Expeditious synthesis of covalent organic frameworks: a review

Journal Article · 31 December 2019 · Journal of Materials Chemistry. A

DOI: https://doi.org/10.1039/d0ta05894g · OSTI ID:1832460

Li, Xinle ^[1]; Yang, Chongqing ^[1];

^[2];

^[3]; Chen, Ziman ^[4];

^[4];

^[1];

^[1]

Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
China University of Geosciences, Beijing (China)
South China Normal University, Guangzhou (China)
Beijing University of Chemical Technology (China)

Covalent organic frameworks (COFs), a burgeoning class of crystalline porous materials constructed by covalently connecting organic building blocks, have garnered tremendous attention. The predominant solvothermal synthesis of COFs usually requires high temperature and long reaction times (three days or longer), which creates substantial obstacles for their accelerated discovery and exploration in practical applications. Hence, the expeditious synthesis of COFs without compromising their inherent properties is exceedingly appealing from the viewpoint of cost, time, and energy footprint. To overcome the sluggishness of the synthesis, considerable efforts have been invested in the rapid synthesis of high-quality COFs through innovations in energy source, catalyst, solvent, monomer, nucleation, and workup activation, leading to a drastic reduction of reaction time from multiple days to a few hours, and even to seconds in some cases. In this contribution, we provide a comprehensive overview of the advances in expediting the synthesis science of COFs. Though a nascent effort, six prevalent strategies have been identified for the rapid synthesis of COFs, which have led to intriguing applications in a diverse range of areas including gas adsorption, separation, heterogeneous catalysis, environmental remediation, and photodynamic therapy. We also outline the major challenges and perspectives on the future directions empowered by expeditious COF synthesis.

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Research Organization:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities Division

Grant/Contract Number:: AC02-05CH11231

OSTI ID:: 1832460

Journal Information:: Journal of Materials Chemistry. A, Journal Name: Journal of Materials Chemistry. A Journal Issue: 32 Vol. 8; ISSN 2050-7488

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

References (112)

Rapid Photochemical Synthesis of Sea-Urchin-Shaped Hierarchical Porous COF-5 and Its Lithography-Free Patterned Growth Kim, Soyoung; Park, Chibeom; Lee, Minkyung Advanced Functional Materials, Vol. 27, Issue 32 https://doi.org/10.1002/adfm.201700925	journal	July 2017
Covalent Organic Frameworks: Structures, Synthesis, and Applications Lohse, Maria S.; Bein, Thomas Advanced Functional Materials, Vol. 28, Issue 33 https://doi.org/10.1002/adfm.201705553	journal	July 2018
The Organic Flatland-Recent Advances in Synthetic 2D Organic Layers Cai, Song-Liang; Zhang, Wei-Guang; Zuckermann, Ronald N. Advanced Materials, Vol. 27, Issue 38 https://doi.org/10.1002/adma.201500124	journal	March 2015
Rapid Synthesis of High Surface Area Imine‐Linked 2D Covalent Organic Frameworks by Avoiding Pore Collapse During Isolation Feriante, Cameron H.; Jhulki, Samik; Evans, Austin M. Advanced Materials, Vol. 32, Issue 2 https://doi.org/10.1002/adma.201905776	journal	November 2019
Opportunities of Covalent Organic Frameworks for Advanced Applications Song, Yanpei; Sun, Qi; Aguila, Briana Advanced Science, Vol. 6, Issue 2 https://doi.org/10.1002/advs.201801410	journal	November 2018
Covalent–Organic Frameworks: Advanced Organic Electrode Materials for Rechargeable Batteries Sun, Tao; Xie, Jian; Guo, Wei Advanced Energy Materials, Vol. 10, Issue 19 https://doi.org/10.1002/aenm.201904199	journal	April 2020
Porous, Covalent Triazine-Based Frameworks Prepared by Ionothermal Synthesis Kuhn, Pierre; Antonietti, Markus; Thomas, Arne Angewandte Chemie International Edition, Vol. 47, Issue 18 https://doi.org/10.1002/anie.200705710	journal	April 2008
Manipulation of Amorphous-to-Crystalline Transformation: Towards the Construction of Covalent Organic Framework Hybrid Microspheres with NIR Photothermal Conversion Ability Tan, Jing; Namuangruk, Supawadee; Kong, Weifu Angewandte Chemie International Edition, Vol. 55, Issue 45 https://doi.org/10.1002/anie.201606155	journal	October 2016
Covalent Triazine Frameworks via a Low-Temperature Polycondensation Approach Wang, Kewei; Yang, Li-Ming; Wang, Xi Angewandte Chemie International Edition, Vol. 56, Issue 45 https://doi.org/10.1002/anie.201708548	journal	October 2017
Direct Synthesis of a Covalent Triazine-Based Framework from Aromatic Amides Yu, Soo-Young; Mahmood, Javeed; Noh, Hyuk-Jun Angewandte Chemie International Edition, Vol. 57, Issue 28 https://doi.org/10.1002/anie.201801128	journal	April 2018
Crystalline Covalent Triazine Frameworks by In Situ Oxidation of Alcohols to Aldehyde Monomers Liu, Manying; Huang, Qi; Wang, Shaolei Angewandte Chemie International Edition, Vol. 57, Issue 37 https://doi.org/10.1002/anie.201806664	journal	August 2018
A Novel Strategy for the Construction of Covalent Organic Frameworks from Nonporous Covalent Organic Polymers Miao, Zhuang; Liu, Guiyan; Cui, Yumeng Angewandte Chemie International Edition, Vol. 58, Issue 15 https://doi.org/10.1002/anie.201813999	journal	March 2019
Construction of Covalent‐Organic Frameworks (COFs) from Amorphous Covalent Organic Polymers via Linkage Replacement Zhai, Yufeng; Liu, Guiyan; Jin, Fenchun Angewandte Chemie International Edition, Vol. 58, Issue 49 https://doi.org/10.1002/anie.201911231	journal	December 2019
Irreversible amide‐linked covalent organic framework for selective and ultrafast gold recovery Qian, Hai-Long; Meng, Fan-Lin; Yang, Cheng-Xiong Angewandte Chemie International Edition https://doi.org/10.1002/anie.202006535	journal	June 2020
Direct On-Surface Patterning of a Crystalline Laminar Covalent Organic Framework Synthesized at Room Temperature de la Peña Ruigómez, Alejandro; Rodríguez-San-Miguel, David; Stylianou, Kyriakos C. Chemistry - A European Journal, Vol. 21, Issue 30 https://doi.org/10.1002/chem.201501692	journal	June 2015
Reconstruction of Covalent Organic Frameworks by Dynamic Equilibrium Gao, Qiang; Bai, Linyi; Zeng, Yongfei Chemistry - A European Journal, Vol. 21, Issue 47 https://doi.org/10.1002/chem.201503053	journal	October 2015
One‐Pot Synthesis of DOX@Covalent Organic Framework with Enhanced Chemotherapeutic Efficacy Liu, Sainan; Hu, Chunling; Liu, Ying Chemistry – A European Journal, Vol. 25, Issue 17 https://doi.org/10.1002/chem.201806242	journal	March 2019
Room‐Temperature Synthesis of Covalent Organic Framework (COF‐LZU1) Nanobars in CO ₂ /Water Solvent Zhang, Fanyu; Zhang, Jianling; Zhang, Bingxing ChemSusChem, Vol. 11, Issue 20 https://doi.org/10.1002/cssc.201801712	journal	September 2018
Scalable ambient pressure synthesis of covalent organic frameworks and their colorimetric nanocomposites through dynamic imine exchange reactions Zhao, Wei; Qiao, Jia; Ning, Tian-Li Chinese Journal of Polymer Science, Vol. 36, Issue 1 https://doi.org/10.1007/s10118-018-2010-5	journal	November 2017
Template synthesis of imine-based covalent organic framework core-shell structure and hollow sphere: a case of COFTTA-DHTA Sun, Bing; Wang, Dong; Wan, Lijun Science China Chemistry, Vol. 60, Issue 8 https://doi.org/10.1007/s11426-017-9071-0	journal	July 2017
A green and fast approach to nanoporous carbons with tuned porosity: UV-assisted condensation of organic compounds at room temperature Balan, Lavinia; Fernández de Córdoba, María C.; Zaier, Mohamed Carbon, Vol. 116 https://doi.org/10.1016/j.carbon.2017.01.088	journal	May 2017
Dynamic Covalent Synthesis of Crystalline Porous Graphitic Frameworks Li, Xinle; Wang, Hongxia; Chen, Hao Chem, Vol. 6, Issue 4 https://doi.org/10.1016/j.chempr.2020.01.011	journal	April 2020
BODIPY-Decorated Nanoscale Covalent Organic Frameworks for Photodynamic Therapy Guan, Qun; Fu, Dan-Dan; Li, Yan-An iScience, Vol. 14 https://doi.org/10.1016/j.isci.2019.03.028	journal	April 2019
Rapid microwave synthesis of dioxin-linked covalent organic framework for efficient micro-extraction of perfluorinated alkyl substances from water Ji, Wenhua; Guo, Yu-Shuang; Xie, Hui-Min Journal of Hazardous Materials, Vol. 397 https://doi.org/10.1016/j.jhazmat.2020.122793	journal	October 2020
Microwave synthesis of zeolite membranes: A review Li, Yanshuo; Yang, Weishen Journal of Membrane Science, Vol. 316, Issue 1-2 https://doi.org/10.1016/j.memsci.2007.08.054	journal	May 2008
Synthesis of COF-5 using microwave irradiation and conventional solvothermal routes Ritchie, Lyndsey K.; Trewin, Abbie; Reguera-Galan, Aida Microporous and Mesoporous Materials, Vol. 132, Issue 1-2 https://doi.org/10.1016/j.micromeso.2010.02.010	journal	July 2010
Microwave-assisted synthesis of metal oxide nanostructures for gas sensing application: A review Mirzaei, A.; Neri, G. Sensors and Actuators B: Chemical, Vol. 237 https://doi.org/10.1016/j.snb.2016.06.114	journal	December 2016
Covalent Organic Frameworks: Organic Chemistry Extended into Two and Three Dimensions Lyle, Steven J.; Waller, Peter J.; Yaghi, Omar M. Trends in Chemistry, Vol. 1, Issue 2 https://doi.org/10.1016/j.trechm.2019.03.001	journal	May 2019
Mixed Matrix Membranes (MMMs) Comprising Exfoliated 2D Covalent Organic Frameworks (COFs) for Efficient CO ₂ Separation Kang, Zixi; Peng, Yongwu; Qian, Yuhong Chemistry of Materials, Vol. 28, Issue 5 https://doi.org/10.1021/acs.chemmater.5b02902	journal	February 2016
Nucleation of FAU and LTA Zeolites from Heterogeneous Aluminosilicate Precursors Oleksiak, Matthew D.; Soltis, Jennifer A.; Conato, Marlon T. Chemistry of Materials, Vol. 28, Issue 14 https://doi.org/10.1021/acs.chemmater.6b01000	journal	July 2016
Facile Synthesis of Highly Porous Metal Oxides by Mechanochemical Nanocasting Xiao, Weiming; Yang, Shize; Zhang, Pengfei Chemistry of Materials, Vol. 30, Issue 9 https://doi.org/10.1021/acs.chemmater.7b05405	journal	April 2018
In Situ, Time-Resolved, and Mechanistic Studies of Metal–Organic Framework Nucleation and Growth Van Vleet, Mary J.; Weng, Tingting; Li, Xinyi Chemical Reviews, Vol. 118, Issue 7 https://doi.org/10.1021/acs.chemrev.7b00582	journal	February 2018
Covalent Organic Frameworks: Design, Synthesis, and Functions Geng, Keyu; He, Ting; Liu, Ruoyang Chemical Reviews https://doi.org/10.1021/acs.chemrev.9b00550	journal	January 2020
Preparation of Amidoxime-Based Nylon-66 Fibers for Removing Uranium from Low-Concentration Aqueous Solutions and Simulated Nuclear Industry Effluents Zhang, Mingxing; Gao, Qianhong; Yang, Chenguang Industrial & Engineering Chemistry Research, Vol. 55, Issue 40 https://doi.org/10.1021/acs.iecr.6b02652	journal	September 2016
Reversible Interlayer Sliding and Conductivity Changes in Adaptive Tetrathiafulvalene-Based Covalent Organic Frameworks Cai, Songliang; Sun, Bing; Li, Xinle ACS Applied Materials & Interfaces, Vol. 12, Issue 16 https://doi.org/10.1021/acsami.0c03280	journal	March 2020
Stable Hydrazone-Linked Covalent Organic Frameworks Containing O,N,O′-Chelating Sites for Fe(III) Detection in Water Chen, Gui; Lan, Hai-Hang; Cai, Song-Liang ACS Applied Materials & Interfaces, Vol. 11, Issue 13 https://doi.org/10.1021/acsami.9b02640	journal	March 2019
Covalent Organic Frameworks as a Platform for Multidimensional Polymerization Bisbey, Ryan P.; Dichtel, William R. ACS Central Science, Vol. 3, Issue 6 https://doi.org/10.1021/acscentsci.7b00127	journal	May 2017
PolyCOFs: A New Class of Freestanding Responsive Covalent Organic Framework Membranes with High Mechanical Performance Wang, Zhifang; Yu, Qi; Huang, Yubo ACS Central Science, Vol. 5, Issue 8 https://doi.org/10.1021/acscentsci.9b00212	journal	June 2019
Microwave-Assisted Organic Synthesis and Transformations using Benign Reaction Media Polshettiwar, Vivek; Varma, Rajender S. Accounts of Chemical Research, Vol. 41, Issue 5 https://doi.org/10.1021/ar700238s	journal	May 2008
Photochemical Synthesis of Monodisperse Size-Controlled Silver Decahedral Nanoparticles and Their Remarkable Optical Properties Pietrobon, Brendan; Kitaev, Vladimir Chemistry of Materials, Vol. 20, Issue 16 https://doi.org/10.1021/cm800926u	journal	August 2008
Rapid Microwave Synthesis and Purification of Porous Covalent Organic Frameworks Campbell, Neil L.; Clowes, Rob; Ritchie, Lyndsey K. Chemistry of Materials, Vol. 21, Issue 2 https://doi.org/10.1021/cm802981m	journal	January 2009
Facile Photochemical Synthesis of Unprotected Aqueous Gold Nanoparticles McGilvray, Katherine L.; Decan, Matthew R.; Wang, Dashan Journal of the American Chemical Society, Vol. 128, Issue 50 https://doi.org/10.1021/ja066522h	journal	December 2006
Crystalline Covalent Organic Frameworks with Hydrazone Linkages Uribe-Romo, Fernando J.; Doonan, Christian J.; Furukawa, Hiroyasu Journal of the American Chemical Society, Vol. 133, Issue 30, p. 11478-11481 https://doi.org/10.1021/ja204728y	journal	August 2011
Construction of Covalent Organic Framework for Catalysis: Pd/COF-LZU1 in Suzuki–Miyaura Coupling Reaction Ding, San-Yuan; Gao, Jia; Wang, Qiong Journal of the American Chemical Society, Vol. 133, Issue 49 https://doi.org/10.1021/ja206846p	journal	December 2011
Large-Scale Production of Edge-Selectively Functionalized Graphene Nanoplatelets via Ball Milling and Their Use as Metal-Free Electrocatalysts for Oxygen Reduction Reaction Jeon, In-Yup; Choi, Hyun-Jung; Jung, Sun-Min Journal of the American Chemical Society, Vol. 135, Issue 4 https://doi.org/10.1021/ja3091643	journal	November 2012
Mechanochemical Synthesis of Chemically Stable Isoreticular Covalent Organic Frameworks Biswal, Bishnu P.; Chandra, Suman; Kandambeth, Sharath Journal of the American Chemical Society, Vol. 135, Issue 14 https://doi.org/10.1021/ja4017842	journal	March 2013
Chemically Stable Multilayered Covalent Organic Nanosheets from Covalent Organic Frameworks via Mechanical Delamination Chandra, Suman; Kandambeth, Sharath; Biswal, Bishnu P. Journal of the American Chemical Society, Vol. 135, Issue 47 https://doi.org/10.1021/ja408121p	journal	November 2013
Mechanistic Studies of Two-Dimensional Covalent Organic Frameworks Rapidly Polymerized from Initially Homogenous Conditions Smith, Brian J.; Dichtel, William R. Journal of the American Chemical Society, Vol. 136, Issue 24 https://doi.org/10.1021/ja5037868	journal	June 2014
Supercritical Processing as a Route to High Internal Surface Areas and Permanent Microporosity in Metal−Organic Framework Materials Nelson, Andrew P.; Farha, Omar K.; Mulfort, Karen L. Journal of the American Chemical Society, Vol. 131, Issue 2, p. 458-460 https://doi.org/10.1021/ja808853q	journal	January 2009
Fabricating Covalent Organic Framework Capsules with Commodious Microenvironment for Enzymes Li, Mingmin; Qiao, Shan; Zheng, Yunlong Journal of the American Chemical Society, Vol. 142, Issue 14 https://doi.org/10.1021/jacs.0c00285	journal	March 2020
Transformation Strategy for Highly Crystalline Covalent Triazine Frameworks: From Staggered AB to Eclipsed AA Stacking Yang, Zhenzhen; Chen, Hao; Wang, Song Journal of the American Chemical Society, Vol. 142, Issue 15 https://doi.org/10.1021/jacs.0c00365	journal	March 2020
Rapid, Scalable Construction of Highly Crystalline Acylhydrazone Two-Dimensional Covalent Organic Frameworks via Dipole-Induced Antiparallel Stacking Li, Xing; Qiao, Jingsi; Chee, See Wee Journal of the American Chemical Society, Vol. 142, Issue 10 https://doi.org/10.1021/jacs.0c00553	journal	February 2020
Electron Beam Irradiation as a General Approach for the Rapid Synthesis of Covalent Organic Frameworks under Ambient Conditions Zhang, Mingxing; Chen, Junchang; Zhang, Shitong Journal of the American Chemical Society, Vol. 142, Issue 20 https://doi.org/10.1021/jacs.0c03941	journal	May 2020
Constructing Ultraporous Covalent Organic Frameworks in Seconds via an Organic Terracotta Process Karak, Suvendu; Kandambeth, Sharath; Biswal, Bishnu P. Journal of the American Chemical Society, Vol. 139, Issue 5 https://doi.org/10.1021/jacs.6b08815	journal	January 2017
Rapid, Low Temperature Formation of Imine-Linked Covalent Organic Frameworks Catalyzed by Metal Triflates Matsumoto, Michio; Dasari, Raghunath R.; Ji, Woojung Journal of the American Chemical Society, Vol. 139, Issue 14 https://doi.org/10.1021/jacs.7b01240	journal	March 2017
Viologen-Based Conjugated Covalent Organic Networks via Zincke Reaction Das, Gobinda; Skorjanc, Tina; Sharma, Sudhir Kumar Journal of the American Chemical Society, Vol. 139, Issue 28 https://doi.org/10.1021/jacs.7b02836	journal	July 2017
Solution Synthesis of Semiconducting Two-Dimensional Polymer via Trimerization of Carbonitrile Liu, Jingjing; Zan, Wu; Li, Ke Journal of the American Chemical Society, Vol. 139, Issue 34 https://doi.org/10.1021/jacs.7b05025	journal	July 2017
Synthesis of 2D Imine-Linked Covalent Organic Frameworks through Formal Transimination Reactions Vitaku, Edon; Dichtel, William R. Journal of the American Chemical Society, Vol. 139, Issue 37 https://doi.org/10.1021/jacs.7b06913	journal	September 2017
A Synthetic Route for Crystals of Woven Structures, Uniform Nanocrystals, and Thin Films of Imine Covalent Organic Frameworks Zhao, Yingbo; Guo, Lei; Gándara, Felipe Journal of the American Chemical Society, Vol. 139, Issue 37 https://doi.org/10.1021/jacs.7b07457	journal	September 2017
Nucleation and Growth of Covalent Organic Frameworks from Solution: The Example of COF-5 Li, Haoyuan; Chavez, Anton D.; Li, Huifang Journal of the American Chemical Society, Vol. 139, Issue 45 https://doi.org/10.1021/jacs.7b09169	journal	October 2017
Fast, Ambient Temperature and Pressure Ionothermal Synthesis of Three-Dimensional Covalent Organic Frameworks Guan, Xinyu; Ma, Yunchao; Li, Hui Journal of the American Chemical Society, Vol. 140, Issue 13 https://doi.org/10.1021/jacs.8b01320	journal	March 2018
Crystalline Dioxin-Linked Covalent Organic Frameworks from Irreversible Reactions Zhang, Bing; Wei, Mufeng; Mao, Haiyan Journal of the American Chemical Society, Vol. 140, Issue 40 https://doi.org/10.1021/jacs.8b08374	journal	September 2018
Covalent Organic Frameworks: Chemistry beyond the Structure Kandambeth, Sharath; Dey, Kaushik; Banerjee, Rahul Journal of the American Chemical Society, Vol. 141, Issue 5 https://doi.org/10.1021/jacs.8b10334	journal	November 2018
Guest-Dependent Dynamics in a 3D Covalent Organic Framework Chen, Yichong; Shi, Zhao-Lin; Wei, Lei Journal of the American Chemical Society, Vol. 141, Issue 7 https://doi.org/10.1021/jacs.8b13691	journal	January 2019
Switching on and off Interlayer Correlations and Porosity in 2D Covalent Organic Frameworks Sick, Torben; Rotter, Julian M.; Reuter, Stephan Journal of the American Chemical Society, Vol. 141, Issue 32 https://doi.org/10.1021/jacs.9b02800	journal	June 2019
Two-Dimensional Chemiresistive Covalent Organic Framework with High Intrinsic Conductivity Meng, Zheng; Stolz, Robert M.; Mirica, Katherine A. Journal of the American Chemical Society, Vol. 141, Issue 30 https://doi.org/10.1021/jacs.9b03441	journal	June 2019
De Novo Design and Facile Synthesis of 2D Covalent Organic Frameworks: A Two-in-One Strategy Li, Yusen; Chen, Qing; Xu, Tiantian Journal of the American Chemical Society, Vol. 141, Issue 35 https://doi.org/10.1021/jacs.9b03463	journal	August 2019
Size-Controllable Synthesis of Uniform Spherical Covalent Organic Frameworks at Room Temperature for Highly Efficient and Selective Enrichment of Hydrophobic Peptides Ma, Wende; Zheng, Qiong; He, Yanting Journal of the American Chemical Society, Vol. 141, Issue 45 https://doi.org/10.1021/jacs.9b09189	journal	October 2019
γ-Ray-induced Formation of Gold Sol from Chloroauric Acid Solution Fujita, Hitoshi; Izawa, Masami; Yamazaki, Hideo Nature, Vol. 196, Issue 4855 https://doi.org/10.1038/196666a0	journal	November 1962
Green processing using ionic liquids and CO2 Blanchard, Lynnette A.; Hancu, Dan; Beckman, Eric J. Nature, Vol. 399, Issue 6731 https://doi.org/10.1038/19887	journal	May 1999
Covalent organic frameworks: a materials platform for structural and functional designs Huang, Ning; Wang, Ping; Jiang, Donglin Nature Reviews Materials, Vol. 1, Issue 10 https://doi.org/10.1038/natrevmats.2016.68	journal	September 2016
Stable and ordered amide frameworks synthesised under reversible conditions which facilitate error checking Stewart, David; Antypov, Dmytro; Dyer, Matthew S. Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/s41467-017-01423-5	journal	October 2017
Facile transformation of imine covalent organic frameworks into ultrastable crystalline porous aromatic frameworks Li, Xinle; Zhang, Changlin; Cai, Songliang Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-05462-4	journal	July 2018
Approaches and challenges in the synthesis of three-dimensional covalent-organic frameworks Ma, Xingjian; Scott, Timothy F. Communications Chemistry, Vol. 1, Issue 1 https://doi.org/10.1038/s42004-018-0098-8	journal	December 2018
Atomistics of pre-nucleation layering of liquid metals at the interface with poor nucleants Ma, Sida; Brown, Adam J.; Yan, Rui Communications Chemistry, Vol. 2, Issue 1 https://doi.org/10.1038/s42004-018-0104-1	journal	January 2019
Microwaves in organic synthesis. Thermal and non-thermal microwave effects de la Hoz, Antonio; Díaz-Ortiz, Ángel; Moreno, Andrés Chem. Soc. Rev., Vol. 34, Issue 2 https://doi.org/10.1039/B411438H	journal	January 2005
Microwave-Assisted Synthesis of Metal–Organic Frameworks Klinowski, Jacek; Almeida Paz, Filipe A.; Silva, Patrícia Dalton Trans., Vol. 40, Issue 2 https://doi.org/10.1039/C0DT00708K	journal	January 2011
Sonochemical synthesis of nanomaterials Xu, Hangxun; Zeiger, Brad W.; Suslick, Kenneth S. Chem. Soc. Rev., Vol. 42, Issue 7 https://doi.org/10.1039/C2CS35282F	journal	January 2013
Mechanosynthesis of imine, β-ketoenamine, and hydrogen-bonded imine-linked covalent organic frameworks using liquid-assisted grinding Das, Gobinda; Balaji Shinde, Digambar; Kandambeth, Sharath Chem. Commun., Vol. 50, Issue 84 https://doi.org/10.1039/C4CC03389B	journal	January 2014
Facile room-temperature solution-phase synthesis of a spherical covalent organic framework for high-resolution chromatographic separation Yang, Cheng-Xiong; Liu, Chang; Cao, Yi-Meng Chemical Communications, Vol. 51, Issue 61 https://doi.org/10.1039/C5CC03413B	journal	January 2015
The microwave-assisted solvothermal synthesis of a crystalline two-dimensional covalent organic framework with high CO ₂ capacity Wei, Hao; Chai, Shuangzhi; Hu, Nantao Chemical Communications, Vol. 51, Issue 61 https://doi.org/10.1039/C5CC04680G	journal	January 2015
Insight into the crystallization of amorphous imine-linked polymer networks to 2D covalent organic frameworks Smith, Brian J.; Overholts, Anna C.; Hwang, Nicky Chemical Communications, Vol. 52, Issue 18 https://doi.org/10.1039/C5CC10221A	journal	January 2016
Conversion of amorphous polymer networks to covalent organic frameworks under ionothermal conditions: a facile synthesis route for covalent triazine frameworks Kuecken, Sophie; Schmidt, Johannes; Zhi, Linjie Journal of Materials Chemistry A, Vol. 3, Issue 48 https://doi.org/10.1039/C5TA07408H	journal	January 2015
A mechanochemically synthesized covalent organic framework as a proton-conducting solid electrolyte Shinde, Digambar Balaji; Aiyappa, Harshitha Barike; Bhadra, Mohitosh Journal of Materials Chemistry A, Vol. 4, Issue 7 https://doi.org/10.1039/C5TA10521H	journal	January 2016
Sub-micron spheres of an imine-based covalent organic framework: supramolecular functionalization and water-dispersibility Rodríguez-San-Miguel, David; Corral-Pérez, Juan J.; Gil-González, Eva CrystEngComm, Vol. 19, Issue 33 https://doi.org/10.1039/C6CE02200F	journal	January 2017
Nucleation and growth of 2D covalent organic frameworks: polymerization and crystallization of COF monomers Koo, B. T.; Heden, R. F.; Clancy, P. Physical Chemistry Chemical Physics, Vol. 19, Issue 15 https://doi.org/10.1039/C6CP08449D	journal	January 2017
Covalent organic frameworks (COFs): perspectives of industrialization Zhao, Wei; Xia, Lieyin; Liu, Xikui CrystEngComm, Vol. 20, Issue 12 https://doi.org/10.1039/C7CE02079A	journal	January 2018
Mechanochemical synthesis of porous organic materials Zhang, Pengfei; Dai, Sheng Journal of Materials Chemistry A, Vol. 5, Issue 31 https://doi.org/10.1039/C7TA04829G	journal	January 2017
Orientation transitions during the growth of imine covalent organic framework thin films Wang, H.; He, B.; Liu, F. Journal of Materials Chemistry C, Vol. 5, Issue 21 https://doi.org/10.1039/C7TC01324H	journal	January 2017
Heterogeneous nucleation and growth of highly crystalline imine-linked covalent organic frameworks Yuan, Yu-Chen; Sun, Bing; Cao, An-Min Chemical Communications, Vol. 54, Issue 47 https://doi.org/10.1039/C8CC02381F	journal	January 2018
Amorphous-to-crystalline transformation toward controllable synthesis of fibrous covalent organic frameworks enabling promotion of proton transport Kong, Weifu; Jia, Wei; Wang, Rong Chemical Communications, Vol. 55, Issue 1 https://doi.org/10.1039/C8CC08590K	journal	January 2019
Controlling the crystalline structure of imine-linked 3D covalent organic frameworks Fischbach, Danyon M.; Rhoades, Grace; Espy, Charlie Chemical Communications, Vol. 55, Issue 25 https://doi.org/10.1039/C8CC09571J	journal	January 2019
Covalent triazine frameworks: synthesis and applications Liu, Manying; Guo, Liping; Jin, Shangbin Journal of Materials Chemistry A, Vol. 7, Issue 10 https://doi.org/10.1039/C8TA12442F	journal	January 2019
Covalent organic frameworks for separation applications Wang, Zhifang; Zhang, Sainan; Chen, Yao Chemical Society Reviews, Vol. 49, Issue 3 https://doi.org/10.1039/C9CS00827F	journal	January 2020
A facile solution-phase synthetic approach for constructing phenol-based porous organic cages and covalent organic frameworks Zhang, Lei; Liang, Rongran; Hang, Cheng Green Chemistry, Vol. 22, Issue 8 https://doi.org/10.1039/C9GC04033A	journal	January 2020
Recent development of covalent organic frameworks (COFs): synthesis and catalytic (organic-electro-photo) applications Sharma, Rakesh Kumar; Yadav, Priya; Yadav, Manavi Materials Horizons, Vol. 7, Issue 2 https://doi.org/10.1039/C9MH00856J	journal	January 2020
Large-scale synthesis of azine-linked covalent organic frameworks in water and promoted by water Lu, Jian; Lin, Feng; Wen, Qiang New Journal of Chemistry, Vol. 43, Issue 16 https://doi.org/10.1039/C9NJ00830F	journal	January 2019
Mechanochemical synthesis of N-doped porous carbon at room temperature Casco, Mirian Elizabeth; Kirchhoff, Sebastian; Leistenschneider, Desirée Nanoscale, Vol. 11, Issue 11 https://doi.org/10.1039/C9NR01019J	journal	January 2019
Controlled growth of imine-linked two-dimensional covalent organic framework nanoparticles Li, Rebecca L.; Flanders, Nathan C.; Evans, Austin M. Chemical Science, Vol. 10, Issue 13 https://doi.org/10.1039/C9SC00289H	journal	January 2019
Ambient aqueous-phase synthesis of covalent organic frameworks for degradation of organic pollutants Liu, Yaozu; Wang, Yujie; Li, Hui Chemical Science, Vol. 10, Issue 46 https://doi.org/10.1039/C9SC03725J	journal	January 2019
Green synthesis of imine-based covalent organic frameworks in water Martín-Illán, Jesús Á.; Rodríguez-San-Miguel, David; Franco, Carlos Chemical Communications, Vol. 56, Issue 49 https://doi.org/10.1039/D0CC02033H	journal	January 2020
Mechanochemistry: an efficient and versatile toolbox for synthesis, transformation, and functionalization of porous metal–organic frameworks Stolar, Tomislav; Užarević, Krunoslav CrystEngComm, Vol. 22, Issue 27 https://doi.org/10.1039/D0CE00091D	journal	January 2020
Two-dimensional covalent organic frameworks with hierarchical porosity Liang, Rong-Ran; Jiang, Shu-Yan; A., Ru-Han Chemical Society Reviews, Vol. 49, Issue 12 https://doi.org/10.1039/D0CS00049C	journal	January 2020
New synthetic strategies toward covalent organic frameworks Li, Yusen; Chen, Weiben; Xing, Guolong Chemical Society Reviews, Vol. 49, Issue 10 https://doi.org/10.1039/D0CS00199F	journal	January 2020
Hierarchically porous covalent organic frameworks assembled in ionic liquids for highly effective catalysis of C–C coupling reactions Qiu, Jikuan; Wang, Huiyong; Zhao, Yuling Green Chemistry, Vol. 22, Issue 8 https://doi.org/10.1039/D0GC00223B	journal	January 2020
Facile synthesis of a mesoporous benzothiadiazole-COF based on a transesterification process Dogru, Mirjam; Sonnauer, Andreas; Zimdars, Silvia CrystEngComm, Vol. 15, Issue 8 https://doi.org/10.1039/c2ce26343b	journal	January 2013
Facile synthesis of covalent organic frameworks COF-1 and COF-5 by sonochemical method Yang, Seung-Tae; Kim, Jun; Cho, Hye-Young RSC Advances, Vol. 2, Issue 27 https://doi.org/10.1039/c2ra21531d	journal	January 2012
Nano-structure and property transformations of carbon systems under γ-ray irradiation: a review Xu, Zhiwei; Chen, Lei; Zhou, Baoming RSC Advances, Vol. 3, Issue 27 https://doi.org/10.1039/c3ra00154g	journal	January 2013
Constructing covalent organic frameworks in water via dynamic covalent bonding Thote, Jayshri; Barike Aiyappa, Harshitha; Rahul Kumar, Raya IUCrJ, Vol. 3, Issue 6 https://doi.org/10.1107/S2052252516013762	journal	September 2016
Porous, Crystalline, Covalent Organic Frameworks Côté, Adrien P.; Benin, Annabelle I.; Ockwig, Nathan W. Science, Vol. 310, Issue 5751, p. 1166-1170 https://doi.org/10.1126/science.1120411	journal	November 2005
The atom, the molecule, and the covalent organic framework Diercks, Christian S.; Yaghi, Omar M. Science, Vol. 355, Issue 6328 https://doi.org/10.1126/science.aal1585	journal	March 2017
Single-crystal x-ray diffraction structures of covalent organic frameworks Ma, Tianqiong; Kapustin, Eugene A.; Yin, Shawn X. Science, Vol. 361, Issue 6397 https://doi.org/10.1126/science.aat7679	journal	July 2018

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