Bifunctional Ionic Covalent Organic Networks for Enhanced Simultaneous Removal of Chromium(VI) and Arsenic(V) Oxoanions via Synergetic Ion Exchange and Redox Process
Abstract
Abstract Chromium (VI) and arsenic (V) oxoanions are major toxic heavy metal pollutants in water threatening both human health and environmental safety. Herein, the development is reported of a bifunctional ionic covalent organic network (iCON) with integrated guanidinium and phenol units to simultaneously sequester chromate and arsenate in water via a synergistic ion‐exchange‐redox process. The guanidinium groups facilitate the ion‐exchange‐based adsorption of chromate and arsenate at neutral pH with fast kinetics and high uptake capacity, whereas the integrated phenol motifs mediate the Cr(VI)/Cr(III) redox process that immobilizes chromate and promotes the adsorption of arsenate via the formation of Cr(III)‐As(V) cluster/complex. The synergistic ion‐exchange‐redox approach not only pushes high adsorption efficiency for both chromate and arsenate but also upholds a balanced Cr/As uptake ratio regardless of the change in concentration and the presence of interfering oxoanions.
- Authors:
-
[1];
[1];
[1];
[1];
[1];
[1];
[1]
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Publication Date:
- Research Org.:
- Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1831644
- Alternate Identifier(s):
- OSTI ID: 1997032
- Grant/Contract Number:
- AC05-00OR22725
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Small
- Additional Journal Information:
- Journal Volume: 17; Journal Issue: 46; Journal ID: ISSN 1613-6810
- Publisher:
- Wiley
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; arsenate; chromate; covalent organic networks; ion exchange; oxoanion sequestration; redox process
Citation Formats
Li, Ping, Damron, Josh, Veith, Gabriel, Bryantsev, Vyacheslav, Mahurin, Shannon Mark, Popovs, Ilja, and Jansone-Popova, Santa. Bifunctional Ionic Covalent Organic Networks for Enhanced Simultaneous Removal of Chromium(VI) and Arsenic(V) Oxoanions via Synergetic Ion Exchange and Redox Process. United States: N. p., 2021.
Web. doi:10.1002/smll.202104703.
Li, Ping, Damron, Josh, Veith, Gabriel, Bryantsev, Vyacheslav, Mahurin, Shannon Mark, Popovs, Ilja, & Jansone-Popova, Santa. Bifunctional Ionic Covalent Organic Networks for Enhanced Simultaneous Removal of Chromium(VI) and Arsenic(V) Oxoanions via Synergetic Ion Exchange and Redox Process. United States. https://doi.org/10.1002/smll.202104703
Li, Ping, Damron, Josh, Veith, Gabriel, Bryantsev, Vyacheslav, Mahurin, Shannon Mark, Popovs, Ilja, and Jansone-Popova, Santa. Fri .
"Bifunctional Ionic Covalent Organic Networks for Enhanced Simultaneous Removal of Chromium(VI) and Arsenic(V) Oxoanions via Synergetic Ion Exchange and Redox Process". United States. https://doi.org/10.1002/smll.202104703. https://www.osti.gov/servlets/purl/1831644.
@article{osti_1831644,
title = {Bifunctional Ionic Covalent Organic Networks for Enhanced Simultaneous Removal of Chromium(VI) and Arsenic(V) Oxoanions via Synergetic Ion Exchange and Redox Process},
author = {Li, Ping and Damron, Josh and Veith, Gabriel and Bryantsev, Vyacheslav and Mahurin, Shannon Mark and Popovs, Ilja and Jansone-Popova, Santa},
abstractNote = {Abstract Chromium (VI) and arsenic (V) oxoanions are major toxic heavy metal pollutants in water threatening both human health and environmental safety. Herein, the development is reported of a bifunctional ionic covalent organic network (iCON) with integrated guanidinium and phenol units to simultaneously sequester chromate and arsenate in water via a synergistic ion‐exchange‐redox process. The guanidinium groups facilitate the ion‐exchange‐based adsorption of chromate and arsenate at neutral pH with fast kinetics and high uptake capacity, whereas the integrated phenol motifs mediate the Cr(VI)/Cr(III) redox process that immobilizes chromate and promotes the adsorption of arsenate via the formation of Cr(III)‐As(V) cluster/complex. The synergistic ion‐exchange‐redox approach not only pushes high adsorption efficiency for both chromate and arsenate but also upholds a balanced Cr/As uptake ratio regardless of the change in concentration and the presence of interfering oxoanions.},
doi = {10.1002/smll.202104703},
journal = {Small},
number = 46,
volume = 17,
place = {United States},
year = {Fri Oct 22 00:00:00 EDT 2021},
month = {Fri Oct 22 00:00:00 EDT 2021}
}
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