Bright and stable light-emitting diodes made with perovskite nanocrystals stabilized in metal–organic frameworks

Tsai, Hsinhan; Shrestha, Shreetu; Vilá, Rafael A.; Huang, Wenxiao; Liu, Cunming; Hou, Cheng-Hung; Huang, Hsin-Hsiang; Wen, Xiewen; Li, Mingxing; Wiederrecht, Gary; Cui, Yi; Cotlet, Mircea; Zhang, Xiaoyi; Ma, Xuedan; Nie, Wanyi

doi:10.1038/s41566-021-00857-0

Title: Bright and stable light-emitting diodes made with perovskite nanocrystals stabilized in metal–organic frameworks

Journal Article · 05 September 2021 · Nature Photonics

DOI: https://doi.org/10.1038/s41566-021-00857-0 · OSTI ID:1831462

Tsai, Hsinhan ^[1]; Shrestha, Shreetu ^[1]; Vilá, Rafael A. ^[2]; Huang, Wenxiao ^[2]; Liu, Cunming ^[3];

^[4];

^[5]; Wen, Xiewen ^[6]; Li, Mingxing ^[7];

^[6];

^[2]; Cotlet, Mircea ^[7];

^[3];

^[6];

^[1]

Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
SLAC National Accelerator Lab., Menlo Park, CA (United States). Stanford Institute for Materials and Energy Science (SIMES); Stanford Univ., CA (United States)
Argonne National Lab. (ANL), Argonne, IL (United States)
Academia Sinica, Taipei (Taiwan)
National Taiwan Univ., Taipei (Taiwan); Argonne National Lab. (ANL), Argonne, IL (United States)
Argonne National Lab. (ANL), Argonne, IL (United States). Center for Nanoscale Materials
Brookhaven National Lab. (BNL), Upton, NY (United States). Center for Functional Nanomaterials (CFN)

Perovskite nanocrystals are exceptional candidates for light-emitting diodes (LEDs). However, they are unstable in the solid film and tend to degrade back to the bulk phase, which undermines their potential for LEDs. Here we demonstrate that perovskite nanocrystals stabilized in metal–organic framework (MOF) thin films make bright and stable LEDs. The perovskite nanocrystals in MOF thin films can maintain the photoluminescence and electroluminescence against continuous ultraviolet irradiation, heat and electrical stress. As revealed by optical and X-ray spectroscopy, the strong emission originates from localized carrier recombination. Bright LEDs made from perovskite-MOF nanocrystals are demonstrated with a maximum external quantum efficiency of over 15% and a high brightness of over 10⁵ cd m^-2 after the device reaches stabilization. During LED operation, the nanocrystals can be well preserved, free of ion migration or crystal merging through protection by the MOF matrix, leading to a stable performance over 50 hours.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States); Brookhaven National Laboratory (BNL), Upton, NY (United States); Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)

Sponsoring Organization:: Ministry of Science and Technology of the Republic of China (MOST); National Academy of Sciences; National Science Foundation (NSF); USDOE Laboratory Directed Research and Development (LDRD) Program; USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division

Grant/Contract Number:: 89233218CNA000001; AC02-06CH11357; SC0012704

OSTI ID:: 1831462

Report Number(s):: BNL-222844-2022-JAAM; 170892

Journal Information:: Nature Photonics, Journal Name: Nature Photonics Journal Issue: 11 Vol. 15; ISSN 1749-4885

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United States

Language:: English

References (49)

In Situ Fabrication of Halide Perovskite Nanocrystal-Embedded Polymer Composite Films with Enhanced Photoluminescence for Display Backlights Zhou, Qingchao; Bai, Zelong; Lu, Wen-gao Advanced Materials, Vol. 28, Issue 41 https://doi.org/10.1002/adma.201602651	journal	August 2016
Confinement of Perovskite‐QDs within a Single MOF Crystal for Significantly Enhanced Multiphoton Excited Luminescence He, Huajun; Cui, Yuanjing; Li, Bin Advanced Materials https://doi.org/10.1002/adma.201806897	journal	December 2018
Critical Role of Organic Spacers for Bright 2D Layered Perovskites Light‐Emitting Diodes Tsai, Hsinhan; Liu, Cunming; Kinigstein, Eli Advanced Science, Vol. 7, Issue 7 https://doi.org/10.1002/advs.201903202	journal	February 2020
Advances in Quantum-Confined Perovskite Nanocrystals for Optoelectronics Polavarapu, Lakshminarayana; Nickel, Bert; Feldmann, Jochen Advanced Energy Materials, Vol. 7, Issue 16 https://doi.org/10.1002/aenm.201700267	journal	April 2017
Excitons in Metal‐Halide Perovskites Baranowski, Michal; Plochocka, Paulina Advanced Energy Materials, Vol. 10, Issue 26 https://doi.org/10.1002/aenm.201903659	journal	February 2020
Near‐Unity Photoluminescence Quantum Efficiency for All CsPbX ₃ (X=Cl, Br, and I) Perovskite Nanocrystals: A Generic Synthesis Approach Dutta, Anirban; Behera, Rakesh Kumar; Pal, Poulami Angewandte Chemie International Edition, Vol. 58, Issue 17 https://doi.org/10.1002/anie.201900374	journal	March 2019
Metal Halide Perovskite Nanocrystals in Metal–Organic Framework Host: Not Merely Enhanced Stability Zhang, Congyang; Li, Wanbin; Li, Liang Angewandte Chemie International Edition, Vol. 60, Issue 14 https://doi.org/10.1002/anie.202006169	journal	August 2020
Intermarriage of Halide Perovskites and Metal‐Organic Framework Crystals Hou, Jingwei; Wang, Zhiliang; Chen, Peng Angewandte Chemie International Edition, Vol. 59, Issue 44 https://doi.org/10.1002/anie.202006956	journal	September 2020
A simple one-step method with wide processing window for high-quality perovskite mini-module fabrication Huang, Hsin-Hsiang; Liu, Qi-Han; Tsai, Hsinhan Joule, Vol. 5, Issue 4 https://doi.org/10.1016/j.joule.2021.02.012	journal	April 2021
Enhancing air-stability of CH3NH3PbBr3 perovskite quantum dots by in-situ growth in metal-organic frameworks and their applications in light emitting diodes Zhang, Qianqian; Wu, Haishan; Lin, Wei Journal of Solid State Chemistry, Vol. 272 https://doi.org/10.1016/j.jssc.2019.02.019	journal	April 2019
Ultraviolet light induced degradation of luminescence in CsPbBr3 perovskite nanocrystals Li, Ji; Wang, Li; Yuan, Xi Materials Research Bulletin, Vol. 102 https://doi.org/10.1016/j.materresbull.2018.02.021	journal	June 2018
Near-Unity Photoluminescence Quantum Yield in CsPbBr ₃ Nanocrystal Solid-State Films via Postsynthesis Treatment with Lead Bromide Di Stasio, Francesco; Christodoulou, Sotirios; Huo, Nengjie Chemistry of Materials, Vol. 29, Issue 18 https://doi.org/10.1021/acs.chemmater.7b02834	journal	September 2017
Near-Unity Red Mn ²⁺ Photoluminescence Quantum Yield of Doped CsPbCl ₃ Nanocrystals with Cd Incorporation Ji, Sihang; Yuan, Xi; Cao, Sheng The Journal of Physical Chemistry Letters, Vol. 11, Issue 6 https://doi.org/10.1021/acs.jpclett.0c00372	journal	February 2020
Direct Spectroscopic Observation of the Hole Polaron in Lead Halide Perovskites Liu, Cunming; Tsai, Hsinhan; Nie, Wanyi The Journal of Physical Chemistry Letters, Vol. 11, Issue 15 https://doi.org/10.1021/acs.jpclett.0c01708	journal	July 2020
Temperature-Dependent Photoluminescence of CH ₃ NH ₃ PbBr ₃ Perovskite Quantum Dots and Bulk Counterparts Woo, Hee Chul; Choi, Jin Woo; Shin, Jisoo The Journal of Physical Chemistry Letters, Vol. 9, Issue 14 https://doi.org/10.1021/acs.jpclett.8b01593	journal	June 2018
In Situ Light-Initiated Ligands Cross-Linking Enables Efficient All-Solution-Processed Perovskite Light-Emitting Diodes Wei, Yi; Li, Xuefei; Chen, Yeqing The Journal of Physical Chemistry Letters, Vol. 11, Issue 3 https://doi.org/10.1021/acs.jpclett.9b03775	journal	January 2020
Spectral and Dynamical Properties of Single Excitons, Biexcitons, and Trions in Cesium–Lead-Halide Perovskite Quantum Dots Makarov, Nikolay S.; Guo, Shaojun; Isaienko, Oleksandr Nano Letters, Vol. 16, Issue 4 https://doi.org/10.1021/acs.nanolett.5b05077	journal	March 2016
Ultrapure Green Light-Emitting Diodes Using Two-Dimensional Formamidinium Perovskites: Achieving Recommendation 2020 Color Coordinates Kumar, Sudhir; Jagielski, Jakub; Kallikounis, Nikolaos Nano Letters, Vol. 17, Issue 9 https://doi.org/10.1021/acs.nanolett.7b01544	journal	August 2017
Nanorod Suprastructures from a Ternary Graphene Oxide–Polymer–CsPbX ₃ Perovskite Nanocrystal Composite That Display High Environmental Stability Pan, Aizhao; Jurow, Matthew J.; Qiu, Fen Nano Letters, Vol. 17, Issue 11 https://doi.org/10.1021/acs.nanolett.7b02959	journal	October 2017
Encapsulation of Perovskite Nanocrystals into Macroscale Polymer Matrices: Enhanced Stability and Polarization Raja, Shilpa N.; Bekenstein, Yehonadav; Koc, Matthew A. ACS Applied Materials & Interfaces, Vol. 8, Issue 51 https://doi.org/10.1021/acsami.6b09443	journal	December 2016
Morphology Evolution and Degradation of CsPbBr ₃ Nanocrystals under Blue Light-Emitting Diode Illumination Huang, Shouqiang; Li, Zhichun; Wang, Bo ACS Applied Materials & Interfaces, Vol. 9, Issue 8 https://doi.org/10.1021/acsami.6b14423	journal	February 2017
Extraordinary Interfacial Stitching between Single All-Inorganic Perovskite Nanocrystals Gomez, Leyre; Lin, Junhao; de Weerd, Chris ACS Applied Materials & Interfaces, Vol. 10, Issue 6 https://doi.org/10.1021/acsami.7b17432	journal	January 2018
Surface Ligand Engineering for Efficient Perovskite Nanocrystal-Based Light-Emitting Diodes Park, Jong Hyun; Lee, Ah-young; Yu, Jae Choul ACS Applied Materials & Interfaces, Vol. 11, Issue 8 https://doi.org/10.1021/acsami.8b20808	journal	January 2019
Validated Analysis of Component Distribution Inside Perovskite Solar Cells and Its Utility in Unveiling Factors of Device Performance and Degradation Hou, Cheng-Hung; Hung, Shu-Han; Jhang, Li-Ji ACS Applied Materials & Interfaces, Vol. 12, Issue 20 https://doi.org/10.1021/acsami.9b22492	journal	May 2020
Origin of the Enhanced Photoluminescence Quantum Yield in MAPbBr ₃ Perovskite with Reduced Crystal Size Droseros, Nikolaos; Longo, Giulia; Brauer, Jan C. ACS Energy Letters, Vol. 3, Issue 6 https://doi.org/10.1021/acsenergylett.8b00475	journal	May 2018
Brightly Luminescent and Color-Tunable Colloidal CH ₃ NH ₃ PbX ₃ (X = Br, I, Cl) Quantum Dots: Potential Alternatives for Display Technology Zhang, Feng; Zhong, Haizheng; Chen, Cheng ACS Nano, Vol. 9, Issue 4 https://doi.org/10.1021/acsnano.5b01154	journal	February 2015
Strategy of Solution-Processed All-Inorganic Heterostructure for Humidity/Temperature-Stable Perovskite Quantum Dot Light-Emitting Diodes Shi, Zhifeng; Li, Sen; Li, Ying ACS Nano, Vol. 12, Issue 2 https://doi.org/10.1021/acsnano.7b07856	journal	January 2018
Two-Dimensional Hybrid Halide Perovskites: Principles and Promises Mao, Lingling; Stoumpos, Constantinos C.; Kanatzidis, Mercouri G. Journal of the American Chemical Society, Vol. 141, Issue 3 https://doi.org/10.1021/jacs.8b10851	journal	November 2018
Asynchronous Photoexcited Electronic and Structural Relaxation in Lead-Free Perovskites Liu, Cunming; Wang, Yingqi; Geng, Huifang Journal of the American Chemical Society, Vol. 141, Issue 33 https://doi.org/10.1021/jacs.9b04557	journal	July 2019
Nanocrystals of Cesium Lead Halide Perovskites (CsPbX ₃ , X = Cl, Br, and I): Novel Optoelectronic Materials Showing Bright Emission with Wide Color Gamut Protesescu, Loredana; Yakunin, Sergii; Bodnarchuk, Maryna I. Nano Letters, Vol. 15, Issue 6 https://doi.org/10.1021/nl5048779	journal	February 2015
High-efficiency two-dimensional Ruddlesden–Popper perovskite solar cells Tsai, Hsinhan; Nie, Wanyi; Blancon, Jean-Christophe Nature, Vol. 536, Issue 7616 https://doi.org/10.1038/nature18306	journal	July 2016
Low-threshold amplified spontaneous emission and lasing from colloidal nanocrystals of caesium lead halide perovskites Yakunin, Sergii; Protesescu, Loredana; Krieg, Franziska Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms9056	journal	August 2015
Lead halide perovskite nanowire lasers with low lasing thresholds and high quality factors Zhu, Haiming; Fu, Yongping; Meng, Fei Nature Materials, Vol. 14, Issue 6 https://doi.org/10.1038/nmat4271	journal	April 2015
Quantaurus-QY: Absolute photoluminescence quantum yield spectrometer Suzuki, Kengo Nature Photonics, Vol. 5, Issue 5 https://doi.org/10.1038/nphoton.an.2011.1	journal	April 2011
Conversion of invisible metal-organic frameworks to luminescent perovskite nanocrystals for confidential information encryption and decryption Zhang, Congyang; Wang, Bo; Li, Wanbin Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/s41467-017-01248-2	journal	October 2017
Intermediate-phase-assisted low-temperature formation of γ-CsPbI3 films for high-efficiency deep-red light-emitting devices Yi, Chang; Liu, Chao; Wen, Kaichuan Nature Communications, Vol. 11, Issue 1 https://doi.org/10.1038/s41467-020-18380-1	journal	September 2020
Genesis, challenges and opportunities for colloidal lead halide perovskite nanocrystals Akkerman, Quinten A.; Rainò, Gabriele; Kovalenko, Maksym V. Nature Materials, Vol. 17, Issue 5 https://doi.org/10.1038/s41563-018-0018-4	journal	February 2018
Continuous-wave lasing in an organic–inorganic lead halide perovskite semiconductor Jia, Yufei; Kerner, Ross A.; Grede, Alex J. Nature Photonics, Vol. 11, Issue 12 https://doi.org/10.1038/s41566-017-0047-6	journal	November 2017
High-efficiency perovskite–polymer bulk heterostructure light-emitting diodes Zhao, Baodan; Bai, Sai; Kim, Vincent Nature Photonics, Vol. 12, Issue 12 https://doi.org/10.1038/s41566-018-0283-4	journal	November 2018
All-inorganic perovskite nanocrystal scintillators Chen, Qiushui; Wu, Jing; Ou, Xiangyu Nature, Vol. 561, Issue 7721 https://doi.org/10.1038/s41586-018-0451-1	journal	August 2018
Perovskite light-emitting diodes with external quantum efficiency exceeding 20 per cent Lin, Kebin; Xing, Jun; Quan, Li Na Nature, Vol. 562, Issue 7726 https://doi.org/10.1038/s41586-018-0575-3	journal	October 2018
Perovskite light-emitting diodes based on spontaneously formed submicrometre-scale structures Cao, Yu; Wang, Nana; Tian, He Nature, Vol. 562, Issue 7726 https://doi.org/10.1038/s41586-018-0576-2	journal	October 2018
Planar perovskite solar cells with long-term stability using ionic liquid additives Bai, Sai; Da, Peimei; Li, Cheng Nature, Vol. 571, Issue 7764 https://doi.org/10.1038/s41586-019-1357-2	journal	July 2019
A fabrication process for flexible single-crystal perovskite devices Lei, Yusheng; Chen, Yimu; Zhang, Ruiqi Nature, Vol. 583, Issue 7818 https://doi.org/10.1038/s41586-020-2526-z	journal	July 2020
Bright and fast scintillation of organolead perovskite MAPbBr ₃ at low temperatures Mykhaylyk, Vitaliy B.; Kraus, Hans; Saliba, Michael Materials Horizons, Vol. 6, Issue 8 https://doi.org/10.1039/C9MH00281B	journal	January 2019
Sonochemical synthesis and structural characterization of a nano-structure Pb(II) benzentricarboxylate coordination polymer: new precursor to pure phase nanoparticles of Pb(II) oxide Sadeghzadeh, Homa; Morsali, Ali Journal of Coordination Chemistry, Vol. 63, Issue 4 https://doi.org/10.1080/00958970903502736	journal	January 2010
Atomically thin two-dimensional organic-inorganic hybrid perovskites Dou, L.; Wong, A. B.; Yu, Y. Science, Vol. 349, Issue 6255 https://doi.org/10.1126/science.aac7660	journal	September 2015
Properties and potential optoelectronic applications of lead halide perovskite nanocrystals Kovalenko, Maksym V.; Protesescu, Loredana; Bodnarchuk, Maryna I. Science, Vol. 358, Issue 6364 https://doi.org/10.1126/science.aam7093	journal	November 2017
Photon-induced carrier recombination in the nonlayered-structured hybrid organic-inorganic perovskite nano-sheets Wang, Di; Shi, Wen-Bo; Jing, Hao Optics Express, Vol. 26, Issue 21 https://doi.org/10.1364/OE.26.027504	journal	January 2018

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