Oxygen redox chemistry in P2-Na0.6Li0.11Fe0.27Mn0.62O2 cathode for high-energy Na-ion batteries
Abstract
Owing to the abundance of raw material reserves and low cost, Na-ion batteries (NIBs) have successfully gained widespread attention from academic and industrial communities in the past few decades. However, the insufficient cathode energy density is still one of the critical bottlenecks restricting the development of NIBs. Following a strategy of introducing Li+ into the transition-metal (TM) layer to enhance the oxygen redox reaction, a novel layered cathode material P2-Na0.6Li0.11Fe0.27Mn0.62O2 (NLFMO) was designed and successfully synthesized. This NLFMO cathode not only delivers a large initial reversible capacity of 207.3 mA h g-1, but also shows a good cycling performance (104.2 mA h g-1 after 80 cycles) and rate capability (126.2 mA h g-1 at 1C). The ultrahigh capacity is contributed by both cationic (Fe3+/Fe4+ and Mn3+/Mn4+) and partially reversible anionic redox (O2-/On-) reactions, revealed by in situ X-ray absorption spectroscopy (XAS) and X-ray photoelectron spectroscopy (XPS) techniques. Moreover, no detrimental P2–O2 phase transition was observed in ex situ X-ray diffraction (XRD) patterns, confirming the high structural stability during Na+ deintercalation/intercalation processes. These results provide valuable information about the high-energy density layered cathode materials based on anionic redox reactions for NIBs.
- Authors:
-
[4];
[6]
- East China University of Technology, Nanchang (China); Fudan Univ., Shanghai (China)
- East China University of Technology, Nanchang (China)
- Brookhaven National Lab. (BNL), Upton, NY (United States). National Synchrotron Light Source II (NSLS-II)
- Brookhaven National Lab. (BNL), Upton, NY (United States)
- Shanghai Jiao Tong Univ. (China)
- Fudan Univ., Shanghai (China)
- Publication Date:
- Research Org.:
- Brookhaven National Laboratory (BNL), Upton, NY (United States)
- Sponsoring Org.:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE), Transportation Office. Vehicle Technologies Office; National Natural Science Foundation of China (NSFC); Shanghai Science and Technology Committee; Doctoral Scientific Research Foundation of East China University of Technology; USDOE
- OSTI Identifier:
- 1831453
- Alternate Identifier(s):
- OSTI ID: 1833909
- Report Number(s):
- BNL-222420-2021-JAAM
Journal ID: ISSN 2050-7488
- Grant/Contract Number:
- SC0012704; 22005047; 19DZ2270100; DHBK2019121; S202110405024
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of Materials Chemistry. A
- Additional Journal Information:
- Journal Volume: 9; Journal Issue: 48; Journal ID: ISSN 2050-7488
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; Na-ion batteries; P2-Layered cathode materials; High energy density; Oxygen redox
Citation Formats
Cao, Ming-Hui, Li, Ren-Yan, Lin, Shi-Ya, Zheng, Shao-Di, Ma, Lu, Tan, Sha, Hu, Enyuan, Shadike, Zulipiya, Yang, Xiao-Qing, and Fu, Zheng-Wen. Oxygen redox chemistry in P2-Na0.6Li0.11Fe0.27Mn0.62O2 cathode for high-energy Na-ion batteries. United States: N. p., 2021.
Web. doi:10.1039/d1ta08471b.
Cao, Ming-Hui, Li, Ren-Yan, Lin, Shi-Ya, Zheng, Shao-Di, Ma, Lu, Tan, Sha, Hu, Enyuan, Shadike, Zulipiya, Yang, Xiao-Qing, & Fu, Zheng-Wen. Oxygen redox chemistry in P2-Na0.6Li0.11Fe0.27Mn0.62O2 cathode for high-energy Na-ion batteries. United States. https://doi.org/10.1039/d1ta08471b
Cao, Ming-Hui, Li, Ren-Yan, Lin, Shi-Ya, Zheng, Shao-Di, Ma, Lu, Tan, Sha, Hu, Enyuan, Shadike, Zulipiya, Yang, Xiao-Qing, and Fu, Zheng-Wen. Fri .
"Oxygen redox chemistry in P2-Na0.6Li0.11Fe0.27Mn0.62O2 cathode for high-energy Na-ion batteries". United States. https://doi.org/10.1039/d1ta08471b. https://www.osti.gov/servlets/purl/1831453.
@article{osti_1831453,
title = {Oxygen redox chemistry in P2-Na0.6Li0.11Fe0.27Mn0.62O2 cathode for high-energy Na-ion batteries},
author = {Cao, Ming-Hui and Li, Ren-Yan and Lin, Shi-Ya and Zheng, Shao-Di and Ma, Lu and Tan, Sha and Hu, Enyuan and Shadike, Zulipiya and Yang, Xiao-Qing and Fu, Zheng-Wen},
abstractNote = {Owing to the abundance of raw material reserves and low cost, Na-ion batteries (NIBs) have successfully gained widespread attention from academic and industrial communities in the past few decades. However, the insufficient cathode energy density is still one of the critical bottlenecks restricting the development of NIBs. Following a strategy of introducing Li+ into the transition-metal (TM) layer to enhance the oxygen redox reaction, a novel layered cathode material P2-Na0.6Li0.11Fe0.27Mn0.62O2 (NLFMO) was designed and successfully synthesized. This NLFMO cathode not only delivers a large initial reversible capacity of 207.3 mA h g-1, but also shows a good cycling performance (104.2 mA h g-1 after 80 cycles) and rate capability (126.2 mA h g-1 at 1C). The ultrahigh capacity is contributed by both cationic (Fe3+/Fe4+ and Mn3+/Mn4+) and partially reversible anionic redox (O2-/On-) reactions, revealed by in situ X-ray absorption spectroscopy (XAS) and X-ray photoelectron spectroscopy (XPS) techniques. Moreover, no detrimental P2–O2 phase transition was observed in ex situ X-ray diffraction (XRD) patterns, confirming the high structural stability during Na+ deintercalation/intercalation processes. These results provide valuable information about the high-energy density layered cathode materials based on anionic redox reactions for NIBs.},
doi = {10.1039/d1ta08471b},
journal = {Journal of Materials Chemistry. A},
number = 48,
volume = 9,
place = {United States},
year = {Fri Jan 01 00:00:00 EST 2021},
month = {Fri Jan 01 00:00:00 EST 2021}
}
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