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Title: Nonaqueous hybrid redox flow energy storage with a sodium–TEMPO chemistry and a single-ion solid electrolyte separator

Journal Article · · Energy Advances
DOI: https://doi.org/10.1039/D1YA00010A · OSTI ID:1831288

Integration of a sodium anode chemistry and a TEMPO cathode chemistry enables the advancement of a high voltage nonaqueous hybrid flow battery (HFB). A single-ion solid-electrolyte separator ensures a crossover-free operation of the HFB.

Sponsoring Organization:
USDOE
Grant/Contract Number:
NONE; SC0005397
OSTI ID:
1831288
Journal Information:
Energy Advances, Journal Name: Energy Advances Journal Issue: 1 Vol. 1; ISSN 2753-1457; ISSN EANDBJ
Publisher:
Royal Society of Chemistry (RSC)Copyright Statement
Country of Publication:
United Kingdom
Language:
English

References (34)

Aqueous Electrochemical Energy Storage with a Mediator-Ion Solid Electrolyte journal January 2017
Redox-Flow Batteries: From Metals to Organic Redox-Active Materials journal November 2016
The Promise of Environmentally Benign Redox Flow Batteries by Molecular Engineering journal April 2017
Synthesis and Charge/Discharge Properties of Polyacetylenes Carrying 2,2,6,6-Tetramethyl-1-piperidinoxy Radicals journal September 2007
Enhancement of the interfacial transfer of iodine by chemical reaction journal February 2000
Ambient Temperature Sodium-Sulfur Batteries journal January 2015
A Unique Single‐Ion Mediation Approach for Crossover‐Free Nonaqueous Redox Flow Batteries with a Na + ‐Ion Solid Electrolyte journal November 2019
Redox flow batteries a review journal September 2011
Progress and prospects of next-generation redox flow batteries journal November 2018
Development of low-cost sodium-aqueous polysulfide hybrid batteries journal May 2019
A mediator-ion nitrobenzene - iodine nonaqueous redox flow battery with asymmetric solvents journal August 2020
Evaluation of redox flow batteries goes beyond round-trip efficiency: A technical review journal April 2018
Electrochemical Energy Storage with Mediator-Ion Solid Electrolytes journal November 2017
Redox flow batteries for the storage of renewable energy: A review journal January 2014
(2,2,6,6-Tetramethylpiperidin-1-yl)oxyl-Containing Zwitterionic Polymer as Catholyte Species for High-Capacity Aqueous Polymer Redox Flow Batteries journal August 2019
Tetramethylpiperidine N -Oxyl (TEMPO), Phthalimide N -Oxyl (PINO), and Related N -Oxyl Species: Electrochemical Properties and Their Use in Electrocatalytic Reactions journal April 2018
Electrochemical Energy Storage with an Aqueous Zinc–Quinone Chemistry Enabled by a Mediator-Ion Solid Electrolyte journal January 2018
Electrochemical Energy Storage with an Aqueous Quinone–Air Chemistry journal May 2018
High-Energy, Single-Ion-Mediated Nonaqueous Zinc-TEMPO Redox Flow Battery journal October 2020
Electrochemical Energy Storage for Green Grid journal May 2011
Flow Batteries: Current Status and Trends journal September 2015
Mass Transport Effects on the Kinetics of Nitrobenzene Reduction by Iron Metal journal May 2001
Energy storage: Power revolution journal October 2015
Germany’s renewable revolution awaits energy forecast journal July 2016
Lithium battery chemistries enabled by solid-state electrolytes journal February 2017
A reflection on lithium-ion battery cathode chemistry journal March 2020
High-nickel layered oxide cathodes for lithium-based automotive batteries journal January 2020
Pathways to low-cost electrochemical energy storage: a comparison of aqueous and nonaqueous flow batteries journal January 2014
Nonaqueous redox-flow batteries: organic solvents, supporting electrolytes, and redox pairs journal January 2015
Redox-active polyimide/carbon nanocomposite electrodes for reversible charge storage at negative potentials: expanding the functional horizon of polyimides journal January 2010
Towards sustainable and versatile energy storage devices: an overview of organic electrode materials journal January 2013
Room-temperature stationary sodium-ion batteries for large-scale electric energy storage journal January 2013
A review of current developments in non-aqueous redox flow batteries: characterization of their membranes for design perspective journal January 2013
Electrochemical Properties of an All-Organic Redox Flow Battery Using 2,2,6,6-Tetramethyl-1-Piperidinyloxy and N-Methylphthalimide journal January 2011