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Title: Atomic Iron and Nickel in the Coma of C/1996 B2 (Hyakutake): Production Rates, Emission Mechanisms, and Possible Parents

Journal Article · · The Planetary Science Journal
DOI: https://doi.org/10.3847/PSJ/ac2dff · OSTI ID:1830454

Abstract Two papers recently reported the detection of gaseous nickel and iron in the comae of over 20 comets from observations collected over two decades, including interstellar comet 2I/Borisov. To evaluate the state of the laboratory data in support of these identifications, we reanalyzed archived spectra of comet C/1996 B2 (Hyakutake), one of the nearest and brightest comets of the past century, using a combined experimental and computational approach. We developed a new, many-level fluorescence model that indicates that the fluorescence emissions of Fe I and Ni I vary greatly with heliocentric velocity. Combining this model with laboratory spectra of an Fe-Ni plasma, we identified 22 lines of Fe I and 14 lines of Ni I in the spectrum of Hyakutake. Using Haser models, we estimate the nickel and iron production rates as Q Ni = (2.6–4.1) × 10 22 s −1 and Q Fe = (0.4–2.8) × 10 23 s −1 . From derived column densities, the Ni/Fe abundance ratio log 10 [Ni/Fe] = −0.15 ± 0.07 deviates significantly from solar abundance ratios, and it is consistent with the ratios observed in solar system comets. Possible production and emission mechanisms are analyzed in the context of existing laboratory measurements. Based on the observed spatial distributions, excellent fluorescence model agreement, and Ni/Fe ratio, our findings support an origin consisting of a short-lived unknown parent followed by fluorescence emission. Our models suggest that the strong heliocentric velocity dependence of the fluorescence efficiencies can provide a meaningful test of the physical process responsible for the Fe I and Ni I emission.

Sponsoring Organization:
USDOE
Grant/Contract Number:
FG02-00ER54610
OSTI ID:
1830454
Journal Information:
The Planetary Science Journal, Journal Name: The Planetary Science Journal Journal Issue: 6 Vol. 2; ISSN 2632-3338
Publisher:
American Astronomical SocietyCopyright Statement
Country of Publication:
United Kingdom
Language:
English

References (63)

Observational Constraints on the Lifetime of Cometary H2O journal September 1993
The Ensemble Properties of Comets: Results from Narrowband Photometry of 85 Comets, 1976-1992 journal December 1995
The NH and CH Bands of Comet C/1996 B2 (Hyakutake) journal December 1998
Long- and Short-Term Photometric Behavior of Comet Hyakutake (1996 B2) journal September 2002
Far- and Extreme-UV Solar Spectral Irradiance and Radiance from Simplified Atmospheric Physical Models journal November 2013
The Science of Sungrazers, Sunskirters, and Other Near-Sun Comets journal December 2017
Possible contribution of organometallic species in the solar system ices. Reactivity and spectroscopy journal September 1996
Enlightening organometallic chemistry: the photochemistry of Fe(CO)5 and the reaction chemistry of unsaturated iron carbonyl fragments journal July 1999
Neutral sodium tails in comets journal April 2002
Evidence for aqueous activity on comet 81P/Wild 2 from sulfide mineral assemblages in Stardust samples and CI chondrites journal June 2011
The rotational structure of the B–X system of sulfur dimers in the spectra of Comet Hyakutake (C/1996 B2) journal November 2003
Water ice and dust in the innermost coma of comet 103P/Hartley 2 journal August 2014
An improved high-resolution solar reference spectrum for earth's atmosphere measurements in the ultraviolet, visible, and near infrared journal June 2010
A new linelist for the A3Π– X 3 Σ − transition of the NH free radical journal September 2018
Planetary Spectrum Generator: An accurate online radiative transfer suite for atmospheres, comets, small bodies and exoplanets journal September 2018
Photoionization and photodissociation rates in solar and blackbody radiation fields journal February 2015
The Influence of Metal Ion Binding on the IR Spectra of Nitrogen-Containing PAHs journal September 2016
Decomposition of Iron Pentacarbonyl Induced by Singly and Multiply Charged Ions and Implications for Focused Ion Beam-Induced Deposition journal March 2019
Optical spectra of transition-metal carbonyls: chromium hexacarbonyl, iron pentacarbonyl, and nickel tetracarbonyl journal September 1989
Ultrafast Photodissociation Dynamics of Ni(CO) 4 journal December 2000
The Impact of Comet Siding Spring's Meteors on the Martian Atmosphere and Ionosphere journal October 2018
The TSIS‐1 Hybrid Solar Reference Spectrum journal June 2021
High-resolution solar spectrum between 2000 and 3100 Å journal January 1991
Metallic emission lines during the impacts L and Q 1 of comet P/Shoemaker Levy 9 in Jupiter journal June 1995
Aspects of the major element composition of Halley's dust journal April 1988
Iron and nickel vapours are present in most comets journal May 2021
Array programming with NumPy journal September 2020
Iron and nickel atoms in cometary atmospheres even far from the Sun journal May 2021
Gaseous atomic nickel in the coma of interstellar comet 2I/Borisov journal May 2021
SciPy 1.0: fundamental algorithms for scientific computing in Python journal February 2020
Astrochemistry of transition metals? The selected cases of [FeN] + , [FeNH] + and [(CO) 2 FeN] + : pathways toward CH 3 NH 2 and HNCO journal January 2014
Plasma properties of suprathermal electrons near comet 67P/Churyumov-Gerasimenko with Rosetta journal September 2019
FeI and NiI in cometary atmospheres: Connections between the NiI/FeI abundance ratio and chemical characteristics of Jupiter-family and Oort-cloud comets journal July 2021
Ultraviolet photodissociation of gas-phase iron pentacarbonyl probed with ultrafast infrared spectroscopy journal April 2021
Structures and binding energies for complexations of different spin states of Ni + and Ni 2+ to aromatic molecules journal June 2018
Design, Construction, and Operation of the Compact Toroidal Hybrid journal May 2017
The Emission Spectrum of Comet Ikeya-Seki 1965-f at Perihelion Passage journal September 1969
The spectrum of Ikkeya-Seki (1965f) journal February 1967
The fluorescence of cometary OH journal August 1988
Composition and radiative properties of grains in molecular clouds and accretion disks journal January 1994
Neutral Sodium from Comet Hale-Bopp: A Third Type of Tail journal December 1997
Unidentified Molecular Bands in the Plasma Tail of Comet Hyakutake (C/1996 B2) journal February 1999
Atomic Data for Resonance Absorption Lines. II. Wavelengths Longward of the Lyman Limit for Heavy Elements journal October 2000
Prompt Emission by oh in Comet Hyakutake journal June 2015
ANALYSIS OF OPTICAL Fe II EMISSION IN A SAMPLE OF ACTIVE GALACTIC NUCLEUS SPECTRA journal June 2010
Semi-empirical scaling for ion–atom single charge exchange cross sections in the intermediate velocity regime journal May 2017
Advances in neutral tungsten ultraviolet spectroscopy for the potential benefit to gross erosion diagnosis journal August 2019
Exocomets from a Solar System Perspective journal September 2020
Elemental and molecular abundances in comet 67P/Churyumov-Gerasimenko journal July 2019
Double dark matter vision: twice the number of compact-source lenses with narrow-line lensing and the WFC3 grism journal December 2019
The composition of cometary ices
  • Bockelée-Morvan, D.; Biver, N.
  • Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences, Vol. 375, Issue 2097 https://doi.org/10.1098/rsta.2016.0252
journal May 2017
EPOXI at Comet Hartley 2 journal June 2011
Dissociative excitation study of iron pentacarbonyl molecule journal April 2015
Cometary Chemistry and the Origin of Icy Solar System Bodies: The View After Rosetta journal August 2019
The Stardust Mission: Analyzing Samples from the Edge of the Solar System journal May 2014
sbpy: A Python module for small-body planetary astronomy journal June 2019
The Peculiar Volatile Composition of CO-dominated Comet C/2016 R2 (PanSTARRS) journal August 2019
H 2 CO Distribution and Formation in the TW HYA Disk journal April 2017
Diagnostics of Collisions between Electrons and Water Molecules in Near-ultraviolet and Visible Wavelengths journal November 2019
Panning for Gold: New Emission Lines from UV–VIS Spectroscopy of Au i and Au ii journal September 2020
Intensity Distribution in the Heads of Comets journal December 2020
All Comets are Somewhat Hyperactive and the Implications Thereof journal May 2021
Photoionization study of Fe(CO)5 and Ni(CO)4 journal March 1970

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