Highly efficient Pt catalyst on newly designed CeO2-ZrO2-Al2O3 support for catalytic removal of pollutants from vehicle exhaust

Tan, Wei; Xie, Shaohua; Wang, Xin; Wang, Chunying; Li, Yaobin; Shaw, Thomas E.; Ma, Lu; Ehrlich, Steven N.; Liu, Annai; Ji, Jiawei; Gao, Fei; Dong, Lin; Liu, Fudong

doi:10.1016/j.cej.2021.131855

Title: Highly efficient Pt catalyst on newly designed CeO₂-ZrO₂-Al₂O₃ support for catalytic removal of pollutants from vehicle exhaust

Journal Article · 18 August 2021 · Chemical Engineering Journal

DOI: https://doi.org/10.1016/j.cej.2021.131855 · OSTI ID:1830195

^[1]; Xie, Shaohua ^[2];

^[3]; Wang, Chunying ^[4]; Li, Yaobin ^[4];

^[2]; Ma, Lu ^[5]; Ehrlich, Steven N. ^[5];

^[3];

^[3]; Dong, Lin ^[3]; Liu, Fudong ^[2]

Nanjing Univ. (China); Univ. of Central Florida, Orlando, FL (United States)
Univ. of Central Florida, Orlando, FL (United States)
Nanjing Univ. (China)
Chinese Academy of Sciences (CAS), Xiamen (China)
Brookhaven National Lab. (BNL), Upton, NY (United States)

Pt-CeO₂ catalysts have been widely studied for the vehicle emission control. Designing novel CeO₂ based supports with improved physical-chemical properties has become a research hotspot to further promote the catalytic performance and stability of Pt-CeO₂ catalysts. In this work, through utilizing a unique, two-step incipient wetness impregnation (T-IWI) method for ceria-zirconia-alumina (CZA-T) support preparation, a Pt single site catalyst (Pt/CZA-T) with excellent thermal stability was synthesized. Higher oxidation activity and Oxygen storage capacity (OSC) were achieved on activated Pt/CZA-T, comparing to Pt catalysts on regular CeO₂/Al₂O₃ (Pt/CA) and one-step prepared CeZrO_x/Al₂O₃ (Pt/CZA). Via the modification of hydrophilic/hydrophobic properties of γ-Al₂O₃ by this unique T-IWI method, finer Ce_0.9Zr_0.1O₂ particles with higher density of surface defects were formed on CZA-T, on which a higher Pt dispersion and stronger Pt-O-Ce interaction were achieved. Upon activation, smaller, well-dispersed Pt clusters on CZA-T were generated. It was concluded that the CO oxidation performance and OSC were highly related to the size of Pt clusters on different supports that we have developed. Finally, more Pt sites located at Pt cluster-CeZrO_x interfaces, which were the real active sites, were responsible for the highest OSC function and CO oxidation activity of activated Pt/CZA-T catalyst.

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Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Organization:: National Natural Science Foundation of China (NSFC); Natural Science Foundation of Jiangsu Province; USDOE; USDOE Office of Science (SC)

Grant/Contract Number:: SC0012704

OSTI ID:: 1830195

Report Number(s):: BNL--222363-2021-JAAM

Journal Information:: Chemical Engineering Journal, Journal Name: Chemical Engineering Journal Vol. 426; ISSN 1385-8947

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

References (57)

Catalytically Active and Spectator Ce ³⁺ in Ceria-Supported Metal Catalysts Kopelent, René; van Bokhoven, Jeroen A.; Szlachetko, Jakub Angewandte Chemie International Edition, Vol. 54, Issue 30 https://doi.org/10.1002/anie.201503022	journal	June 2015
Tuning the Structure of Platinum Particles on Ceria In Situ for Enhancing the Catalytic Performance of Exhaust Gas Catalysts Gänzler, Andreas M.; Casapu, Maria; Vernoux, Philippe Angewandte Chemie International Edition, Vol. 56, Issue 42 https://doi.org/10.1002/anie.201707842	journal	September 2017
Economizing on Precious Metals in Three‐Way Catalysts: Thermally Stable and Highly Active Single‐Atom Rhodium on Ceria for NO Abatement under Dry and Industrially Relevant Conditions** Khivantsev, Konstantin; Vargas, Carlos Garcia; Tian, Jinshu Angewandte Chemie International Edition, Vol. 60, Issue 1 https://doi.org/10.1002/anie.202010815	journal	October 2020
Activating Lattice Oxygen at the Twisted Surface in a Mesoporous CeO ₂ Single Crystal for Efficient and Durable Catalytic CO Oxidation Xiao, Yongchun; Li, Hao; Xie, Kui Angewandte Chemie International Edition, Vol. 60, Issue 10 https://doi.org/10.1002/anie.202013633	journal	January 2021
Morphology Effect of CeO ₂ Support in the Preparation, Metal-Support Interaction, and Catalytic Performance of Pt/CeO ₂ Catalysts Gao, Yuxian; Wang, Wendong; Chang, Sujie ChemCatChem, Vol. 5, Issue 12 https://doi.org/10.1002/cctc.201300709	journal	September 2013
Effects of Trivalent Dopants on the Redox Properties of Ce0.6Zr0.4O2Mixed Oxide Vidmar, Polona; Fornasiero, Paolo; Kašpar, Jan Journal of Catalysis, Vol. 171, Issue 1 https://doi.org/10.1006/jcat.1997.1784	journal	October 1997
Nanosized CeO2–SiO2, CeO2–TiO2, and CeO2–ZrO2 Mixed Oxides: Influence of Supporting Oxide on Thermal Stability and Oxygen Storage Properties of Ceria Reddy, Benjaram M.; Khan, Ataullah Catalysis Surveys from Asia, Vol. 9, Issue 3 https://doi.org/10.1007/s10563-005-7552-1	journal	September 2005
Insight of the stability and activity of platinum single atoms on ceria Ye, Xuxu; Wang, Hengwei; Lin, Yue Nano Research, Vol. 12, Issue 6 https://doi.org/10.1007/s12274-019-2351-6	journal	May 2019
Investigation of the oxygen storage process on ceria- and ceria–zirconia-supported catalysts Bedrane, Sumeya; Descorme, Claude; Duprez, Daniel Catalysis Today, Vol. 75, Issue 1-4 https://doi.org/10.1016/S0920-5861(02)00089-5	journal	July 2002
Thermal stability of oxygen storage properties in a mixed CeO2-ZrO2 system Hori, C. Applied Catalysis B: Environmental, Vol. 16, Issue 2 https://doi.org/10.1016/S0926-3373(97)00060-X	journal	March 1998
The effect of ceria content on the performance of Pt/CeO/AlO catalysts in the partial oxidation of methane Santos, A.; Damyanova, S.; Teixeira, G. Applied Catalysis A: General, Vol. 290, Issue 1-2 https://doi.org/10.1016/j.apcata.2005.05.015	journal	August 2005
Influence of preparation method on the catalytic activities of CuO/Ce0.67Zr0.33O2 catalysts in CO+O2 reaction Zhu, Jie; Zhang, Lingling; Deng, Yu Applied Catalysis B: Environmental, Vol. 96, Issue 3-4 https://doi.org/10.1016/j.apcatb.2010.03.003	journal	June 2010
Influence of cerium precursors on the structure and reducibility of mesoporous CuO-CeO2 catalysts for CO oxidation Qi, Lei; Yu, Qiang; Dai, Yue Applied Catalysis B: Environmental, Vol. 119-120 https://doi.org/10.1016/j.apcatb.2012.02.029	journal	May 2012
Nano-Au/CeO2 catalysts for CO oxidation: Influence of dopants (Fe, La and Zr) on the physicochemical properties and catalytic activity Sudarsanam, Putla; Mallesham, Baithy; Reddy, Padigapati S. Applied Catalysis B: Environmental, Vol. 144 https://doi.org/10.1016/j.apcatb.2013.08.035	journal	January 2014
Low-temperature CO oxidation by Pd/CeO2 catalysts synthesized using the coprecipitation method Slavinskaya, E. M.; Gulyaev, R. V.; Zadesenets, A. V. Applied Catalysis B: Environmental, Vol. 166-167 https://doi.org/10.1016/j.apcatb.2014.11.015	journal	May 2015
Synergy between hydrogen and ceria in Pt-catalyzed CO oxidation: An investigation on Pt–CeO2 catalysts synthesized by solution combustion Morfin, Franck; Nguyen, Thanh-Son; Rousset, Jean-Luc Applied Catalysis B: Environmental, Vol. 197 https://doi.org/10.1016/j.apcatb.2016.01.056	journal	November 2016
Structuring Pt/CeO2/Al2O3 WGS catalyst: Introduction of buffer layer González-Castaño, M.; Ivanova, S.; Laguna, O. H. Applied Catalysis B: Environmental, Vol. 200 https://doi.org/10.1016/j.apcatb.2016.07.039	journal	January 2017
Design considerations for low-temperature hydrocarbon oxidation reactions on Pd based catalysts Xiong, Haifeng; Wiebenga, Michelle H.; Carrillo, Cristihan Applied Catalysis B: Environmental, Vol. 236 https://doi.org/10.1016/j.apcatb.2018.05.049	journal	November 2018
Effect of ethanol–gasoline blends on CO and HC emissions in last generation SI engines within the cold-start transient: An experimental investigation Iodice, Paolo; Senatore, Adolfo; Langella, Giuseppe Applied Energy, Vol. 179 https://doi.org/10.1016/j.apenergy.2016.06.144	journal	October 2016
Oxygen vacancy promoted CO oxidation over Pt/CeO 2 catalysts: A reaction at Pt–CeO 2 interface Liu, Huan-Huan; Wang, Yu; Jia, Ai-Pin Applied Surface Science, Vol. 314 https://doi.org/10.1016/j.apsusc.2014.06.196	journal	September 2014
Theoretical insights into the hydrophobicity of low index CeO2 surfaces Fronzi, Marco; Assadi, M. Hussein N.; Hanaor, Dorian A. H. Applied Surface Science, Vol. 478 https://doi.org/10.1016/j.apsusc.2019.01.208	journal	June 2019
Raman spectroscopy as a powerful tool to characterize ceria-based catalysts Loridant, Stéphane Catalysis Today, Vol. 373 https://doi.org/10.1016/j.cattod.2020.03.044	journal	August 2021
Preferential CO oxidation in hydrogen (PROX) on ceria-supported catalysts, part I: Oxidation state and surface species on Pt/CeO2 under reaction conditions Pozdnyakova, O.; Teschner, D.; Wootsch, A. Journal of Catalysis, Vol. 237, Issue 1 https://doi.org/10.1016/j.jcat.2005.10.014	journal	January 2006
Synthesis and physicochemical characterizations of nanostructured Pt/Al2O3–CeO2 catalysts for total oxidation of VOCs Abbasi, Zahra; Haghighi, Mohammad; Fatehifar, Esmaeil Journal of Hazardous Materials, Vol. 186, Issue 2-3 https://doi.org/10.1016/j.jhazmat.2010.12.034	journal	February 2011
Support Morphology-Dependent Catalytic Activity of Pd/CeO ₂ for Formaldehyde Oxidation Tan, Hongyi; Wang, Jin; Yu, Shuzhen Environmental Science & Technology, Vol. 49, Issue 14 https://doi.org/10.1021/acs.est.5b01264	journal	July 2015
How Pt Interacts with CeO ₂ under the Reducing and Oxidizing Environments at Elevated Temperature: The Origin of Improved Thermal Stability of Pt/CeO ₂ Compared to CeO ₂ Lee, Jaeha; Ryou, YoungSeok; Chan, Xiaojun The Journal of Physical Chemistry C, Vol. 120, Issue 45 https://doi.org/10.1021/acs.jpcc.6b08656	journal	November 2016
Correlating DFT Calculations with CO Oxidation Reactivity on Ga-Doped Pt/CeO ₂ Single-Atom Catalysts Feng, Yingxin; Wan, Qiang; Xiong, Haifeng The Journal of Physical Chemistry C, Vol. 122, Issue 39 https://doi.org/10.1021/acs.jpcc.8b05815	journal	September 2018
Structural Insight into Strong Pt–CeO ₂ Interaction: From Single Pt Atoms to PtO _x Clusters Derevyannikova, Elizaveta A.; Kardash, Tatyana Yu; Stadnichenko, Andrey I. The Journal of Physical Chemistry C, Vol. 123, Issue 2 https://doi.org/10.1021/acs.jpcc.8b11009	journal	December 2018
Unravelling the Different Reaction Pathways for Low Temperature CO Oxidation on Pt/CeO ₂ and Pt/Al ₂ O ₃ by Spatially Resolved Structure–Activity Correlations Gänzler, Andreas M.; Casapu, Maria; Doronkin, Dmitry E. The Journal of Physical Chemistry Letters, Vol. 10, Issue 24 https://doi.org/10.1021/acs.jpclett.9b02768	journal	November 2019
Comparative Study of Moisture-Treated Pd@CeO ₂ /Al ₂ O ₃ and Pd/CeO ₂ /Al ₂ O ₃ Catalysts for Automobile Exhaust Emission Reactions: Effect of Core–Shell Interface Li, Lingcong; Zhang, Ningqiang; Wu, Rui ACS Applied Materials & Interfaces, Vol. 12, Issue 9 https://doi.org/10.1021/acsami.9b20734	journal	February 2020
Water-Mediated Mars–Van Krevelen Mechanism for CO Oxidation on Ceria-Supported Single-Atom Pt ₁ Catalyst Wang, Chunlei; Gu, Xiang-Kui; Yan, Huan ACS Catalysis, Vol. 7, Issue 1 https://doi.org/10.1021/acscatal.6b02685	journal	December 2016
Oxygen Vacancy Promoting Dimethyl Carbonate Synthesis from CO ₂ and Methanol over Zr-Doped CeO ₂ Nanorods Liu, Bin; Li, Congming; Zhang, Guoqiang ACS Catalysis, Vol. 8, Issue 11 https://doi.org/10.1021/acscatal.8b00415	journal	October 2018
Catalytic CO Oxidation over Au Nanoparticles Supported on CeO 2 Nanocrystals: Effect of the Au–CeO 2 Interface Ha, Hyunwoo; Yoon, Sinmyung; An, Kwangjin ACS Catalysis, Vol. 8, Issue 12 https://doi.org/10.1021/acscatal.8b03539	journal	October 2018
Stabilizing High Metal Loadings of Thermally Stable Platinum Single Atoms on an Industrial Catalyst Support Kunwar, Deepak; Zhou, Shulan; DeLaRiva, Andrew ACS Catalysis, Vol. 9, Issue 5 https://doi.org/10.1021/acscatal.8b04885	journal	February 2019
Modular Pd/Zeolite Composites Demonstrating the Key Role of Support Hydrophobic/Hydrophilic Character in Methane Catalytic Combustion Losch, Pit; Huang, Weixin; Vozniuk, Olena ACS Catalysis, Vol. 9, Issue 6 https://doi.org/10.1021/acscatal.9b00596	journal	April 2019
Getting Insights into the Temperature-Specific Active Sites on Platinum Nanoparticles for CO Oxidation: A Combined in Situ Spectroscopic and ab Initio Density Functional Theory Study Liu, Annai; Liu, Xiao; Liu, Lichen ACS Catalysis, Vol. 9, Issue 9 https://doi.org/10.1021/acscatal.9b02552	journal	July 2019
Effects of Zr Doping into Ceria for the Dry Reforming of Methane over Ni/CeZrO ₂ Catalysts: In Situ Studies with XRD, XAFS, and AP-XPS Zhang, Feng; Liu, Zongyuan; Chen, Xiaobo ACS Catalysis, Vol. 10, Issue 5 https://doi.org/10.1021/acscatal.9b04451	journal	January 2020
Concentration of Ce ³⁺ and Oxygen Vacancies in Cerium Oxide Nanoparticles Dutta, P.; Pal, S.; Seehra, M. S. Chemistry of Materials, Vol. 18, Issue 21 https://doi.org/10.1021/cm061580n	journal	October 2006
Thermally Stable Pt/CeO₂ Hetero-Nanocomposites with High Catalytic Activity Zhou, Huan-Ping; Wu, Hao-Shuai; Shen, Jie Journal of the American Chemical Society, Vol. 132, Issue 14, p. 4998-4999 https://doi.org/10.1021/ja101110m	journal	April 2010
Quantitative and Atomic-Scale View of CO-Induced Pt Nanoparticle Surface Reconstruction at Saturation Coverage via DFT Calculations Coupled with in Situ TEM and IR Avanesian, Talin; Dai, Sheng; Kale, Matthew J. Journal of the American Chemical Society, Vol. 139, Issue 12 https://doi.org/10.1021/jacs.7b01081	journal	March 2017
Enhanced Thermal Stability and Oxygen Storage Capacity for Ce _x Zr _1- _x O ₂ ( x = 0.4−0.6) Solid Solutions by Hydrothermally Homogenous Doping of Trivalent Rare Earths Si, Rui; Zhang, Ya-Wen; Wang, Li-Min The Journal of Physical Chemistry C, Vol. 111, Issue 2 https://doi.org/10.1021/jp0630875	journal	January 2007
Structural Features and Catalytic Properties of Pt/CeO ₂ Catalysts Prepared by Modified Reduction-Deposition Techniques Tang, Xiaolan; Zhang, Baocai; Li, Yong Catalysis Letters, Vol. 97, Issue 3/4 https://doi.org/10.1023/B:CATL.0000038579.19128.32	journal	September 2004
Creating single-atom Pt-ceria catalysts by surface step decoration Dvořák, Filip; Farnesi Camellone, Matteo; Tovt, Andrii Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms10801	journal	February 2016
Tuning Pt-CeO2 interactions by high-temperature vapor-phase synthesis for improved reducibility of lattice oxygen Pereira-Hernández, Xavier Isidro; DeLaRiva, Andrew; Muravev, Valery Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-09308-5	journal	March 2019
Surpassing the single-atom catalytic activity limit through paired Pt-O-Pt ensemble built from isolated Pt1 atoms Wang, Hui; Liu, Jin-Xun; Allard, Lawrence F. Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-11856-9	journal	August 2019
Opportunities and challenges in the development of advanced materials for emission control catalysts Datye, Abhaya K.; Votsmeier, Martin Nature Materials https://doi.org/10.1038/s41563-020-00805-3	journal	October 2020
Highly durable metal ensemble catalysts with full dispersion for automotive applications beyond single-atom catalysts Jeong, Hojin; Kwon, Ohmin; Kim, Beom-Sik Nature Catalysis, Vol. 3, Issue 4 https://doi.org/10.1038/s41929-020-0427-z	journal	February 2020
Investigation of the physicochemical properties and catalytic activities of Ce _0.67 M _0.33 O ₂ (M = Zr ⁴⁺ , Ti ⁴⁺ , Sn ⁴⁺ ) solid solutions for NO removal by CO Yao, Xiaojiang; Tang, Changjin; Ji, Zeyang Catal. Sci. Technol., Vol. 3, Issue 3 https://doi.org/10.1039/C2CY20610B	journal	January 2013
Development of a thermally stable Pt catalyst by redispersion between CeO ₂ and Al ₂ O ₃ Lan, Li; Huang, Xin; Zhou, Weiqi RSC Advances, Vol. 11, Issue 12 https://doi.org/10.1039/D1RA00059D	journal	January 2021
Surface characterization of modified aluminas. Part 4.—Surface hydration and Lewis acidity of CeO ₂ –Al ₂ O ₃ systems Morterra, Claudio; Bolis, Vera; Magnacca, Giuliana J. Chem. Soc., Faraday Trans., Vol. 92, Issue 11 https://doi.org/10.1039/FT9969201991	journal	January 1996
Stabilisation of nanostructured Ce0.2Zr0.8O2 solid solution by impregnation on Al2O3: a suitable method for the production of thermally stable oxygen storage/release promoters for three-way catalysts Di Monte, R.; Fornasiero, P.; Kašpar, J. Chemical Communications, Issue 21 https://doi.org/10.1039/b006674p	journal	January 2000
Synthesis, structure and catalytic properties of Zr–Ce–Pr–O mixed oxides Rossignol, Sylvie; Descorme, Claude; Kappenstein, Charles Journal of Materials Chemistry, Vol. 11, Issue 10 https://doi.org/10.1039/b102763h	journal	January 2001
Catalytic Properties of Ceria and CeO ₂ -Containing Materials Trovarelli, Alessandro Catalysis Reviews, Vol. 38, Issue 4 https://doi.org/10.1080/01614949608006464	journal	November 1996
Control of Metal Nanocrystal Size Reveals Metal-Support Interface Role for Ceria Catalysts Cargnello, M.; Doan-Nguyen, V. V. T.; Gordon, T. R. Science, Vol. 341, Issue 6147 https://doi.org/10.1126/science.1240148	journal	July 2013
Identification of active sites in CO oxidation and water-gas shift over supported Pt catalysts Ding, K.; Gulec, A.; Johnson, A. M. Science, Vol. 350, Issue 6257 https://doi.org/10.1126/science.aac6368	journal	September 2015
Thermally stable single-atom platinum-on-ceria catalysts via atom trapping Jones, J.; Xiong, H.; DeLaRiva, A. T. Science, Vol. 353, Issue 6295 https://doi.org/10.1126/science.aaf8800	journal	July 2016
Activation of surface lattice oxygen in single-atom Pt/CeO ₂ for low-temperature CO oxidation Nie, Lei; Mei, Donghai; Xiong, Haifeng Science, Vol. 358, Issue 6369 https://doi.org/10.1126/science.aao2109	journal	December 2017

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
CO oxidation
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incipient wetness impregnation
oxygen storage capacity
thermal stability

Title: Highly efficient Pt catalyst on newly designed CeO2-ZrO2-Al2O3 support for catalytic removal of pollutants from vehicle exhaust

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Title: Highly efficient Pt catalyst on newly designed CeO₂-ZrO₂-Al₂O₃ support for catalytic removal of pollutants from vehicle exhaust