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Title: The chemical and physical origin of incineration ash reactivity in cementitious systems

Abstract

Incorporating industrial byproducts and waste in concrete is the key to reducing landfill usage as well as lowering the environmental footprint of cement industry. An emerging industrial byproduct which can partly replace cement is the Municipal Solid Waste Incinerator Ash (MSWI ash: residue that is left after incineration of municipal solid waste in a Waste-to-Energy facility). These ashes are predominantly calcium-rich; however, they also contain additional elements whose speciation is not known. These elements can significantly alter the hydration characteristics of a cementitious system. Here, our results suggest these ashes can accelerate as well as retard cement hydration. Specifically, Pb, Br, S, Ca, and Cl appear to accelerate cement hydration, whereas Cu, Fe, Al, Ti, Si, K, Zn, and Sr appear to retard cement hydration. Changes in hydration characteristics can have a strong bearing on the physical characteristics of cementitious systems incorporating incineration ashes. Thus, to selectively screen ashes that synergistically enhance the physical characteristics, we introduce a novel “Incineration Ash Coefficient (IAC),” which shows a strong correlation with the compressive strength (R2=0.79) of cement-ash binary mixtures.

Authors:
 [1];  [1]
  1. Univ. of Illinois at Urbana-Champaign, IL (United States)
Publication Date:
Research Org.:
Univ. of Illinois at Urbana-Champaign, IL (United States)
Sponsoring Org.:
USDOE Advanced Research Projects Agency - Energy (ARPA-E)
OSTI Identifier:
1828778
Grant/Contract Number:  
AR0001401
Resource Type:
Accepted Manuscript
Journal Name:
Resources, Conservation and Recycling
Additional Journal Information:
Journal Volume: 177; Journal ID: ISSN 0921-3449
Publisher:
Elsevier
Country of Publication:
United States
Language:
English
Subject:
54 ENVIRONMENTAL SCIENCES; 42 ENGINEERING; 99 GENERAL AND MISCELLANEOUS; Cement; Waste to Energy; Municipal Solid Waste Incineration Ashes

Citation Formats

Kumar, Vikram, and Garg, Nishant. The chemical and physical origin of incineration ash reactivity in cementitious systems. United States: N. p., 2021. Web. doi:10.1016/j.resconrec.2021.106009.
Kumar, Vikram, & Garg, Nishant. The chemical and physical origin of incineration ash reactivity in cementitious systems. United States. https://doi.org/10.1016/j.resconrec.2021.106009
Kumar, Vikram, and Garg, Nishant. Fri . "The chemical and physical origin of incineration ash reactivity in cementitious systems". United States. https://doi.org/10.1016/j.resconrec.2021.106009. https://www.osti.gov/servlets/purl/1828778.
@article{osti_1828778,
title = {The chemical and physical origin of incineration ash reactivity in cementitious systems},
author = {Kumar, Vikram and Garg, Nishant},
abstractNote = {Incorporating industrial byproducts and waste in concrete is the key to reducing landfill usage as well as lowering the environmental footprint of cement industry. An emerging industrial byproduct which can partly replace cement is the Municipal Solid Waste Incinerator Ash (MSWI ash: residue that is left after incineration of municipal solid waste in a Waste-to-Energy facility). These ashes are predominantly calcium-rich; however, they also contain additional elements whose speciation is not known. These elements can significantly alter the hydration characteristics of a cementitious system. Here, our results suggest these ashes can accelerate as well as retard cement hydration. Specifically, Pb, Br, S, Ca, and Cl appear to accelerate cement hydration, whereas Cu, Fe, Al, Ti, Si, K, Zn, and Sr appear to retard cement hydration. Changes in hydration characteristics can have a strong bearing on the physical characteristics of cementitious systems incorporating incineration ashes. Thus, to selectively screen ashes that synergistically enhance the physical characteristics, we introduce a novel “Incineration Ash Coefficient (IAC),” which shows a strong correlation with the compressive strength (R2=0.79) of cement-ash binary mixtures.},
doi = {10.1016/j.resconrec.2021.106009},
journal = {Resources, Conservation and Recycling},
number = ,
volume = 177,
place = {United States},
year = {2021},
month = {10}
}

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