A switchable sensor and scavenger: detection and removal of fluorinated chemical species by a luminescent metal–organic framework

Yin, Hua-Qing; Tan, Kui; Jensen, Stephanie; Teat, Simon J.; Ullah, Saif; Hei, Xiuze; Velasco, Ever; Oyekan, Kolade; Meyer, Noah; Wang, Xin-Yao; Thonhauser, Timo; Yin, Xue-Bo; Li, Jing

doi:10.1039/D1SC04070G

Title: A switchable sensor and scavenger: detection and removal of fluorinated chemical species by a luminescent metal–organic framework

Journal Article · 02 November 2021 · Chemical Science

DOI: https://doi.org/10.1039/D1SC04070G · OSTI ID:1825773

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Department of Chemistry and Chemical Biology; Rutgers University; 123 Bevier Road; Piscataway; NJ 08854; USA; State Key Laboratory of Medicinal Chemical Biology; Tianjin Key Laboratory of Biosensing and Molecular Recognition; College of Chemistry; Nankai University; 94 Weijin Road; Tianjin 300071; P. R. China; Institute for New Energy Materials and Low Carbon Technologies; School of Materials Science & Engineering; Tianjin University of Technology; 391 Bin Shui Xi Dao Road; Tianjin 300384; P. R. China
Materials Science and Engineering, The University of Texas at Dallas, 800 W. Campbell Road, Richardson, TX 75080, USA
Department of Physics and Center for Functional Materials, Wake Forest University, 1834 Wake Forest Road, Winston–Salem, NC 27109, USA
Advanced Light Source, Lawrence Berkeley National Laboratory, 1 Cyclotron Road, Berkeley, CA 94720, USA
Department of Chemistry and Chemical Biology, Rutgers University, 123 Bevier Road, Piscataway, NJ 08854, USA
State Key Laboratory of Medicinal Chemical Biology, Tianjin Key Laboratory of Biosensing and Molecular Recognition, College of Chemistry, Nankai University, 94 Weijin Road, Tianjin 300071, P. R. China

A robust In-MOF, In(tcpp), demonstrates sensitive detection of the fluorinated chemical species F ⁻ and PFOA via distinctly different luminescence signal change, and effective adsorption and removal of both species from aqueous solution.

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Research Organization:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States); Wake Forest Univ., Winston-Salem, NC (United States)

Sponsoring Organization:: China Scholarship Council (CSC); National Natural Science Foundation of China (NSFC); USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-05CH11231; SC0019902

OSTI ID:: 1825773

Journal Information:: Chemical Science, Journal Name: Chemical Science Journal Issue: 42 Vol. 12; ISSN 2041-6520; ISSN CSHCBM

Publisher:: Royal Society of Chemistry (RSC)Copyright Statement

Country of Publication:: United Kingdom

Language:: English

References (52)

Thermoreversible Self-Assembly of Perfluorinated Core-Coronas Cellulose-Nanoparticles in Dry State Wang, Yonggui; Groszewicz, Pedro B.; Rosenfeldt, Sabine Advanced Materials, Vol. 29, Issue 43 https://doi.org/10.1002/adma.201702473	journal	October 2017
Stable Metal-Organic Frameworks: Design, Synthesis, and Applications Yuan, Shuai; Feng, Liang; Wang, Kecheng Advanced Materials, Vol. 30, Issue 37 https://doi.org/10.1002/adma.201704303	journal	February 2018
Graphene Oxide‐Based Sensor for Ultrasensitive Visual Detection of Fluoride Mandal, Tapas K.; Hou, Yi; Gao, Zhenyu Advanced Science, Vol. 3, Issue 12 https://doi.org/10.1002/advs.201600217	journal	July 2016
Selective and Efficient Removal of Fluoride from Water: In Situ Engineered Amyloid Fibril/ZrO ₂ Hybrid Membranes Zhang, Qingrui; Bolisetty, Sreenath; Cao, Yiping Angewandte Chemie International Edition, Vol. 58, Issue 18 https://doi.org/10.1002/anie.201901596	journal	April 2019
Perfluoroalkyl and polyfluoroalkyl substances in the environment: Terminology, classification, and origins Buck, Robert C.; Franklin, James; Berger, Urs Integrated Environmental Assessment and Management, Vol. 7, Issue 4 https://doi.org/10.1002/ieam.258	journal	September 2011
A review of global outlook on fluoride contamination in groundwater with prominence on the Pakistan current situation Rasool, Atta; Farooqi, Abida; Xiao, Tangfu Environmental Geochemistry and Health, Vol. 40, Issue 4 https://doi.org/10.1007/s10653-017-0054-z	journal	December 2017
Underneath mechanisms into the super effective degradation of PFOA by BiOF nanosheets with tunable oxygen vacancies on exposed (101) facets Wang, Jingzhen; Cao, Chunshuai; Zhang, Ying Applied Catalysis B: Environmental, Vol. 286 https://doi.org/10.1016/j.apcatb.2021.119911	journal	June 2021
Imaging-based fluorescent sensing platform for quantitative monitoring and visualizing of fluoride ions with dual-emission quantum dots hybrid Zhang, Jian; Qian, Jingjing; Mei, Qingsong Biosensors and Bioelectronics, Vol. 128 https://doi.org/10.1016/j.bios.2018.12.044	journal	March 2019
Molecular mechanisms of fluoride toxicity Barbier, Olivier; Arreola-Mendoza, Laura; Del Razo, Luz María Chemico-Biological Interactions, Vol. 188, Issue 2 https://doi.org/10.1016/j.cbi.2010.07.011	journal	November 2010
Simultaneous detection and removal of fluoride from water using smart metal-organic framework-based adsorbents Ahmadijokani, Farhad; Molavi, Hossein; Rezakazemi, Mashallah Coordination Chemistry Reviews, Vol. 445 https://doi.org/10.1016/j.ccr.2021.214037	journal	October 2021
Smartphone app-based/portable sensor for the detection of fluoro-surfactant PFOA Fang, Cheng; Zhang, Xian; Dong, Zhaomin Chemosphere, Vol. 191 https://doi.org/10.1016/j.chemosphere.2017.10.057	journal	January 2018
Evaluation of vascular and kidney injury biomarkers in Mexican children exposed to inorganic fluoride Jiménez-Córdova, Mónica I.; González-Horta, Carmen; Ayllón-Vergara, Julio C. Environmental Research, Vol. 169 https://doi.org/10.1016/j.envres.2018.10.028	journal	February 2019
Monitoring emerging contaminants in the drinking water of Milan and assessment of the human risk Riva, Francesco; Castiglioni, Sara; Fattore, Elena International Journal of Hygiene and Environmental Health, Vol. 221, Issue 3 https://doi.org/10.1016/j.ijheh.2018.01.008	journal	April 2018
Simple and fast determination of perfluorinated compounds in Taihu Lake by SPE-UHPLC–MS/MS Zhu, Pengfei; Ling, Xia; Liu, Wenwei Journal of Chromatography B, Vol. 1031 https://doi.org/10.1016/j.jchromb.2016.07.031	journal	September 2016
Adsorption behavior and mechanism of perfluorinated compounds on various adsorbents—A review Du, Ziwen; Deng, Shubo; Bei, Yue Journal of Hazardous Materials, Vol. 274 https://doi.org/10.1016/j.jhazmat.2014.04.038	journal	June 2014
Smartphone as a simple device for visual and on-site detection of fluoride in groundwater Tian, Yayang; Che, Huachao; Wang, Jiahuan Journal of Hazardous Materials, Vol. 411 https://doi.org/10.1016/j.jhazmat.2021.125182	journal	June 2021
Electrochemical adsorption of perfluorooctanoic acid on a novel reduced graphene oxide aerogel loaded with Cu nanoparticles and fluorine Liu, Longfei; Liu, Yanli; Che, Naiju Journal of Hazardous Materials, Vol. 416 https://doi.org/10.1016/j.jhazmat.2021.125866	journal	August 2021
An erythrosin B-based “turn on” fluorescent sensor for detecting perfluorooctane sulfonate and perfluorooctanoic acid in environmental water samples Cheng, Zhen; Du, Lingling; Zhu, Panpan Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, Vol. 201 https://doi.org/10.1016/j.saa.2018.05.013	journal	August 2018
Genotypic variation and mechanism in uptake and translocation of perfluorooctanoic acid (PFOA) in lettuce (Lactuca sativa L.) cultivars grown in PFOA-polluted soils Xiang, Lei; Chen, Lei; Yu, Le-Yi Science of The Total Environment, Vol. 636 https://doi.org/10.1016/j.scitotenv.2018.04.354	journal	September 2018
Core-shell quantum dots coated with molecularly imprinted polymer for selective photoluminescence sensing of perfluorooctanoic acid Zheng, Li; Zheng, Yonghong; Liu, Yang Talanta, Vol. 194 https://doi.org/10.1016/j.talanta.2018.09.106	journal	March 2019
Luminescent metal organic frameworks–based chemiluminescence resonance energy transfer platform for turn–on detection of fluoride ion Sun, Yuan; Xu, Xiaotong; Zhao, Yaxin Talanta, Vol. 209 https://doi.org/10.1016/j.talanta.2019.120582	journal	March 2020
An interlaboratory study on passive sampling of emerging water pollutants Vrana, Branislav; Smedes, Foppe; Prokeš, Roman TrAC Trends in Analytical Chemistry, Vol. 76 https://doi.org/10.1016/j.trac.2015.10.013	journal	February 2016
Boric-Acid-Functional Lanthanide Metal–Organic Frameworks for Selective Ratiometric Fluorescence Detection of Fluoride Ions Yang, Zhong-Rui; Wang, Man-Man; Wang, Xue-Sheng Analytical Chemistry, Vol. 89, Issue 3 https://doi.org/10.1021/acs.analchem.6b04421	journal	January 2017
Removal of Pharmaceuticals from Water via π–π Stacking Interactions in Perfluorinated Metal–Organic Frameworks DeFuria, Mariah D.; Zeller, Matthias; Genna, Douglas T. Crystal Growth & Design, Vol. 16, Issue 6 https://doi.org/10.1021/acs.cgd.6b00488	journal	May 2016
Structure-Driven Photoluminescence Enhancement in a Zn-Based Metal–Organic Framework Jensen, Stephanie; Tan, Kui; Lustig, William P. Chemistry of Materials, Vol. 31, Issue 19 https://doi.org/10.1021/acs.chemmater.9b02056	journal	September 2019
Water and Metal–Organic Frameworks: From Interaction toward Utilization Liu, Xinlei; Wang, Xuerui; Kapteijn, Freek Chemical Reviews, Vol. 120, Issue 16 https://doi.org/10.1021/acs.chemrev.9b00746	journal	May 2020
Exceptionally Robust In-Based Metal–Organic Framework for Highly Efficient Carbon Dioxide Capture and Conversion Liu, Lin; Wang, Shi-Ming; Han, Zheng-Bo Inorganic Chemistry, Vol. 55, Issue 7 https://doi.org/10.1021/acs.inorgchem.6b00050	journal	March 2016
Synthesis of Mg/Al Layered Double Hydroxides for Adsorptive Removal of Fluoride from Water: A Mechanistic and Kinetic Study Sarma, Gautam Kumar; Rashid, Md. Harunar Journal of Chemical & Engineering Data, Vol. 63, Issue 8 https://doi.org/10.1021/acs.jced.8b00242	journal	June 2018
The p K _a Values of PFOA and Other Highly Fluorinated Carboxylic Acids Goss, Kai-Uwe Environmental Science & Technology, Vol. 42, Issue 2 https://doi.org/10.1021/es702192c	journal	January 2008
Perfluorooctanesulfonate and Related Fluorochemicals in the Amur Tiger (Panthera tigris altaica) from China Li, Xuemei; Yeung, Leo W. Y.; Taniyasu, Sachi Environmental Science & Technology, Vol. 42, Issue 19 https://doi.org/10.1021/es801453d	journal	August 2008
A Luminescent Microporous Metal−Organic Framework for the Recognition and Sensing of Anions Chen, Banglin; Wang, Liangbo; Zapata, Fatima Journal of the American Chemical Society, Vol. 130, Issue 21 https://doi.org/10.1021/ja802035e	journal	May 2008
Kinetically Controlled Reticular Assembly of a Chemically Stable Mesoporous Ni(II)-Pyrazolate Metal–Organic Framework He, Tao; Huang, Zhehao; Yuan, Shuai Journal of the American Chemical Society, Vol. 142, Issue 31 https://doi.org/10.1021/jacs.0c05074	journal	July 2020
A Practice of Reticular Chemistry: Construction of a Robust Mesoporous Palladium Metal–Organic Framework via Metal Metathesis He, Tao; Kong, Xiang-Jing; Zhou, Jian Journal of the American Chemical Society, Vol. 143, Issue 26 https://doi.org/10.1021/jacs.1c04077	journal	June 2021
Highly Stable Zr(IV)-Based Metal–Organic Frameworks for the Detection and Removal of Antibiotics and Organic Explosives in Water Wang, Bin; Lv, Xiu-Liang; Feng, Dawei Journal of the American Chemical Society, Vol. 138, Issue 19 https://doi.org/10.1021/jacs.6b01663	journal	May 2016
Non-Fullerene Polymer Solar Cells Based on Alkylthio and Fluorine Substituted 2D-Conjugated Polymers Reach 9.5% Efficiency Bin, Haijun; Zhang, Zhi-Guo; Gao, Liang Journal of the American Chemical Society, Vol. 138, Issue 13 https://doi.org/10.1021/jacs.6b01744	journal	March 2016
A Base-Resistant Metalloporphyrin Metal–Organic Framework for C–H Bond Halogenation Lv, Xiu-Liang; Wang, Kecheng; Wang, Bin Journal of the American Chemical Society, Vol. 139, Issue 1 https://doi.org/10.1021/jacs.6b09463	journal	December 2016
Selective, Fast-Response, and Regenerable Metal–Organic Framework for Sampling Excess Fluoride Levels in Drinking Water Ebrahim, Fatmah Mish; Nguyen, Tu N.; Shyshkanov, Serhii Journal of the American Chemical Society, Vol. 141, Issue 7 https://doi.org/10.1021/jacs.8b11907	journal	February 2019
Rotation Restricted Emission and Antenna Effect in Single Metal–Organic Frameworks Yin, Hua-Qing; Wang, Xin-Yao; Yin, Xue-Bo Journal of the American Chemical Society, Vol. 141, Issue 38 https://doi.org/10.1021/jacs.9b06755	journal	September 2019
A stable zirconium based metal-organic framework for specific recognition of representative polychlorinated dibenzo-p-dioxin molecules Wang, Bin; Wang, Peilong; Xie, Lin-Hua Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-11912-4	journal	August 2019
Impact of Drinking Water Fluoride on Human Thyroid Hormones: A Case- Control Study Kheradpisheh, Zohreh; Mirzaei, Masoud; Mahvi, Amir Hossein Scientific Reports, Vol. 8, Issue 1 https://doi.org/10.1038/s41598-018-20696-4	journal	February 2018
Highly sensitive and selective fluoride detection in water through fluorophore release from a metal-organic framework Hinterholzinger, Florian M.; Rühle, Bastian; Wuttke, Stefan Scientific Reports, Vol. 3, Issue 1 https://doi.org/10.1038/srep02562	journal	September 2013
A fluorescent probe for rapid aqueous fluoride detection and cell imaging Ke, Bowen; Chen, Weixuan; Ni, Nanting Chem. Commun., Vol. 49, Issue 25 https://doi.org/10.1039/C2CC37270C	journal	January 2013
Lewis acidic stiborafluorenes for the fluorescence turn-on sensing of fluoride in drinking water at ppm concentrations Hirai, Masato; Gabbaï, François P. Chem. Sci., Vol. 5, Issue 5 https://doi.org/10.1039/C4SC00343H	journal	January 2014
Rationally designed upconversion nanoprobe for simultaneous highly sensitive ratiometric detection of fluoride ions and fluorosis theranostics Liu, Yuxin; Jiang, Anqi; Jia, Qi Chemical Science, Vol. 9, Issue 23 https://doi.org/10.1039/C8SC00670A	journal	January 2018
Quenching of photoluminescence in a Zn-MOF sensor by nitroaromatic molecules Jensen, S.; Tan, K.; Lustig, W. Journal of Materials Chemistry C, Vol. 7, Issue 9 https://doi.org/10.1039/C8TC06281A	journal	January 2019
Switchable electrical conductivity in a three-dimensional metal–organic framework via reversible ligand n-doping Wentz, Hanna C.; Skorupskii, Grigorii; Bonfim, Ana B. Chemical Science, Vol. 11, Issue 5 https://doi.org/10.1039/C9SC06150A	journal	January 2020
Fluoride in Drinking Water: A Review on the Status and Stress Effects Ayoob, S.; Gupta, A. K. Critical Reviews in Environmental Science and Technology, Vol. 36, Issue 6 https://doi.org/10.1080/10643380600678112	journal	December 2006
Fluoride Ion Toxicity in Human Kidney Collecting Duct Cells Cittanova, Marie-Laure; Lelongt, Brigitte; Verpont, Marie-Christine Anesthesiology, Vol. 84, Issue 2 https://doi.org/10.1097/00000542-199602000-00022	journal	February 1996
Prevention and reversal of dental caries: role of low level fluoride Featherstone, John D. B. Community Dentistry and Oral Epidemiology, Vol. 27, Issue 1 https://doi.org/10.1111/j.1600-0528.1999.tb01989.x	journal	February 1999
The Exposure Experience: Ohio River Valley Residents Respond to Local Perfluorooctanoic Acid (PFOA) Contamination Judge, J. Matthew; Brown, Phil; Brody, Julia Green Journal of Health and Social Behavior, Vol. 57, Issue 3 https://doi.org/10.1177/0022146516661595	journal	September 2016
In Vivo Comparison of the Phenotypic Aspects and Molecular Mechanisms of Two Nephrotoxic Agents, Sodium Fluoride and Uranyl Nitrate Bontemps, Alice; Conquet, Laurine; Elie, Christelle International Journal of Environmental Research and Public Health, Vol. 16, Issue 7 https://doi.org/10.3390/ijerph16071136	journal	March 2019
Survey of Fluoride Concentration in Drinking Water Sources and Prevalence of DMFT in the 12 Years Old Students in Behshar City ., A. H. Mahvi; ., M. A. Zazoli; ., M. Younecian Journal of Medical Sciences, Vol. 6, Issue 4 https://doi.org/10.3923/jms.2006.658.661	journal	June 2006

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