Unconventional Thermoelectric Materials for Energy Harvesting and Sensing Applications

Massetti, Matteo; Jiao, Fei; Ferguson, Andrew J.; Zhao, Dan; Wijeratne, Kosala; Würger, Alois; Blackburn, Jeffrey L.; Crispin, Xavier; Fabiano, Simone

doi:10.1021/acs.chemrev.1c00218

Title: Unconventional Thermoelectric Materials for Energy Harvesting and Sensing Applications

Abstract

Heat is an abundant but often wasted source of energy. Thus, harvesting just a portion of this tremendous amount of energy holds significant promise for a more sustainable society. While traditional solid-state inorganic semiconductors have dominated the research stage on thermal-to-electrical energy conversion, carbon-based semiconductors have recently attracted a great deal of attention as potential thermoelectric materials for low-temperature energy harvesting, primarily driven by the high abundance of their atomic elements, ease of processing/manufacturing, and intrinsically low thermal conductivity. This quest for new materials has resulted in the discovery of several new kinds of thermoelectric materials and concepts capable of converting a heat flux into an electrical current by means of various types of particles transporting the electric charge: (i) electrons, (ii) ions, and (iii) redox molecules. This has contributed to expanding the applications envisaged for thermoelectric materials far beyond simple conversion of heat into electricity. This is the motivation behind this review. This work is divided in three sections. In the first section, we present the basic principle of the thermoelectric effects when the particles transporting the electric charge are electrons, ions, and redox molecules and describe the conceptual differences between the three thermodiffusion phenomena. In the second section,more »« less

Authors:

Massetti, Matteo ^[1];

^[2];

^[3]; Zhao, Dan ^[1]; Wijeratne, Kosala ^[1]; Würger, Alois ^[4];

^[3];

^[1];

^[1]

Linköping Univ., Norrköping (Sweden)
Linköping Univ., Norrköping (Sweden); Tianjin Univ. & Collaborative Innovation Center of Chemical Science and Engineering (China)
National Renewable Energy Lab. (NREL), Golden, CO (United States)
Univ. of Bordeaux, Talence (France)

Publication Date:: Mon Aug 16 00:00:00 EDT 2021

Research Org.:: National Renewable Energy Laboratory (NREL), Golden, CO (United States)

Sponsoring Org.:: USDOE Office of Energy Efficiency and Renewable Energy (EERE); Alice Wallenberg Foundation; Swedish Research Council (SRC); Olle Engkvists Stiftelse; Marie Sklodowska-Curie Foundation; Linkoping University

OSTI Identifier:: 1821642

Report Number(s):: NREL/JA-5K00-79566
Journal ID: ISSN 0009-2665; MainId:35787;UUID:43e60368-408d-4223-a7c1-56b835220c58;MainAdminID:62891

Grant/Contract Number:: AC36-08GO28308; 2016-03979; 2020-03243; 18-313; 19-310; 204-0256; GA-955837; SFO-Mat-LiU 2009-00971

Resource Type:: Accepted Manuscript

Journal Name:: Chemical Reviews

Additional Journal Information:: Journal Volume: 121; Journal Issue: 20; Journal ID: ISSN 0009-2665

Publisher:: American Chemical Society

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; carbon nanotube; graphene; organic semiconductor; polymer; thermoelectric; electrodes; thermoelectric materials; power; electrolytes

Citation Formats


                    Massetti, Matteo, Jiao, Fei, Ferguson, Andrew J., Zhao, Dan, Wijeratne, Kosala, Würger, Alois, Blackburn, Jeffrey L., Crispin, Xavier, and Fabiano, Simone. Unconventional Thermoelectric Materials for Energy Harvesting and Sensing Applications.  United States: N. p., 2021. 
Web.  doi:10.1021/acs.chemrev.1c00218.

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                    Massetti, Matteo, Jiao, Fei, Ferguson, Andrew J., Zhao, Dan, Wijeratne, Kosala, Würger, Alois, Blackburn, Jeffrey L., Crispin, Xavier, & Fabiano, Simone. Unconventional Thermoelectric Materials for Energy Harvesting and Sensing Applications.  United States.  https://doi.org/10.1021/acs.chemrev.1c00218

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                    Massetti, Matteo, Jiao, Fei, Ferguson, Andrew J., Zhao, Dan, Wijeratne, Kosala, Würger, Alois, Blackburn, Jeffrey L., Crispin, Xavier, and Fabiano, Simone. Mon .  
"Unconventional Thermoelectric Materials for Energy Harvesting and Sensing Applications".  United States.  https://doi.org/10.1021/acs.chemrev.1c00218.  https://www.osti.gov/servlets/purl/1821642.

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@article{osti_1821642,

  title        = {Unconventional Thermoelectric Materials for Energy Harvesting and Sensing Applications},

  author       = {Massetti, Matteo and Jiao, Fei and Ferguson, Andrew J. and Zhao, Dan and Wijeratne, Kosala and Würger, Alois and Blackburn, Jeffrey L. and Crispin, Xavier and Fabiano, Simone},

  abstractNote = {Heat is an abundant but often wasted source of energy. Thus, harvesting just a portion of this tremendous amount of energy holds significant promise for a more sustainable society. While traditional solid-state inorganic semiconductors have dominated the research stage on thermal-to-electrical energy conversion, carbon-based semiconductors have recently attracted a great deal of attention as potential thermoelectric materials for low-temperature energy harvesting, primarily driven by the high abundance of their atomic elements, ease of processing/manufacturing, and intrinsically low thermal conductivity. This quest for new materials has resulted in the discovery of several new kinds of thermoelectric materials and concepts capable of converting a heat flux into an electrical current by means of various types of particles transporting the electric charge: (i) electrons, (ii) ions, and (iii) redox molecules. This has contributed to expanding the applications envisaged for thermoelectric materials far beyond simple conversion of heat into electricity. This is the motivation behind this review. This work is divided in three sections. In the first section, we present the basic principle of the thermoelectric effects when the particles transporting the electric charge are electrons, ions, and redox molecules and describe the conceptual differences between the three thermodiffusion phenomena. In the second section, we review the efforts made on developing devices exploiting these three effects and give a thorough understanding of what limits their performance. In the third section, we review the state-of-the-art thermoelectric materials investigated so far and provide a comprehensive understanding of what limits charge and energy transport in each of these classes of materials.},

  doi          = {10.1021/acs.chemrev.1c00218},

  journal      = {Chemical Reviews},

  number       = 20,

  volume       = 121,

  place        = {United States},

  year         = {Mon Aug 16 00:00:00 EDT 2021},

  month        = {Mon Aug 16 00:00:00 EDT 2021}

}

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High Thermoelectric Performance in n‐Type Perylene Bisimide Induced by the Soret Effect journal, September 2020

Enhancement of Thermoelectric Performance in Oligomeric PEDOT-SWCNT Nanocomposite via Band Gap Tuning journal, August 2018

Aqueous thermogalvanic cells with a high Seebeck coefficient for low-grade heat harvest journal, December 2018

Thermoelectric effects in graphene nanostructures journal, March 2015

Conductivity, thermoelectric power and field-effect mobility in self-assembled films of polyanilines and oligoanilines journal, February 1995

Thermogalvanic cells with aqueous redox couples and temperature differences larger than 100 K journal, May 1993

Enhanced thermoelectric properties of copper phthalocyanine/single-walled carbon nanotubes hybrids journal, April 2020

Poly(3,4-ethylenedioxythiophene)-tosylate (PEDOT-Tos) electrodes in thermogalvanic cells journal, January 2017

Anisotropic thermoelectric power of TTF-TCNQ journal, March 1975

In situ filling of metallic single-walled carbon nanotubes with ferrocene molecules journal, October 2012

Dependence of Optical Transition Energies on Structure for Single-Walled Carbon Nanotubes in Aqueous Suspension: An Empirical Kataura Plot journal, September 2003

Flexible layer-structured Bi2Te3 thermoelectric on a carbon nanotube scaffold journal, November 2018

Enhanced Thermoelectric Performance of Single-Walled Carbon Nanotubes/Polyaniline Hybrid Nanocomposites journal, March 2010

Enhanced power factor in flexible reduced graphene oxide/nanowires hybrid films for thermoelectrics journal, January 2016

The Role of Ordering on the Thermoelectric Properties of Blends of Regioregular and Regiorandom Poly(3‐hexylthiophene) journal, April 2019

Bendable n-Type Metallic Nanocomposites with Large Thermoelectric Power Factor journal, November 2016

Electrochemistry of conducting polypyrrole films journal, November 1981

Dispenser-printed planar thick-film thermoelectric energy generators journal, September 2011

Self‐Healing and Stretchable 3D‐Printed Organic Thermoelectrics journal, October 2019

Flexible and Robust Thermoelectric Generators Based on All-Carbon Nanotube Yarn without Metal Electrodes journal, July 2017

An efficient thermoelectric material: preparation of reduced graphene oxide/polyaniline hybrid composites by cryogenic grinding journal, January 2015

N-type organic thermoelectrics: demonstration of ZT > 0.3 journal, November 2020

Thermal and Thermoelectric Properties of Graphene journal, March 2014

Strong, Light, Multifunctional Fibers of Carbon Nanotubes with Ultrahigh Conductivity journal, January 2013

Spray-Coated Multiwalled Carbon Nanotube Composite Electrodes for Thermal Energy Scavenging Electrochemical Cells journal, August 2016

Synthesis of electrically conducting organic polymers: halogen derivatives of polyacetylene, (CH) x journal, January 1977

An empirical model to predict temperature-dependent thermal conductivity of amorphous polymers journal, May 2017

Preparation of Pristine Graphene Sheets and Large-Area/Ultrathin Graphene Films for High Conducting and Transparent Applications journal, August 2013

Isotropic Seebeck coefficient of aligned single-wall carbon nanotube films journal, December 2018

Structural Dependence of Excitonic Optical Transitions and Band-Gap Energies in Carbon Nanotubes journal, November 2005

Macroscopically aligned carbon nanotubes for flexible and high-temperature electronics, optoelectronics, and thermoelectrics journal, December 2019

Enhanced thermoelectric performance of nanostructured CNTs/BiSbTe bulk composite from rapid pressure-quenching induced multi-scale microstructure journal, December 2016

Engineered Molecular Chain Ordering in Single-Walled Carbon Nanotubes/Polyaniline Composite Films for High-Performance Organic Thermoelectric Materials journal, May 2016

Graphene boosts thermoelectric performance of a Zintl phase compound journal, January 2015

Miniaturization limitations of HCCI internal combustion engines journal, February 2009

Diameter dependence of thermoelectric power of semiconducting carbon nanotubes journal, October 2015

Synthesis and Raman characterization of boron-doped single-walled carbon nanotubes journal, January 2005

Thermoelectrics: From history, a window to the future journal, October 2019

Flexible n-Type High-Performance Thermoelectric Thin Films of Poly(nickel-ethylenetetrathiolate) Prepared by an Electrochemical Method journal, March 2016

Dependence on cation size of thermally induced capacitive effect of a nanoporous carbon journal, August 2012

A novel self-powered wireless temperature sensor based on thermoelectric generators journal, April 2014

Dopant‐Dependent Increase in Seebeck Coefficient and Electrical Conductivity in Blended Polymers with Offset Carrier Energies journal, February 2019

Sequential Doping of Ladder-Type Conjugated Polymers for Thermally Stable n-Type Organic Conductors journal, November 2020

Thermoelectric properties of conducting polyaniline/graphite composites journal, April 2011

Ionic transport properties and their empirical correlations for thermal-to-electrical energy conversion journal, July 2021

Solution-fabrication dependent thermoelectric behavior of iodine-doped regioregular and regiorandom P3HT/carbon nanotube composites journal, May 2018

A review on mechanical exfoliation for the scalable production of graphene journal, January 2015

Preparation of polypyrrole/graphene nanosheets composites with enhanced thermoelectric properties journal, January 2014

Enhanced thermoelectric property by the construction of a nanocomposite 3D interconnected architecture consisting of graphene nanolayers sandwiched by polypyrrole nanowires journal, January 2015

Enhanced thermoelectric and mechanical properties of Na-doped polycrystalline SnSe thermoelectric materials via CNTs dispersion journal, April 2018

Enhanced thermoelectric performance of PEDOT with different counter-ions optimized by chemical reduction journal, January 2014

Robust PEDOT:PSS Wet‐Spun Fibers for Thermoelectric Textiles journal, February 2020

Large-scalable RTCVD Graphene/PEDOT:PSS hybrid conductive film for application in transparent and flexible thermoelectric nanogenerators journal, January 2017

Solvent effects on the kinetics of simple electrochemical reactions journal, July 1981

A three-in-one improvement in thermoelectric properties of polyaniline brought by nanostructures journal, November 2010

Achieving pseudo -‘n-type p-type’ in-series and parallel liquid thermoelectrics using all-iron thermoelectrochemical cells with opposite Seebeck coefficients journal, November 2016

Size‐ and Temperature‐Dependent Suppression of Phonon Thermal Conductivity in Carbon Nanotube Thermoelectric Films journal, October 2020

Large scale, selective dispersion of long single-walled carbon nanotubes with high photoluminescence quantum yield by shear force mixing journal, August 2016

Impurity scattering and Mott’s formula in graphene journal, November 2007

Carbon Nanotube - Reduced Graphene Oxide Composites for Thermal Energy Harvesting Applications journal, October 2013

Self-Powered Multimodal Temperature and Force Sensor Based-On a Liquid Droplet journal, November 2016

Thermoelectric Properties of Organic Charge-Transfer Compounds
journal, April 2009

Application of a water-soluble cobalt redox couple in free-standing cellulose films for thermal energy harvesting
journal, February 2019

Doping of single-walled carbon nanotube bundles by Brønsted acids
journal, January 2003

Carbon-Nanotube-Based Thermoelectric Materials and Devices
journal, January 2018

Helical microtubules of graphitic carbon
journal, November 1991

Development of carbon nanotube organic thermoelectric materials using cyclodextrin polymer: control of semiconductor characteristics by the solvent effect
journal, January 2020

Transport properties of alkali-metal-doped single-wall carbon nanotubes
journal, August 1998

Role of Polymer Structure on the Conductivity of N-Doped Polymers
journal, March 2016

Stretchable fabric generates electric power from woven thermoelectric fibers
journal, January 2020

Bulk Interpenetration Network of Thermoelectric Polymer in Insulating Supporting Matrix
journal, February 2014

A high-conductivity n-type polymeric ink for printed electronics
journal, April 2021

Reduction-Controlled Viologen in Bisolvent as an Environmentally Stable n-Type Dopant for Carbon Nanotubes
journal, January 2009

Conjugated Polymer Blends for Organic Thermoelectrics
journal, January 2019

Chloride transport in conductive polymer films for an n-type thermoelectric platform
journal, January 2020

Polyvinyl alcohol covalently grafted CNT for free-standing, flexible, and high-performance thermoelectric generator film
journal, February 2019

Power Conversion Efficiency, Electrode Separation, and Overpotential in the Ferricyanide/Ferrocyanide Thermogalvanic Cell
journal, August 1996

High Thermoelectric Performance in n‐Type Perylene Bisimide Induced by the Soret Effect
journal, September 2020

Enhancement of Thermoelectric Performance in Oligomeric PEDOT-SWCNT Nanocomposite via Band Gap Tuning
journal, August 2018

Aqueous thermogalvanic cells with a high Seebeck coefficient for low-grade heat harvest
journal, December 2018

Thermoelectric effects in graphene nanostructures
journal, March 2015

Conductivity, thermoelectric power and field-effect mobility in self-assembled films of polyanilines and oligoanilines
journal, February 1995

Thermogalvanic cells with aqueous redox couples and temperature differences larger than 100 K
journal, May 1993

Enhanced thermoelectric properties of copper phthalocyanine/single-walled carbon nanotubes hybrids
journal, April 2020

Poly(3,4-ethylenedioxythiophene)-tosylate (PEDOT-Tos) electrodes in thermogalvanic cells
journal, January 2017

Anisotropic thermoelectric power of TTF-TCNQ
journal, March 1975

In situ filling of metallic single-walled carbon nanotubes with ferrocene molecules
journal, October 2012

Dependence of Optical Transition Energies on Structure for Single-Walled Carbon Nanotubes in Aqueous Suspension: An Empirical Kataura Plot
journal, September 2003

Flexible layer-structured Bi2Te3 thermoelectric on a carbon nanotube scaffold
journal, November 2018

Enhanced Thermoelectric Performance of Single-Walled Carbon Nanotubes/Polyaniline Hybrid Nanocomposites
journal, March 2010

Enhanced power factor in flexible reduced graphene oxide/nanowires hybrid films for thermoelectrics
journal, January 2016

The Role of Ordering on the Thermoelectric Properties of Blends of Regioregular and Regiorandom Poly(3‐hexylthiophene)
journal, April 2019

Bendable n-Type Metallic Nanocomposites with Large Thermoelectric Power Factor
journal, November 2016

Electrochemistry of conducting polypyrrole films
journal, November 1981

Dispenser-printed planar thick-film thermoelectric energy generators
journal, September 2011

Self‐Healing and Stretchable 3D‐Printed Organic Thermoelectrics
journal, October 2019

Flexible and Robust Thermoelectric Generators Based on All-Carbon Nanotube Yarn without Metal Electrodes
journal, July 2017

An efficient thermoelectric material: preparation of reduced graphene oxide/polyaniline hybrid composites by cryogenic grinding
journal, January 2015

N-type organic thermoelectrics: demonstration of ZT > 0.3
journal, November 2020

Thermal and Thermoelectric Properties of Graphene
journal, March 2014

Strong, Light, Multifunctional Fibers of Carbon Nanotubes with Ultrahigh Conductivity
journal, January 2013

Spray-Coated Multiwalled Carbon Nanotube Composite Electrodes for Thermal Energy Scavenging Electrochemical Cells
journal, August 2016

Synthesis of electrically conducting organic polymers: halogen derivatives of polyacetylene, (CH) x
journal, January 1977

An empirical model to predict temperature-dependent thermal conductivity of amorphous polymers
journal, May 2017

Preparation of Pristine Graphene Sheets and Large-Area/Ultrathin Graphene Films for High Conducting and Transparent Applications
journal, August 2013

Isotropic Seebeck coefficient of aligned single-wall carbon nanotube films
journal, December 2018

Structural Dependence of Excitonic Optical Transitions and Band-Gap Energies in Carbon Nanotubes
journal, November 2005

Macroscopically aligned carbon nanotubes for flexible and high-temperature electronics, optoelectronics, and thermoelectrics
journal, December 2019

Enhanced thermoelectric performance of nanostructured CNTs/BiSbTe bulk composite from rapid pressure-quenching induced multi-scale microstructure
journal, December 2016

Engineered Molecular Chain Ordering in Single-Walled Carbon Nanotubes/Polyaniline Composite Films for High-Performance Organic Thermoelectric Materials
journal, May 2016

Graphene boosts thermoelectric performance of a Zintl phase compound
journal, January 2015

Miniaturization limitations of HCCI internal combustion engines
journal, February 2009

Diameter dependence of thermoelectric power of semiconducting carbon nanotubes
journal, October 2015

Synthesis and Raman characterization of boron-doped single-walled carbon nanotubes
journal, January 2005

Thermoelectrics: From history, a window to the future
journal, October 2019

Flexible n-Type High-Performance Thermoelectric Thin Films of Poly(nickel-ethylenetetrathiolate) Prepared by an Electrochemical Method
journal, March 2016

Dependence on cation size of thermally induced capacitive effect of a nanoporous carbon
journal, August 2012

A novel self-powered wireless temperature sensor based on thermoelectric generators
journal, April 2014

Dopant‐Dependent Increase in Seebeck Coefficient and Electrical Conductivity in Blended Polymers with Offset Carrier Energies
journal, February 2019

Sequential Doping of Ladder-Type Conjugated Polymers for Thermally Stable n-Type Organic Conductors
journal, November 2020

Thermoelectric properties of conducting polyaniline/graphite composites
journal, April 2011

Ionic transport properties and their empirical correlations for thermal-to-electrical energy conversion
journal, July 2021

Solution-fabrication dependent thermoelectric behavior of iodine-doped regioregular and regiorandom P3HT/carbon nanotube composites
journal, May 2018

A review on mechanical exfoliation for the scalable production of graphene
journal, January 2015

Preparation of polypyrrole/graphene nanosheets composites with enhanced thermoelectric properties
journal, January 2014

Enhanced thermoelectric property by the construction of a nanocomposite 3D interconnected architecture consisting of graphene nanolayers sandwiched by polypyrrole nanowires
journal, January 2015

Enhanced thermoelectric and mechanical properties of Na-doped polycrystalline SnSe thermoelectric materials via CNTs dispersion
journal, April 2018

Enhanced thermoelectric performance of PEDOT with different counter-ions optimized by chemical reduction
journal, January 2014

Robust PEDOT:PSS Wet‐Spun Fibers for Thermoelectric Textiles
journal, February 2020

Large-scalable RTCVD Graphene/PEDOT:PSS hybrid conductive film for application in transparent and flexible thermoelectric nanogenerators
journal, January 2017

Solvent effects on the kinetics of simple electrochemical reactions
journal, July 1981

A three-in-one improvement in thermoelectric properties of polyaniline brought by nanostructures
journal, November 2010

Achieving pseudo -‘n-type p-type’ in-series and parallel liquid thermoelectrics using all-iron thermoelectrochemical cells with opposite Seebeck coefficients
journal, November 2016

Size‐ and Temperature‐Dependent Suppression of Phonon Thermal Conductivity in Carbon Nanotube Thermoelectric Films
journal, October 2020

Large scale, selective dispersion of long single-walled carbon nanotubes with high photoluminescence quantum yield by shear force mixing
journal, August 2016

Impurity scattering and Mott’s formula in graphene
journal, November 2007

Carbon Nanotube - Reduced Graphene Oxide Composites for Thermal Energy Harvesting Applications
journal, October 2013

Self-Powered Multimodal Temperature and Force Sensor Based-On a Liquid Droplet
journal, November 2016

Exploring different doping mechanisms in thermoelectric polymer/carbon nanotube composites
journal, March 2017

Magnetoresistance and thermoelectric power studies of metal-nonmetal transition in iodine-doped polyacetylene
journal, April 1993

Highly selective dispersion of single-walled carbon nanotubes using aromatic polymers
journal, September 2007