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Title: Reversible electrochemical conversion from selenium to cuprous selenide

Abstract

Using elemental selenium as an electrode, the redox-active Cu 2+ /Cu + ion is reversibly hosted via the sequential conversion reactions of Se → CuSe → Cu 3 Se 2 → Cu 2 Se.

Authors:
 [1];  [1]; ORCiD logo [2];  [1]; ORCiD logo [1];  [1]; ORCiD logo [2]; ORCiD logo [1]
  1. Department of Chemistry, Oregon State University, Corvallis, OR, 97331, USA
  2. School of Chemical, Biological, and Environmental Engineering, Oregon State University, Corvallis, OR, 97331, USA
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1821248
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
ChemComm
Additional Journal Information:
Journal Name: ChemComm Journal Volume: 57 Journal Issue: 82; Journal ID: ISSN 1359-7345
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Sandstrom, Sean K., Jiang, Heng, Lucero, Marcos, Xu, Yunkai, Gallagher, Trenton C., Cao, Mengyuan, Feng, Zhenxing, and Ji, Xiulei. Reversible electrochemical conversion from selenium to cuprous selenide. United Kingdom: N. p., 2021. Web. doi:10.1039/D1CC03983K.
Sandstrom, Sean K., Jiang, Heng, Lucero, Marcos, Xu, Yunkai, Gallagher, Trenton C., Cao, Mengyuan, Feng, Zhenxing, & Ji, Xiulei. Reversible electrochemical conversion from selenium to cuprous selenide. United Kingdom. https://doi.org/10.1039/D1CC03983K
Sandstrom, Sean K., Jiang, Heng, Lucero, Marcos, Xu, Yunkai, Gallagher, Trenton C., Cao, Mengyuan, Feng, Zhenxing, and Ji, Xiulei. Thu . "Reversible electrochemical conversion from selenium to cuprous selenide". United Kingdom. https://doi.org/10.1039/D1CC03983K.
@article{osti_1821248,
title = {Reversible electrochemical conversion from selenium to cuprous selenide},
author = {Sandstrom, Sean K. and Jiang, Heng and Lucero, Marcos and Xu, Yunkai and Gallagher, Trenton C. and Cao, Mengyuan and Feng, Zhenxing and Ji, Xiulei},
abstractNote = {Using elemental selenium as an electrode, the redox-active Cu 2+ /Cu + ion is reversibly hosted via the sequential conversion reactions of Se → CuSe → Cu 3 Se 2 → Cu 2 Se.},
doi = {10.1039/D1CC03983K},
journal = {ChemComm},
number = 82,
volume = 57,
place = {United Kingdom},
year = {2021},
month = {10}
}

Works referenced in this record:

A Dual Plating Battery with the Iodine/[ZnI x (OH 2 ) 4− x ] 2− x Cathode
journal, September 2019

  • Hong, Jessica J.; Zhu, Liangdong; Chen, Cheng
  • Angewandte Chemie, Vol. 131, Issue 44
  • DOI: 10.1002/ange.201909324

Rechargeable Ca-Ion Batteries: A New Energy Storage System
journal, December 2015


Pitfalls in X-ray absorption spectroscopy analysis and interpretation: A practical guide for general users
journal, December 2021


Aqueous Li-ion battery enabled by halogen conversion–intercalation chemistry in graphite
journal, May 2019


An Aqueous Dual‐Ion Battery Cathode of Mn 3 O 4 via Reversible Insertion of Nitrate
journal, April 2019

  • Jiang, Heng; Wei, Zhixuan; Ma, Lu
  • Angewandte Chemie International Edition, Vol. 58, Issue 16
  • DOI: 10.1002/anie.201814646

A New Class of Lithium and Sodium Rechargeable Batteries Based on Selenium and Selenium–Sulfur as a Positive Electrode
journal, February 2012

  • Abouimrane, Ali; Dambournet, Damien; Chapman, Karena W.
  • Journal of the American Chemical Society, Vol. 134, Issue 10
  • DOI: 10.1021/ja211766q

An ultrafast rechargeable aluminium-ion battery
journal, April 2015

  • Lin, Meng-Chang; Gong, Ming; Lu, Bingan
  • Nature, Vol. 520, Issue 7547
  • DOI: 10.1038/nature14340

Recent Progress on Engineering Highly Efficient Porous Semiconductor Photocatalysts Derived from Metal–Organic Frameworks
journal, January 2019


Recent developments and future perspectives of anionic batteries
journal, January 2021


Chloride ion battery: A new member in the rechargeable battery family
journal, January 2014


Ultra-high thermoelectric performance in graphene incorporated Cu2Se: Role of mismatching phonon modes
journal, November 2018


A review of halide charge carriers for rocking‐chair and dual‐ion batteries
journal, May 2021

  • Sandstrom, Sean K.; Chen, Xin; Ji, Xiulei
  • Carbon Energy, Vol. 3, Issue 4
  • DOI: 10.1002/cey2.110

Li–Se battery: absence of lithium polyselenides in carbonate based electrolyte
journal, January 2014

  • Cui, Yanjie; Abouimrane, Ali; Sun, Cheng-Jun
  • Chem. Commun., Vol. 50, Issue 42
  • DOI: 10.1039/C4CC00934G

An Energetic CuS–Cu Battery System Based on CuS Nanosheet Arrays
journal, March 2021


Sodium-Ion Batteries
journal, May 2012

  • Slater, Michael D.; Kim, Donghan; Lee, Eungje
  • Advanced Functional Materials, Vol. 23, Issue 8, p. 947-958
  • DOI: 10.1002/adfm.201200691

Charge carriers in rechargeable batteries: Na ions vs. Li ions
journal, January 2013

  • Hong, Sung You; Kim, Youngjin; Park, Yuwon
  • Energy & Environmental Science, Vol. 6, Issue 7
  • DOI: 10.1039/c3ee40811f

Energetic Zinc Ion Chemistry: The Rechargeable Zinc Ion Battery
journal, December 2011


(De)Lithiation Mechanism of Li/SeS x ( x = 0–7) Batteries Determined by in Situ Synchrotron X-ray Diffraction and X-ray Absorption Spectroscopy
journal, May 2013

  • Cui, Yanjie; Abouimrane, Ali; Lu, Jun
  • Journal of the American Chemical Society, Vol. 135, Issue 21
  • DOI: 10.1021/ja402597g

High-power Mg batteries enabled by heterogeneous enolization redox chemistry and weakly coordinating electrolytes
journal, November 2020


Potassium secondary cell based on Prussian blue cathode
journal, February 2004


A Four‐Electron Sulfur Electrode Hosting a Cu 2+ /Cu + Redox Charge Carrier
journal, July 2019


Tuning crystal phase and morphology of copper selenide nanostructures and their visible-light photocatalytic applications to degrade organic pollutants
journal, February 2020

  • Nouri, Morteza; Yousefi, Ramin; Zare-Dehnavi, Nasser
  • Colloids and Surfaces A: Physicochemical and Engineering Aspects, Vol. 586
  • DOI: 10.1016/j.colsurfa.2019.124196

Towards a calcium-based rechargeable battery
journal, October 2015

  • Ponrouch, A.; Frontera, C.; Bardé, F.
  • Nature Materials, Vol. 15, Issue 2
  • DOI: 10.1038/nmat4462

A highly ordered nanostructured carbon–sulphur cathode for lithium–sulphur batteries
journal, May 2009

  • Ji, Xiulei; Lee, Kyu Tae; Nazar, Linda F.
  • Nature Materials, Vol. 8, Issue 6, p. 500-506
  • DOI: 10.1038/nmat2460

Scientific Challenges for the Implementation of Zn-Ion Batteries
journal, April 2020


The rise of lithium–selenium batteries
journal, January 2017


The Renaissance of Proton Batteries
journal, February 2021


The rechargeable aluminum-ion battery
journal, January 2011

  • Jayaprakash, N.; Das, S. K.; Archer, L. A.
  • Chemical Communications, Vol. 47, Issue 47
  • DOI: 10.1039/c1cc15779e