Quasi-One-Dimensional Structure and Possible Helical Antiferromagnetism of RbMn6Bi5

Chen, Long; Zhao, Linlin; Qiu, Xiaole; Zhang, Qinghua; Liu, Kai; Lin, Qisheng; Wang, Gang

doi:10.1021/acs.inorgchem.1c01318

Title: Quasi-One-Dimensional Structure and Possible Helical Antiferromagnetism of RbMn₆Bi₅

Journal Article · 25 August 2021 · Inorganic Chemistry

DOI: https://doi.org/10.1021/acs.inorgchem.1c01318 · OSTI ID:1820992

Chen, Long ^[1]; Zhao, Linlin ^[1]; Qiu, Xiaole ^[2]; Zhang, Qinghua ^[3];

^[2]; Lin, Qisheng ^[4];

^[5]

Chinese Academy of Sciences (CAS), Beijing (China). Institute of Physics; University of Chinese Academy of Sciences, Beijing (China)
Renmin Univ. of China, Beijing (China)
Chinese Academy of Sciences (CAS), Beijing (China). Institute of Physics
Ames Lab., and Iowa State Univ., Ames, IA (United States)
Chinese Academy of Sciences (CAS), Beijing (China). Institute of Physics; University of Chinese Academy of Sciences, Beijing (China); Songshan Lake Materials Laboratory, Dongguan (China)

Quasi-one-dimensional materials exhibit not only unique crystal structure but also abundant physical properties such as charge density wave, Luttinger liquid, and superconductivity. In this study, we report the discovery, structure, and physical properties of a new manganese-based quasi-one-dimensional material RbMn₆Bi₅, which crystallizes in a monoclinic space group C2/m (No. 12) with lattice parameters a = 23.286(5) Å, b = 4.6215(9) Å, c = 13.631(3) Å, and β = 125.00(3)°. The structure features [Mn₆Bi₅]^–1 double-walled column extending along the [010] direction, together with Bi–Bi homoatomic bonds linking the columns and the countercation Rb⁺. The temperature-dependent resistivity clearly indicates a significant resistivity anisotropy for RbMn₆Bi₅, whereas the magnetic susceptibility and specific heat measurements show that RbMn₆Bi₅ is antiferromagnetic below 82 K. The density functional theory calculations indicate that RbMn₆Bi₅ is a quasi-one-dimensional metal with possible helical antiferromagnetic configuration. The discovery of RbMn₆Bi₅ confirms the viability of discovering new quasi-one-dimensional materials in manganese-based compounds.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Ames Laboratory (AMES), Ames, IA (United States)

Sponsoring Organization:: Beijing Natural Science Foundation; Chinese Academy of Sciences (CAS); National Key Research and Development Program of China; National Natural Science Foundation of China (NSFC); USDOE

Grant/Contract Number:: AC02-07CH11358

OSTI ID:: 1820992

Report Number(s):: IS--J-10,59*2; 2017YFA0302900; 2018YFE0202600; Z200005; 11774424; 51532010; 51572291; 51832010; QYZDJ-SSW-SLH013

Journal Information:: Inorganic Chemistry, Journal Name: Inorganic Chemistry Journal Issue: 17 Vol. 60; ISSN 0020-1669

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

References (68)

Crystal Structure, Charge Transport, and Magnetic Properties of MnSb2Se4 Djieutedjeu, Honore; Makongo, Julien P. A.; Rotaru, Aurelian European Journal of Inorganic Chemistry, Vol. 2011, Issue 26 https://doi.org/10.1002/ejic.201100364	journal	August 2011
Semiempirical GGA-type density functional constructed with a long-range dispersion correction Grimme, Stefan Journal of Computational Chemistry, Vol. 27, Issue 15, p. 1787-1799 https://doi.org/10.1002/jcc.20495	journal	January 2006
The Zintl-Klemm Concept - A Historical Survey: The Zintl-Klemm Concept - A Historical Survey Nesper, Reinhard Zeitschrift für anorganische und allgemeine Chemie, Vol. 640, Issue 14 https://doi.org/10.1002/zaac.201400403	journal	November 2014
Über Alkalimetallmanganchalkogenide A2MnX2 mit A K, Rb oder Cs und X S, Se oder Te Bronger, W.; Balk-Hardtdegen, H.; Schmitz, D. Zeitschrift für anorganische und allgemeine Chemie, Vol. 574, Issue 1 https://doi.org/10.1002/zaac.655740110	journal	July 1989
Resistivity and Magnetism of AMn2P2 (A = Sr, Ba): The Effect of Structure Type on Physical Properties Brock, Stephanie L.; Greedan, J. E.; Kauzlarich, Susan M. Journal of Solid State Chemistry, Vol. 113, Issue 2 https://doi.org/10.1006/jssc.1994.1375	journal	December 1994
Magnetic properties and neutron diffraction study of two manganese sulfosalts: monoclinic MnSb2S4 and benavidesite (MnPb4Sb6S14) Léone, Philippe; Doussier-Brochard, Charlotte; André, Gilles Physics and Chemistry of Minerals, Vol. 35, Issue 4 https://doi.org/10.1007/s00269-007-0213-3	journal	January 2008
Superconductivity in quasi-one-dimensional Cs2Cr3As3 with large interchain distance Tang, Zhang-Tu; Bao, Jin-Ke; Wang, Zhen Science China Materials, Vol. 58, Issue 1 https://doi.org/10.1007/s40843-015-0021-x	journal	January 2015
Structure and Jahn-Teller effect in mixed crystals Rb2Cr1−xMnxCl4: A single-crystal neutron diffraction study and spectroscopic results Münninghoff, G.; Treutmann, W.; Hellner, E. Journal of Solid State Chemistry, Vol. 34, Issue 3 https://doi.org/10.1016/0022-4596(80)90427-2	journal	October 1980
Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set Kresse, G.; Furthmüller, J. Computational Materials Science, Vol. 6, Issue 1, p. 15-50 https://doi.org/10.1016/0927-0256(96)00008-0	journal	July 1996
Magnetic order in CaMn2Sb2 studied via powder neutron diffraction Bridges, C. A.; Krishnamurthy, V. V.; Poulton, S. Journal of Magnetism and Magnetic Materials, Vol. 321, Issue 22 https://doi.org/10.1016/j.jmmm.2009.07.015	journal	November 2009
Structural and physical properties of SrMn2As2 Wang, Z. W.; Yang, H. X.; Tian, H. F. Journal of Physics and Chemistry of Solids, Vol. 72, Issue 5 https://doi.org/10.1016/j.jpcs.2010.10.053	journal	May 2011
Crystals, magnetic and electronic properties of a new ThCr2Si2-type BaMn2Bi2 and K-doped compositions Saparov, Bayrammurad; Sefat, Athena S. Journal of Solid State Chemistry, Vol. 204 https://doi.org/10.1016/j.jssc.2013.05.010	journal	August 2013
Facile synthesis, thermal, magnetic, Raman characterizations of spinel structure ZnMn2O4 Li, H.; Song, B.; Wang, W. J. Materials Chemistry and Physics, Vol. 130, Issue 1-2 https://doi.org/10.1016/j.matchemphys.2011.04.072	journal	October 2011
Superconductivity at 10.4 K in a novel quasi-one-dimensional ternary molybdenum pnictide K 2 Mo 3 As 3 Mu, Qing-Ge; Ruan, Bin-Bin; Zhao, Kang Science Bulletin, Vol. 63, Issue 15 https://doi.org/10.1016/j.scib.2018.06.011	journal	August 2018
Future Earth and Sustainable Developments Cheng, Hai The Innovation, Vol. 1, Issue 3 https://doi.org/10.1016/j.xinn.2020.100055	journal	November 2020
Intrinsic magnetic topological insulators Wang, Pinyuan; Ge, Jun; Li, Jiaheng The Innovation, Vol. 2, Issue 2 https://doi.org/10.1016/j.xinn.2021.100098	journal	May 2021
Structural and Magnetical Studies of Mixed-Valence Hexavanadate Hybrids: How Organic Ligands Affect the Magnetism of Polyoxometalates? Wu, Pingfan; Wang, Yu; Chen, Weizhou Inorganic Chemistry, Vol. 60, Issue 7 https://doi.org/10.1021/acs.inorgchem.1c00044	journal	March 2021
Unusual Mn−Mn Spin Coupling in the Polar Intermetallic Compounds CaMn ₂ Sb ₂ and SrMn ₂ Sb ₂ Bobev, Svilen; Merz, Justin; Lima, Ana Inorganic Chemistry, Vol. 45, Issue 10 https://doi.org/10.1021/ic060092e	journal	May 2006
Sr ₂ Mn ₃ Sb ₂ O ₂ Type Oxyselenides: Structures, Magnetism, and Electronic Properties of Sr ₂ A O ₂ M ₂ Se ₂ ( A =Co, Mn; M =Cu, Ag) Jin, Shifeng; Chen, Xiaolong; Guo, Jiangang Inorganic Chemistry, Vol. 51, Issue 19 https://doi.org/10.1021/ic301022g	journal	September 2012
Structures and Physical Properties of Layered Oxyselenides Ba ₂ MO ₂ Ag ₂ Se ₂ (M = Co, Mn) Zhou, Tingting; Wang, Yumei; Jin, Shifeng Inorganic Chemistry, Vol. 53, Issue 8 https://doi.org/10.1021/ic500203k	journal	April 2014
Combined Magnetic and Single-Crystal X-ray Structural Study of the Linear Chain Antiferromagnet [(CH ₃ ) ₄ N][MnCl ₃ ] under Varying Pressure Tancharakorn, Somchai; Fabbiani, Francesca P. A.; Allan, David R. Journal of the American Chemical Society, Vol. 128, Issue 28 https://doi.org/10.1021/ja061923i	journal	July 2006
Unique [Mn ₆ Bi ₅ ] ⁻ Nanowires in KMn ₆ Bi ₅ : A Quasi-One-Dimensional Antiferromagnetic Metal Bao, Jin-Ke; Tang, Zhang-Tu; Jung, Hee Joon Journal of the American Chemical Society, Vol. 140, Issue 12 https://doi.org/10.1021/jacs.8b00465	journal	February 2018
Transition-metal-based magnetic refrigerants for room-temperature applications Tegus, O.; Brück, E.; Buschow, K. H. J. Nature, Vol. 415, Issue 6868 https://doi.org/10.1038/415150a	journal	January 2002
Coherence–incoherence and dimensional crossover in layered strongly correlated metals Valla, T.; Johnson, P. D.; Yusof, Z. Nature, Vol. 417, Issue 6889 https://doi.org/10.1038/nature00774	journal	June 2002
Magnetic control of ferroelectric polarization Kimura, T.; Goto, T.; Shintani, H. Nature, Vol. 426, Issue 6962 https://doi.org/10.1038/nature02018	journal	November 2003
Collapse of magnetic moment drives the Mott transition in MnO Kuneš, Jan; Lukoyanov, Alexey V.; Anisimov, Vladimir I. Nature Materials, Vol. 7, Issue 3 https://doi.org/10.1038/nmat2115	journal	February 2008
A family of binary magnetic icosahedral quasicrystals based on rare earths and cadmium Goldman, Alan I.; Kong, Tai; Kreyssig, Andreas Nature Materials, Vol. 12, Issue 8 https://doi.org/10.1038/nmat3672	journal	June 2013
Pressure-induced superconductivity in the iron-based ladder material BaFe2S3 Takahashi, Hiroki; Sugimoto, Akira; Nambu, Yusuke Nature Materials, Vol. 14, Issue 10 https://doi.org/10.1038/nmat4351	journal	July 2015
Spin-induced multiferroicity in the binary perovskite manganite Mn2O3 Cong, Junzhuang; Zhai, Kun; Chai, Yisheng Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-05296-0	journal	July 2018
Robust axion insulator and Chern insulator phases in a two-dimensional antiferromagnetic topological insulator Liu, Chang; Wang, Yongchao; Li, Hao Nature Materials https://doi.org/10.1038/s41563-019-0573-3	journal	January 2020
A tetragonal polymorph of SrMn ₂ P ₂ made under high pressure – theory and experiment in harmony Xie, Weiwei; Winiarski, Michał J.; Klimczuk, Tomasz Dalton Transactions, Vol. 46, Issue 21 https://doi.org/10.1039/C7DT00781G	journal	January 2017
Geometrically frustrated magnetic materials Greedan, John E. Journal of Materials Chemistry, Vol. 11, Issue 1 https://doi.org/10.1039/b003682j	journal	January 2001
Giant magnetoresistance in oxypnictides (La,Nd)OMnAs Emery, Nicolas; Wildman, Eve J.; Skakle, Janet M. S. Chemical Communications, Vol. 46, Issue 36 https://doi.org/10.1039/c0cc01380c	journal	January 2010
Magnetocaloric effect in La _0.67 Ca _0.33 MnO _δ and La _0.60 Y _0.07 Ca _0.33 MnO _δ bulk materials Zhang, X. X.; Tejada, J.; Xin, Y. Applied Physics Letters, Vol. 69, Issue 23 https://doi.org/10.1063/1.117218	journal	December 1996
Direct and specific heat study of magnetocaloric effect in La0.845Sr0.155MnO3 Szewczyk, A.; Gutowska, M.; Piotrowski, K. Journal of Applied Physics, Vol. 94, Issue 3 https://doi.org/10.1063/1.1591411	journal	August 2003
Antiferromagnetic bipolar semiconductor LaMnPO with ZrCuSiAs-type structure Yanagi, Hiroshi; Watanabe, Takumi; Kodama, Katsuaki Journal of Applied Physics, Vol. 105, Issue 9 https://doi.org/10.1063/1.3124582	journal	May 2009
The puzzle of high temperature superconductivity in layered iron pnictides and chalcogenides Johnston, David C. Advances in Physics, Vol. 59, Issue 6 https://doi.org/10.1080/00018732.2010.513480	journal	October 2010
One-dimensional Fermi liquids Voit, J. Reports on Progress in Physics, Vol. 58, Issue 9 https://doi.org/10.1088/0034-4885/58/9/002	journal	September 1995
Magnetic properties of the Ag–In–rare-earth 1/1 approximants Ibuka, Soshi; Iida, Kazuki; Sato, Taku J. Journal of Physics: Condensed Matter, Vol. 23, Issue 5 https://doi.org/10.1088/0953-8984/23/5/056001	journal	January 2011
Colossal magnetoresistance Ramirez, A. P. Journal of Physics: Condensed Matter, Vol. 9, Issue 39 https://doi.org/10.1088/0953-8984/9/39/005	journal	September 1997
Highly-ordered wide bandgap materials for quantized anomalous Hall and magnetoelectric effects Otrokov, M. M.; Menshchikova, T. V.; Vergniory, M. G. 2D Materials, Vol. 4, Issue 2 https://doi.org/10.1088/2053-1583/aa6bec	journal	April 2017
Atomic structure, work function and magnetism in layered single crystal VOCl Wang, Wenjie; Sun, Rong; He, Shijie 2D Materials, Vol. 8, Issue 1 https://doi.org/10.1088/2053-1583/abc5cf	journal	December 2020
Magnetically controllable topological quantum phase transitions in the antiferromagnetic topological insulator MnBi 2 Te 4 Li, Jiaheng; Wang, Chong; Zhang, Zetao Physical Review B, Vol. 100, Issue 12 https://doi.org/10.1103/PhysRevB.100.121103	journal	September 2019
Miscibility gap and possible intrinsic Griffiths phase in Sr ( Fe 1 − x Mn x ) 2 As 2 crystals grown by transition metal arsenide flux Chen, Long; Cao, Cheng; Chen, Hongxiang Physical Review B, Vol. 103, Issue 13 https://doi.org/10.1103/PhysRevB.103.134509	journal	April 2021
Neutron Scattering in the Linear Chain Antiferromagnet CsMn Cl 3 ·2 H 2 O Skalyo, J.; Shirane, G.; Friedberg, S. A. Physical Review B, Vol. 2, Issue 5 https://doi.org/10.1103/PhysRevB.2.1310	journal	September 1970
Ab initiomolecular dynamics for liquid metals Kresse, G.; Hafner, J. Physical Review B, Vol. 47, Issue 1, p. 558-561 https://doi.org/10.1103/PhysRevB.47.558	journal	January 1993
Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set Kresse, G.; Furthmüller, J. Physical Review B, Vol. 54, Issue 16, p. 11169-11186 https://doi.org/10.1103/PhysRevB.54.11169	journal	October 1996
Rotational tuning of H c 2 anomalies in ErNi 2 B 2 C : Angular-dependent superzone gap formation and its effect on the superconducting ground state Bud’ko, Sergey L.; Canfield, Paul C. Physical Review B, Vol. 61, Issue 22 https://doi.org/10.1103/PhysRevB.61.R14932	journal	June 2000
Electronic structure of the antiferromagnetic semiconductor Mn Sb 2 S 4 Matar, S. F.; Weihrich, R.; Kurowski, D. Physical Review B, Vol. 71, Issue 23 https://doi.org/10.1103/PhysRevB.71.235207	journal	June 2005
Electronic structure and magnetism in BaMn 2 As 2 and BaMn 2 Sb 2 An, Jiming; Sefat, A. S.; Singh, D. J. Physical Review B, Vol. 79, Issue 7 https://doi.org/10.1103/PhysRevB.79.075120	journal	February 2009
Magnetic order in BaMn 2 As 2 from neutron diffraction measurements Singh, Yogesh; Green, M. A.; Huang, Q. Physical Review B, Vol. 80, Issue 10 https://doi.org/10.1103/PhysRevB.80.100403	journal	September 2009
Long-range magnetic order in the quasicrystalline approximant Cd 6 Tb Tamura, R.; Muro, Y.; Hiroto, T. Physical Review B, Vol. 82, Issue 22 https://doi.org/10.1103/PhysRevB.82.220201	journal	December 2010
Variable temperature study of the crystal and magnetic structures of the giant magnetoresistant materials L MnAsO( L = La, Nd) Emery, N.; Wildman, E. J.; Skakle, J. M. S. Physical Review B, Vol. 83, Issue 14 https://doi.org/10.1103/PhysRevB.83.144429	journal	April 2011
Magnetic and transport properties of i- R -Cd icosahedral quasicrystals ( R = Y , Gd-Tm ) Kong, Tai; Bud'ko, Sergey L.; Jesche, Anton Physical Review B, Vol. 90, Issue 1 https://doi.org/10.1103/PhysRevB.90.014424	journal	July 2014
Unconventional superconductivity in quasi-one-dimensional Rb 2 Cr 3 As 3 Tang, Zhang-Tu; Bao, Jin-Ke; Liu, Yi Physical Review B, Vol. 91, Issue 2 https://doi.org/10.1103/PhysRevB.91.020506	journal	January 2015
Magnetic and electronic properties of CaMn 2 Bi 2 : A possible hybridization gap semiconductor Gibson, Q. D.; Wu, H.; Liang, T. Physical Review B, Vol. 91, Issue 8 https://doi.org/10.1103/PhysRevB.91.085128	journal	February 2015
Structure and magnetic properties of L n MnSbO ( L n = La and Ce) Zhang, Qiang; Kumar, C. M. N.; Tian, Wei Physical Review B, Vol. 93, Issue 9 https://doi.org/10.1103/PhysRevB.93.094413	journal	March 2016
Pressure dependence of the magnetic ground states in MnP Matsuda, M.; Ye, F.; Dissanayake, S. E. Physical Review B, Vol. 93, Issue 10 https://doi.org/10.1103/PhysRevB.93.100405	journal	March 2016
Strong magnetic correlations to 900 K in single crystals of the trigonal antiferromagnetic insulators SrMn 2 As 2 and CaMn 2 As 2 Sangeetha, N. S.; Pandey, Abhishek; Benson, Zackery A. Physical Review B, Vol. 94, Issue 9 https://doi.org/10.1103/PhysRevB.94.094417	journal	September 2016
Pressure Induced Superconductivity on the border of Magnetic Order in MnP Cheng, J. -G.; Matsubayashi, K.; Wu, W. Physical Review Letters, Vol. 114, Issue 11 https://doi.org/10.1103/PhysRevLett.114.117001	journal	March 2015
Unique Thickness-Dependent Properties of the van der Waals Interlayer Antiferromagnet MnBi 2 Te 4 Films Otrokov, M. M.; Rusinov, I. P.; Blanco-Rey, M. Physical Review Letters, Vol. 122, Issue 10 https://doi.org/10.1103/PhysRevLett.122.107202	journal	March 2019
Generalized Gradient Approximation Made Simple Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868 https://doi.org/10.1103/PhysRevLett.77.3865	journal	October 1996
The dynamics of charge-density waves Grüner, G. Reviews of Modern Physics, Vol. 60, Issue 4 https://doi.org/10.1103/RevModPhys.60.1129	journal	October 1988
Colloquium : Saturation of electrical resistivity Gunnarsson, O.; Calandra, M.; Han, J. E. Reviews of Modern Physics, Vol. 75, Issue 4 https://doi.org/10.1103/RevModPhys.75.1085	journal	October 2003
Short-range order and spin-glass-like freezing in A –Mg– R ( A = Zn or Cd; R = rare-earth elements) magnetic quasicrystals Sato, Taku J. Acta Crystallographica Section A Foundations of Crystallography, Vol. 61, Issue 1 https://doi.org/10.1107/S0108767304026625	journal	December 2004
A short history of SHELX Sheldrick, George M. Acta Crystallographica Section A Foundations of Crystallography, Vol. 64, Issue 1, p. 112-122 https://doi.org/10.1107/S0108767307043930	journal	December 2007
Quantum Hall effect in a bulk antiferromagnet EuMnBi ₂ with magnetically confined two-dimensional Dirac fermions Masuda, Hidetoshi; Sakai, Hideaki; Tokunaga, Masashi Science Advances, Vol. 2, Issue 1 https://doi.org/10.1126/sciadv.1501117	journal	January 2016
Energy Gaps and Electrical Resistivity Associated with Screw-Type Spin Arrangements Miwa, Hirosi Progress of Theoretical Physics, Vol. 29, Issue 4 https://doi.org/10.1143/PTP.29.477	journal	April 1963

Similar Records

Unique [Mn₆Bi₅]^- Nanowires in KMn₆Bi₅: A Quasi-One-Dimensional Antiferromagnetic Metal

Journal Article · 2018 · Journal of the American Chemical Society · OSTI ID:1433916

Bao, Jin-Ke; Tang, Zhang-Tu; Jung, Hee Joon; +11 more

Antiferromagnetic Ordering in Quasi-One-Dimensional FeBi₄S₇

Journal Article · 2024 · Chemistry of Materials · OSTI ID:2447238

Campbell, Ian; Garlea, Vasile Ovidiu; Zhang, Qiang; +5 more

Long-range antiferromagnetic ordering in Cu{sub 2}NiB{sub 2}O{sub 6}

Journal Article · 2006 · Journal of Solid State Chemistry · OSTI ID:20900935

Zhangzhen, He; Kyomen, Toru; Taniyama, Tomoyasu; +1 more

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
crystal structure
energy
magnetic properties
materials
transition metals

Title: Quasi-One-Dimensional Structure and Possible Helical Antiferromagnetism of RbMn6Bi5

Citation Formats

References (68)

Linked Research (1)

Similar Records

Related Subjects

Title: Quasi-One-Dimensional Structure and Possible Helical Antiferromagnetism of RbMn₆Bi₅