Status and prospect of in situ and operando characterization of solid-state batteries

Dixit, Marm B.; Park, Jun-Sang; Kenesei, Peter; Almer, Jonathan; Hatzell, Kelsey B.

doi:10.1039/d1ee00638j

Title: Status and prospect of in situ and operando characterization of solid-state batteries

Journal Article · 26 July 2021 · Energy & Environmental Science

DOI: https://doi.org/10.1039/d1ee00638j · OSTI ID:1820322

Dixit, Marm B. ^[1]; Park, Jun-Sang ^[2]; Kenesei, Peter ^[2]; Almer, Jonathan ^[2];

^[3]

Vanderbilt Univ., Nashville, TN (United States)
Argonne National Lab. (ANL), Lemont, IL (United States)
Vanderbilt Univ., Nashville, TN (United States); Princeton Univ., NJ (United States)

Electrification of the transportation sector relies on radical re-imagining of energy storage technologies to provide affordable, high energy density, durable and safe systems. Next generation energy storage systems will need to leverage high energy density anodes and high voltage cathodes to achieve the required performance metrics (longer vehicle range, long life, production costs, safety). Solid-state batteries (SSBs) are promising materials technology for achieving these metrics by enabling these electrode systems due to the underlying material properties of the solid electrolyte (viz. mechanical strength, electrochemical stability, ionic conductivity). Electro-chemo-mechanical degradation in SSBs detrimentally impact the Coulombic efficiencies, capacity retention, durability and safety in SSBs restricting their practical implementation. Solid|solid interfaces in SSBs are hot-spots of dynamics that contribute to the degradation of SSBs. Characterizing and understanding the processes at the solid|solid interfaces in SSBs is crucial towards designing of resilient, durable, high energy density SSBs. This work provides a comprehensive and critical summary of the SSB characterization with a focus on in situ and operando studies. Additionally, perspectives on experimental design, emerging characterization techniques and data analysis methods are provided. Furthermore, this work provides a thorough analysis of current status of SSB characterization as well as highlights important avenues for future work.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: National Science Foundation; USDOE

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1820322

Journal Information:: Energy & Environmental Science, Journal Name: Energy & Environmental Science Journal Issue: 9 Vol. 14; ISSN 1754-5692

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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On Modeling the Detrimental Effects of Inhomogeneous Plating-and-Stripping at a Lithium-Metal/Solid-Electrolyte Interface in a Solid-State-Battery Narayan, Sooraj; Anand, Lallit Journal of The Electrochemical Society, Vol. 167, Issue 4 https://doi.org/10.1149/1945-7111/ab75c1	journal	January 2020
Polymerized Ionic Liquid Block Copolymer Electrolytes for All-Solid-State Lithium-Metal Batteries Mendes, Tiago C.; Goujon, Nicolas; Malic, Nino Journal of The Electrochemical Society, Vol. 167, Issue 7 https://doi.org/10.1149/1945-7111/ab75c6	journal	January 2020
Molar Volume Mismatch: A Malefactor for Irregular Metallic Electrodeposition with Solid Electrolytes Mistry, Aashutosh; Mukherjee, Partha P. Journal of The Electrochemical Society, Vol. 167, Issue 8 https://doi.org/10.1149/1945-7111/ab8ecd	journal	May 2020
Evaluation of The Electrochemo-Mechanically Induced Stress in All-Solid-State Li-Ion Batteries Tian, Hong-Kang; Chakraborty, Aritra; Talin, A. Alec Journal of The Electrochemical Society, Vol. 167, Issue 9 https://doi.org/10.1149/1945-7111/ab8f5b	journal	May 2020
Lithium Mechanics: Roles of Strain Rate and Temperature and Implications for Lithium Metal Batteries LePage, William S.; Chen, Yuxin; Kazyak, Eric Journal of The Electrochemical Society, Vol. 166, Issue 2 https://doi.org/10.1149/2.0221902jes	journal	January 2019
Toward All-Solid-State Lithium Batteries: Three-Dimensional Visualization of Lithium Migration in β-Li 3 PS 4 Ceramic Electrolyte Seitzman, Natalie; Guthrey, Harvey; Sulas, Dana B. Journal of The Electrochemical Society, Vol. 165, Issue 16 https://doi.org/10.1149/2.0301816jes	journal	January 2018
Simulation of the Effect of Contact Area Loss in All-Solid-State Li-Ion Batteries Tian, Hong-Kang; Qi, Yue Journal of The Electrochemical Society, Vol. 164, Issue 11 https://doi.org/10.1149/2.0481711jes	journal	January 2017
Elucidation of Separator Effect on Energy Density of Li-Ion Batteries Parikh, Dhrupad; Christensen, Tommiejean; Hsieh, Chien-Te Journal of The Electrochemical Society, Vol. 166, Issue 14 https://doi.org/10.1149/2.0571914jes	journal	January 2019
Mesoscale Analysis of the Electrolyte-Electrode Interface in All-Solid-State Li-Ion Batteries Hao, Feng; Mukherjee, Partha P. Journal of The Electrochemical Society, Vol. 165, Issue 9 https://doi.org/10.1149/2.1251809jes	journal	January 2018
Review—Practical Challenges Hindering the Development of Solid State Li Ion Batteries Kerman, Kian; Luntz, Alan; Viswanathan, Venkatasubramanian Journal of The Electrochemical Society, Vol. 164, Issue 7 https://doi.org/10.1149/2.1571707jes	journal	January 2017
Asynchronous stoichiometric response in lithium iron phosphate batteries Paxton, William A.; Akdoğan, E. Koray; Şavkliyildiz, İlyas Journal of Materials Research, Vol. 30, Issue 3 https://doi.org/10.1557/jmr.2014.321	journal	November 2014
High-energy X-ray phase analysis of CMAS-infiltrated 7YSZ thermal barrier coatings: Effect of time and temperature Stein, Zachary; Kenesei, Peter; Park, Jun-Sang Journal of Materials Research, Vol. 35, Issue 17 https://doi.org/10.1557/jmr.2020.212	journal	August 2020
Interfaces Between Cathode and Electrolyte in Solid State Lithium Batteries: Challenges and Perspectives Nie, Kaihui; Hong, Yanshuai; Qiu, Jiliang Frontiers in Chemistry, Vol. 6 https://doi.org/10.3389/fchem.2018.00616	journal	December 2018
Coin-Cell-Based In Situ Characterization Techniques for Li-Ion Batteries Zhang, Liao; Guo, Xiaolong; Huang, Jiangtao Frontiers in Energy Research, Vol. 6 https://doi.org/10.3389/fenrg.2018.00016	journal	March 2018
Insight Into the Formation of Lithium Alloys in All-Solid-State Thin Film Lithium Batteries Goonetilleke, Damian; Sharma, Neeraj; Kimpton, Justin Frontiers in Energy Research, Vol. 6 https://doi.org/10.3389/fenrg.2018.00064	journal	July 2018
Factors That Control the Formation of Dendrites and Other Morphologies on Lithium Metal Anodes Frenck, Louise; Sethi, Gurmukh K.; Maslyn, Jacqueline A. Frontiers in Energy Research, Vol. 7 https://doi.org/10.3389/fenrg.2019.00115	journal	November 2019
Direct Observation of Ion Concentration Distribution in All-Solid-State Rechargeable Battery Using operando X-ray Radiography and Silver-Ion Conductor Kandori, Koji; Yamashige, Hisao; Furuta, Noritoshi Electrochemistry, Vol. 87, Issue 3 https://doi.org/10.5796/electrochemistry.19-00011	journal	January 2019

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