Photodriven Elimination of Chlorine From Germanium and Platinum in a Dinuclear Pt II →Ge IV Complex

Karimi, Mohammadjavad; Tabei, Elham S.; Fayad, Remi; Saber, Mohamed R.; Danilov, Evgeny O.; Jones, Cameron; Castellano, Felix N.; Gabbaï, François P.

doi:10.1002/ange.202107485

Title: Photodriven Elimination of Chlorine From Germanium and Platinum in a Dinuclear Pt ^II →Ge ^IV Complex

Journal Article · 08 September 2021 · Angewandte Chemie

DOI: https://doi.org/10.1002/ange.202107485 · OSTI ID:1819373

Karimi, Mohammadjavad ^[1]; Tabei, Elham S. ^[1]; Fayad, Remi ^[2]; Saber, Mohamed R. ^[1]; Danilov, Evgeny O. ^[2];

^[3];

^[2];

^[1]

Department of Chemistry Texas A&,M University College Station TX 77843 USA
Department of Chemistry North Carolina State University Raleigh NC 27695-8204 USA
School of Chemistry Monash University PO Box 23 Melbourne VIC 3800 Australia

Abstract Searching for a connection between the two‐electron redox behavior of Group‐14 elements and their possible use as platforms for the photoreductive elimination of chlorine, we have studied the photochemistry of [( o ‐(Ph ₂ P)C ₆ H ₄ ) ₂ Ge ^IV Cl ₂ ]Pt ^II Cl ₂ and [( o ‐(Ph ₂ P)C ₆ H ₄ ) ₂ ClGe ^III ]Pt ^III Cl ₃ , two newly isolated isomeric complexes. These studies show that, in the presence of a chlorine trap, both isomers convert cleanly into the platinum germyl complex [( o ‐(Ph ₂ P)C ₆ H ₄ ) ₂ ClGe ^III ]Pt ^I Cl with quantum yields of 1.7 % and 3.2 % for the Ge ^IV –Pt ^II and Ge ^III –Pt ^III isomers, respectively. Conversion of the Ge ^IV –Pt ^II isomer into the platinum germyl complex is a rare example of a light‐induced transition‐metal/main‐group‐element bond‐forming process. Finally, transient‐absorption‐spectroscopy studies carried out on the Ge ^III –Pt ^III isomer point to a ligand arene–Cl ^. charge‐transfer complex as an intermediate.

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Sponsoring Organization:: USDOE

Grant/Contract Number:: SC0019370

OSTI ID:: 1819373

Journal Information:: Angewandte Chemie, Journal Name: Angewandte Chemie Journal Issue: 41 Vol. 133; ISSN 0044-8249

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

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Title: Photodriven Elimination of Chlorine From Germanium and Platinum in a Dinuclear Pt ^II →Ge ^IV Complex