Performance of Carbide Alloy Compounds in Carbon Doped MoNbTaW

Zhang, Congyan; Bhandari, Uttam; Lei, Jialin; Zeng, Congyuan; Guo, Shengmin; Choi, Hyunjoo; Nam, Seungjin; Yan, Jinyuan; Yang, Shizhong; Gao, Feng

doi:10.3390/cryst11091073

Title: Performance of Carbide Alloy Compounds in Carbon Doped MoNbTaW

Journal Article · 03 September 2021 · Crystals

DOI: https://doi.org/10.3390/cryst11091073 · OSTI ID:1818805

Zhang, Congyan;

; Lei, Jialin; Zeng, Congyuan;

; Choi, Hyunjoo; Nam, Seungjin; Yan, Jinyuan;

; Gao, Feng

In this work, the performance of the carbon doped compositionally complex alloy (CCA) MoNbTaW was studied under ambient and high pressure and high temperature conditions. TaC and NbC carbides were formed when a large concentration of carbon was introduced while synthesizing the MoNbTaW alloy. Both FCC carbides and BCC CCA phases were detected in the sample compound at room temperature, in which the BCC phase was believed to have only refractory elements MoNbTaW while FCC carbide came from TaC and NbC. Carbides in the carbon doped MoNbTaW alloy were very stable since no phase transition was obtained even under 3.1 GPa and 870 °C by employing the resistor-heating diamond anvil cell (DAC) synchrotron X-ray diffraction technique. Via in situ examination, this study confirms the stability of carbides and MoNbTaW in the carbon doped CCA even under high pressure and high temperature.

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Research Organization:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States). Advanced Light Source (ALS); Southern Univ. and A&M College, Baton Rouge, LA (United States)

Sponsoring Organization:: National Science Foundation (NSF); US Army Research Office (ARO); USDOE; USDOE National Nuclear Security Administration (NNSA); USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-05CH11231; NA0003979

OSTI ID:: 1818805

Journal Information:: Crystals, Journal Name: Crystals Journal Issue: 9 Vol. 11; ISSN CRYSBC; ISSN 2073-4352

Publisher:: MDPI AGCopyright Statement

Country of Publication:: Germany

Language:: English

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36 MATERIALS SCIENCE
calculation of phase diagram
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synchrotron X-ray diffraction

Title: Performance of Carbide Alloy Compounds in Carbon Doped MoNbTaW

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