Analysis of energetics and economics of sub-ambient hybrid post-combustion carbon dioxide capture

DeWitt, Stephen A.; Awati, Rohan; Octavio Rubiera Landa, Héctor; Park, Jongwoo; Kawajiri, Yoshiaki; Sholl, David S.; Realff, Matthew J.; Lively, Ryan P.

doi:10.1002/aic.17403

Title: Analysis of energetics and economics of sub-ambient hybrid post-combustion carbon dioxide capture

Abstract

Abstract Adsorption of CO ₂ from post‐combustion flue gas is one of the leading candidates for globally impactful carbon capture systems. This work focused on understanding the opportunities and limitations of sub‐ambient CO ₂ capture processes utilizing a multistage separation process. A hybrid process design using a combination of pressure‐driven separation of CO ₂ from flue gas (e.g., adsorption‐ or membrane‐based separation) followed by CO ₂ ‐rich product liquefaction to produce high‐purity (>99%) CO ₂ at pipeline conditions is considered. The operating pressure of the separation unit is a key cost parameter and also an important process variable that regulates the available heat removal necessary to reach the sub‐ambient operating conditions. The economic viability of applying pressure swing adsorption (PSA) processes using fiber sorbent contactors with internal heat management was found to be most influenced by the productivity of the adsorption system, with productivities as high as 0.015 /kg _sorb ⁻¹ sec ⁻¹ being required to reduce costs of capture below $60/ton CO ₂ captured. This analysis was carried out using a simplified two‐bed process, and thus there is opportunity for further cost reduction with exploration of more complex cycle designs. Three exemplar fiber sorbents (MIL‐101(Cr), UiO‐66, and zeolite 13X)more »« less

Authors:

^[1]; Awati, Rohan ^[1];

^[1]; Park, Jongwoo ^[1];

^[1];

^[1]

Georgia Institute of Technology, Atlanta, GA (United States)

Publication Date:: Tue Aug 17 00:00:00 EDT 2021

Research Org.:: Georgia Institute of Technology, Atlanta, GA (United States)

Sponsoring Org.:: USDOE Office of Fossil Energy (FE)

OSTI Identifier:: 1976256

Alternate Identifier(s):: OSTI ID: 1818603

Grant/Contract Number:: FE0026433; DE‐FE0026433

Resource Type:: Accepted Manuscript

Journal Name:: AIChE Journal

Additional Journal Information:: Journal Volume: 67; Journal Issue: 11; Journal ID: ISSN 0001-1541

Publisher:: American Institute of Chemical Engineers

Country of Publication:: United States

Language:: English

Subject:: 42 ENGINEERING; CO2 capture; pressure swing adsorption; sub-ambient process; fiber sorbents; heat management

Citation Formats


                    DeWitt, Stephen A., Awati, Rohan, Octavio Rubiera Landa, Héctor, Park, Jongwoo, Kawajiri, Yoshiaki, Sholl, David S., Realff, Matthew J., and Lively, Ryan P. Analysis of energetics and economics of sub-ambient hybrid post-combustion carbon dioxide capture.  United States: N. p., 2021. 
Web.  doi:10.1002/aic.17403.

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                    DeWitt, Stephen A., Awati, Rohan, Octavio Rubiera Landa, Héctor, Park, Jongwoo, Kawajiri, Yoshiaki, Sholl, David S., Realff, Matthew J., & Lively, Ryan P. Analysis of energetics and economics of sub-ambient hybrid post-combustion carbon dioxide capture.  United States.  https://doi.org/10.1002/aic.17403

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                    DeWitt, Stephen A., Awati, Rohan, Octavio Rubiera Landa, Héctor, Park, Jongwoo, Kawajiri, Yoshiaki, Sholl, David S., Realff, Matthew J., and Lively, Ryan P. Tue .  
"Analysis of energetics and economics of sub-ambient hybrid post-combustion carbon dioxide capture".  United States.  https://doi.org/10.1002/aic.17403.  https://www.osti.gov/servlets/purl/1976256.

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@article{osti_1976256,

  title        = {Analysis of energetics and economics of sub-ambient hybrid post-combustion carbon dioxide capture},

  author       = {DeWitt, Stephen A. and Awati, Rohan and Octavio Rubiera Landa, Héctor and Park, Jongwoo and Kawajiri, Yoshiaki and Sholl, David S. and Realff, Matthew J. and Lively, Ryan P.},

  abstractNote = {Abstract Adsorption of CO 2 from post‐combustion flue gas is one of the leading candidates for globally impactful carbon capture systems. This work focused on understanding the opportunities and limitations of sub‐ambient CO 2 capture processes utilizing a multistage separation process. A hybrid process design using a combination of pressure‐driven separation of CO 2 from flue gas (e.g., adsorption‐ or membrane‐based separation) followed by CO 2 ‐rich product liquefaction to produce high‐purity (>99%) CO 2 at pipeline conditions is considered. The operating pressure of the separation unit is a key cost parameter and also an important process variable that regulates the available heat removal necessary to reach the sub‐ambient operating conditions. The economic viability of applying pressure swing adsorption (PSA) processes using fiber sorbent contactors with internal heat management was found to be most influenced by the productivity of the adsorption system, with productivities as high as 0.015 /kg sorb −1 sec −1 being required to reduce costs of capture below $60/ton CO 2 captured. This analysis was carried out using a simplified two‐bed process, and thus there is opportunity for further cost reduction with exploration of more complex cycle designs. Three exemplar fiber sorbents (MIL‐101(Cr), UiO‐66, and zeolite 13X) were considered for application in the sub‐ambient process of PSA unit. Among the considered sorbents, zeolite 13X fiber composites were found to perform better at ambient temperatures as compared to sub‐ambient. MIL‐101(Cr) and UiO‐66 fiber composites had improved purity, recovery, and productivity at colder temperatures reducing costs of capture as low as $61/ton CO 2 . Future economic improvement could be achieved by reducing the required operating pressure of the PSA unit and pushing the Pareto frontier closer to the final pipeline requirement via a combination of PSA cycle design and material selection.},

  doi          = {10.1002/aic.17403},

  journal      = {AIChE Journal},

  number       = 11,

  volume       = 67,

  place        = {United States},

  year         = {Tue Aug 17 00:00:00 EDT 2021},

  month        = {Tue Aug 17 00:00:00 EDT 2021}

}

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Title: Analysis of energetics and economics of sub-ambient hybrid post-combustion carbon dioxide capture

Abstract

Citation Formats

CO2 Capture by Cold Membrane Operation journal, January 2014

Techno-economic Performance of a Hybrid Membrane – Liquefaction Process for Post-combustion CO2 Capture journal, January 2014

Thermodynamics of mixed-gas adsorption journal, January 1965

Synthesis of Distillation Column Configurations for a Multicomponent Separation journal, January 1996

A Review of CO2 Capture by Absorption and Adsorption journal, January 2012

Carbon capture in metal–organic frameworks—a comparative study journal, January 2011

On the inner workings of Monte Carlo codes journal, December 2013

Addressing the Criticalities for the Deployment of Adsorption-based CO2 Capture Processes journal, July 2017

Adsorption of Carbon Dioxide by MIL-101(Cr): Regeneration Conditions and Influence of Flue Gas Contaminants journal, October 2013

Evaluation and optimization of VPSA processes with nanostructured zeolite NaX for post-combustion CO2 capture journal, September 2019

How Reproducible Are Isotherm Measurements in Metal–Organic Frameworks? journal, November 2017

Hybrid Polymer/UiO-66(Zr) and Polymer/NaY Fiber Sorbents for Mercaptan Removal from Natural Gas journal, April 2016

Sub-ambient temperature flue gas carbon dioxide capture via Matrimid® hollow fiber membranes journal, September 2014

High-Temperature Activation of Zeolite-Loaded Fiber Sorbents journal, July 2018

Thermally moderated hollow fiber sorbent modules in rapidly cycled pressure swing adsorption mode for hydrogen purification journal, October 2012

Impact of CO2 impurity on CO2 compression, liquefaction and transportation journal, January 2014

Effects of SO2 on CO2 capture using a hollow fiber membrane contactor journal, December 2013

Impact of intrinsic framework flexibility for selective adsorption of sarin in non-aqueous solvents using metal–organic frameworks journal, January 2020

Critical Comparison of Structured Contactors for Adsorption-Based Gas Separations journal, June 2018

How Well Do Approximate Models of Adsorption-Based CO 2 Capture Processes Predict Results of Detailed Process Models? journal, January 2020

New CCS system integration with CO2 carrier and liquefaction process journal, January 2011

Database for CO 2 Separation Performances of MOFs Based on Computational Materials Screening journal, May 2018

Estimating refrigeration costs at cryogenic temperatures journal, August 2017

Water-Lean Solvents for Post-Combustion CO 2 Capture: Fundamentals, Uncertainties, Opportunities, and Outlook journal, May 2017

SOCEMO: Surrogate Optimization of Computationally Expensive Multiobjective Problems journal, November 2017

Air separation and liquefaction: recent developments and prospects for the beginning of the new millennium journal, January 2002

Stabilization Wedges: Solving the Climate Problem for the Next 50 Years with Current Technologies journal, August 2004

Thin zeolite laminates for rapid and energy-efficient carbon capture journal, September 2017

Advancing Adsorption and Membrane Separation Processes for the Gigaton Carbon Capture Challenge journal, June 2014

Rational design of temperature swing adsorption cycles for post-combustion CO 2 capture journal, February 2017

Amine Scrubbing for CO2 Capture journal, September 2009

Process-integrated design of a sub-ambient membrane process for CO2 removal from natural gas power plants journal, February 2020

Effect of Rinse and Recycle Methods on the Pressure Swing Adsorption Process To Recover CO2 from Power Plant Flue Gas Using Activated Carbon journal, October 2002

CO2 capture by sub-ambient membrane operation journal, January 2013

Simulation and Energy Evaluation of Two Novel Solvents Developed in the EU Project HiPerCap journal, July 2017

Advancement in porous adsorbents for post-combustion CO2 capture journal, March 2019

Multiobjective Optimization of a Four-Step Adsorption Process for Postcombustion CO 2 Capture Via Finite Volume Simulation journal, February 2013

Reducing the energy consumption of membrane-cryogenic hybrid CO2 capture by process optimization journal, April 2017

Predicting multicomponent adsorption: 50 years of the ideal adsorbed solution theory journal, August 2015

High-yield, fluoride-free and large-scale synthesis of MIL-101(Cr) journal, January 2015

CO 2 capture from dry flue gas by vacuum swing adsorption: A pilot plant study journal, March 2014

Efficiently Exploring Adsorption Space to Identify Privileged Adsorbents for Chemical Separations of a Diverse Set of Molecules journal, April 2018

CO2 capture by vacuum swing adsorption: role of multiple pressure equalization steps journal, September 2015

Post-combustion CO2 capture with the HKUST-1 and MIL-101(Cr) metal–organic frameworks: Adsorption, separation and regeneration investigations journal, September 2013

Cycle synthesis and optimization of a VSA process for postcombustion CO 2 capture journal, August 2013

Economic impacts of carbon dioxide and methane released from thawing permafrost journal, September 2015

Hierarchical N-Doped Carbon as CO 2 Adsorbent with High CO 2 Selectivity from Rationally Designed Polypyrrole Precursor journal, January 2016

How Useful Are Common Simulants of Chemical Warfare Agents at Predicting Adsorption Behavior? journal, October 2018

Power plant post-combustion carbon dioxide capture: An opportunity for membranes journal, September 2010

Using molecular simulation to characterise metal–organic frameworks for adsorption applications journal, January 2009

Establishing upper bounds on CO 2 swing capacity in sub-ambient pressure swing adsorption via molecular simulation of metal–organic frameworks journal, January 2017

Post combustion CO2 capture by carbon fibre monolithic adsorbents journal, October 2009

Low temperature swing process for CO2 absorption-desorption using phase separation CO2 capture solvent journal, August 2018

Recent progress on fabrication methods of polymeric thin film gas separation membranes for CO2 capture journal, February 2019

Cooperative insertion of CO2 in diamine-appended metal-organic frameworks journal, March 2015

A method for efficiently solving the IAST equations with an application to adsorber dynamics journal, September 2012

Screening CO 2 /N 2 selectivity in metal-organic frameworks using Monte Carlo simulations and ideal adsorbed solution theory journal, December 2011

An optimal design methodology for large-scale gas liquefaction journal, November 2012

CO 2 Sorption Performance of Composite Polymer/Aminosilica Hollow Fiber Sorbents: An Experimental and Modeling Study journal, February 2015

Assessing the risk of corrosion in amine-based CO2 capture process journal, September 2016

Carbon capture and storage (CCS): the way forward journal, January 2018

Integrated Adsorbent Process Optimization for Minimum Cost of Electricity Including Carbon Capture by a VSA Process journal, September 2018

A New Multi-bed Vacuum Swing Adsorption Cycle for CO2 Capture from Flue Gas Streams journal, July 2017

MOF-801 incorporated PEBA mixed-matrix composite membranes for CO2 capture journal, June 2019

CO2 Capture by Cold Membrane Operation
journal, January 2014

Techno-economic Performance of a Hybrid Membrane – Liquefaction Process for Post-combustion CO2 Capture
journal, January 2014

Thermodynamics of mixed-gas adsorption
journal, January 1965

Synthesis of Distillation Column Configurations for a Multicomponent Separation
journal, January 1996

A Review of CO2 Capture by Absorption and Adsorption
journal, January 2012

Carbon capture in metal–organic frameworks—a comparative study
journal, January 2011

On the inner workings of Monte Carlo codes
journal, December 2013

Addressing the Criticalities for the Deployment of Adsorption-based CO2 Capture Processes
journal, July 2017

Adsorption of Carbon Dioxide by MIL-101(Cr): Regeneration Conditions and Influence of Flue Gas Contaminants
journal, October 2013

Evaluation and optimization of VPSA processes with nanostructured zeolite NaX for post-combustion CO2 capture
journal, September 2019

How Reproducible Are Isotherm Measurements in Metal–Organic Frameworks?
journal, November 2017

Hybrid Polymer/UiO-66(Zr) and Polymer/NaY Fiber Sorbents for Mercaptan Removal from Natural Gas
journal, April 2016

Sub-ambient temperature flue gas carbon dioxide capture via Matrimid® hollow fiber membranes
journal, September 2014

High-Temperature Activation of Zeolite-Loaded Fiber Sorbents
journal, July 2018

Thermally moderated hollow fiber sorbent modules in rapidly cycled pressure swing adsorption mode for hydrogen purification
journal, October 2012

Impact of CO2 impurity on CO2 compression, liquefaction and transportation
journal, January 2014

Effects of SO2 on CO2 capture using a hollow fiber membrane contactor
journal, December 2013

Impact of intrinsic framework flexibility for selective adsorption of sarin in non-aqueous solvents using metal–organic frameworks
journal, January 2020

Critical Comparison of Structured Contactors for Adsorption-Based Gas Separations
journal, June 2018

How Well Do Approximate Models of Adsorption-Based CO ₂ Capture Processes Predict Results of Detailed Process Models?
journal, January 2020

New CCS system integration with CO2 carrier and liquefaction process
journal, January 2011

Database for CO ₂ Separation Performances of MOFs Based on Computational Materials Screening
journal, May 2018

Estimating refrigeration costs at cryogenic temperatures
journal, August 2017

Water-Lean Solvents for Post-Combustion CO ₂ Capture: Fundamentals, Uncertainties, Opportunities, and Outlook
journal, May 2017

SOCEMO: Surrogate Optimization of Computationally Expensive Multiobjective Problems
journal, November 2017

Air separation and liquefaction: recent developments and prospects for the beginning of the new millennium
journal, January 2002

Stabilization Wedges: Solving the Climate Problem for the Next 50 Years with Current Technologies
journal, August 2004

Thin zeolite laminates for rapid and energy-efficient carbon capture
journal, September 2017

Advancing Adsorption and Membrane Separation Processes for the Gigaton Carbon Capture Challenge
journal, June 2014

Rational design of temperature swing adsorption cycles for post-combustion CO 2 capture
journal, February 2017

Amine Scrubbing for CO2 Capture
journal, September 2009

Process-integrated design of a sub-ambient membrane process for CO2 removal from natural gas power plants
journal, February 2020

Effect of Rinse and Recycle Methods on the Pressure Swing Adsorption Process To Recover CO₂ from Power Plant Flue Gas Using Activated Carbon
journal, October 2002

CO2 capture by sub-ambient membrane operation
journal, January 2013

Simulation and Energy Evaluation of Two Novel Solvents Developed in the EU Project HiPerCap
journal, July 2017

Advancement in porous adsorbents for post-combustion CO2 capture
journal, March 2019

Multiobjective Optimization of a Four-Step Adsorption Process for Postcombustion CO ₂ Capture Via Finite Volume Simulation
journal, February 2013

Reducing the energy consumption of membrane-cryogenic hybrid CO2 capture by process optimization
journal, April 2017

Predicting multicomponent adsorption: 50 years of the ideal adsorbed solution theory
journal, August 2015

High-yield, fluoride-free and large-scale synthesis of MIL-101(Cr)
journal, January 2015

CO ₂ capture from dry flue gas by vacuum swing adsorption: A pilot plant study
journal, March 2014

Efficiently Exploring Adsorption Space to Identify Privileged Adsorbents for Chemical Separations of a Diverse Set of Molecules
journal, April 2018

CO2 capture by vacuum swing adsorption: role of multiple pressure equalization steps
journal, September 2015

Post-combustion CO2 capture with the HKUST-1 and MIL-101(Cr) metal–organic frameworks: Adsorption, separation and regeneration investigations
journal, September 2013

Cycle synthesis and optimization of a VSA process for postcombustion CO ₂ capture
journal, August 2013

Economic impacts of carbon dioxide and methane released from thawing permafrost
journal, September 2015

Hierarchical N-Doped Carbon as CO ₂ Adsorbent with High CO ₂ Selectivity from Rationally Designed Polypyrrole Precursor
journal, January 2016

How Useful Are Common Simulants of Chemical Warfare Agents at Predicting Adsorption Behavior?
journal, October 2018

Power plant post-combustion carbon dioxide capture: An opportunity for membranes
journal, September 2010

Using molecular simulation to characterise metal–organic frameworks for adsorption applications
journal, January 2009

Establishing upper bounds on CO ₂ swing capacity in sub-ambient pressure swing adsorption via molecular simulation of metal–organic frameworks
journal, January 2017

Post combustion CO2 capture by carbon fibre monolithic adsorbents
journal, October 2009

Low temperature swing process for CO2 absorption-desorption using phase separation CO2 capture solvent
journal, August 2018

Recent progress on fabrication methods of polymeric thin film gas separation membranes for CO2 capture
journal, February 2019

Cooperative insertion of CO2 in diamine-appended metal-organic frameworks
journal, March 2015

A method for efficiently solving the IAST equations with an application to adsorber dynamics
journal, September 2012

Screening CO ₂ /N ₂ selectivity in metal-organic frameworks using Monte Carlo simulations and ideal adsorbed solution theory
journal, December 2011

An optimal design methodology for large-scale gas liquefaction
journal, November 2012

CO ₂ Sorption Performance of Composite Polymer/Aminosilica Hollow Fiber Sorbents: An Experimental and Modeling Study
journal, February 2015

Assessing the risk of corrosion in amine-based CO2 capture process
journal, September 2016

Carbon capture and storage (CCS): the way forward
journal, January 2018

Integrated Adsorbent Process Optimization for Minimum Cost of Electricity Including Carbon Capture by a VSA Process
journal, September 2018

A New Multi-bed Vacuum Swing Adsorption Cycle for CO2 Capture from Flue Gas Streams
journal, July 2017

MOF-801 incorporated PEBA mixed-matrix composite membranes for CO2 capture
journal, June 2019