Polyethylene Hydrogenolysis at Mild Conditions over Ruthenium on Tungstated Zirconia

Wang, Cong; Xie, Tianjun; Kots, Pavel A.; Vance, Brandon C.; Yu, Kewei; Kumar, Pawan; Fu, Jiayi; Liu, Sibao; Tsilomelekis, George; Stach, Eric A.; Zheng, Weiqing; Vlachos, Dionisios G.

doi:10.1021/jacsau.1c00200

Title: Polyethylene Hydrogenolysis at Mild Conditions over Ruthenium on Tungstated Zirconia

Journal Article · 29 August 2021 · JACS Au

DOI: https://doi.org/10.1021/jacsau.1c00200 · OSTI ID:1817830

^[1]; Xie, Tianjun ^[1]; Kots, Pavel A. ^[1]; Vance, Brandon C. ^[2]; Yu, Kewei ^[3];

^[4]; Fu, Jiayi ^[3]; Liu, Sibao ^[5];

^[6];

^[4]; Zheng, Weiqing ^[1];

^[2]

Center for Plastics Innovation, University of Delaware, 221 Academy Street, Newark, Delaware 19716, United States
Center for Plastics Innovation, University of Delaware, 221 Academy Street, Newark, Delaware 19716, United States, Department of Chemical and Biomolecular Engineering, University of Delaware, 150 Academy Street, Newark, Delaware 19716, United States
Department of Chemical and Biomolecular Engineering, University of Delaware, 150 Academy Street, Newark, Delaware 19716, United States
Department of Materials Science and Engineering, University of Pennsylvania, Philadelphia, Pennsylvania 19104, United States
Key Laboratory for Green Chemical Technology of Ministry of Education, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China
Department of Chemical and Biochemical Engineering, School of Engineering, Rutgers, The State University of New Jersey, Piscataway, New Jersey 08854, United States

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Research Organization:: Univ. of Delaware, Newark, DE (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0012704; SC0021166

OSTI ID:: 1817830

Journal Information:: JACS Au, Journal Name: JACS Au Journal Issue: 9 Vol. 1; ISSN 2691-3704

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

References (72)

Polyethylene catalytic hydrocracking by PtHZSM-5, PtHY, and PtHMCM-41 Hesse, Nathan D.; White, Robert L. Journal of Applied Polymer Science, Vol. 92, Issue 2 https://doi.org/10.1002/app.20083	journal	January 2004
Catalytic Production of Branched Small Alkanes from Biohydrocarbons Oya, Shin-ichi; Kanno, Daisuke; Watanabe, Hideo ChemSusChem, Vol. 8, Issue 15 https://doi.org/10.1002/cssc.201500375	journal	June 2015
Regioselectivity and Reaction Mechanism of Ru-Catalyzed Hydrogenolysis of Squalane and Model Alkanes Nakagawa, Yoshinao; Oya, Shin-ichi; Kanno, Daisuke ChemSusChem, Vol. 10, Issue 1 https://doi.org/10.1002/cssc.201601204	journal	November 2016
Selective Hydrogenolysis of Glycerol to 1,3-Propanediol: Manipulating the Frustrated Lewis Pairs by Introducing Gold to Pt/WO _x Zhao, Xiaochen; Wang, Jia; Yang, Man ChemSusChem, Vol. 10, Issue 5 https://doi.org/10.1002/cssc.201601503	journal	December 2016
The Chemistry and Kinetics of Polyethylene Pyrolysis: A Process to Produce Fuels and Chemicals Zhao, Dongting; Wang, Xianhua; Miller, James B. ChemSusChem, Vol. 13, Issue 7 https://doi.org/10.1002/cssc.201903434	journal	February 2020
The Use of Heterogeneous Catalysis in the Chemical Valorization of Plastic Waste Mark, Lesli O.; Cendejas, Melissa C.; Hermans, Ive ChemSusChem, Vol. 13, Issue 22 https://doi.org/10.1002/cssc.202001905	journal	October 2020
Effect of the damping function in dispersion corrected density functional theory Grimme, Stefan; Ehrlich, Stephan; Goerigk, Lars Journal of Computational Chemistry, Vol. 32, Issue 7 https://doi.org/10.1002/jcc.21759	journal	March 2011
Resolving ruthenium: XPS studies of common ruthenium materials Morgan, David J. Surface and Interface Analysis, Vol. 47, Issue 11 https://doi.org/10.1002/sia.5852	journal	September 2015
Anwendung von kinetischen Methoden f�r die Untersuchung der Struktur und der Reaktionen der Bildung von hochmolekularen Aquowolframaten Spitzin, Vikt. I.; Kabanow, V. J. Zeitschrift f�r anorganische und allgemeine Chemie, Vol. 322, Issue 5-6 https://doi.org/10.1002/zaac.19633220505	journal	June 1963
Role of Hydrogen Spillover in Methanol Synthesis over Cu/ZrO2 Jung, Kwang-Deog; Bell, Alexis T. Journal of Catalysis, Vol. 193, Issue 2 https://doi.org/10.1006/jcat.2000.2881	journal	July 2000
Catalytic hydrogenolysis on metals Sinfelt, J. H. Catalysis Letters, Vol. 9, Issue 3-4 https://doi.org/10.1007/BF00773174	journal	January 1991
A Study of Tetrahydrofurfuryl Alcohol to 1,5-Pentanediol Over Pt–WOx/C Wang, Cong; Lee, Jennifer D.; Ji, Yichen Catalysis Letters, Vol. 148, Issue 4 https://doi.org/10.1007/s10562-018-2323-6	journal	February 2018
H-D Exchange of Simple Aromatics as a Measure of Brønsted-Acid Site Strengths in Solids Wang, Cong; Li, Sha; Mao, Xinyu Catalysis Letters, Vol. 148, Issue 11 https://doi.org/10.1007/s10562-018-2563-5	journal	September 2018
Molecular Redistribution and Molecular Averaging: Disproportionation of Paraffins via Bifunctional Catalysis Chen, C. Y.; O’Rear, D. J.; Leung, P. Topics in Catalysis, Vol. 55, Issue 19-20 https://doi.org/10.1007/s11244-012-9910-3	journal	October 2012
Multiwavelength Raman Spectroscopic Characterization of Alumina-Supported Molybdenum Oxide Prepared by Vapor Deposition Drake, Tasha L.; Stair, Peter C. Topics in Catalysis, Vol. 60, Issue 19-20 https://doi.org/10.1007/s11244-017-0842-9	journal	November 2017
Composite zeolite beta catalysts for catalytic hydrocracking of plastic waste to liquid fuels Munir, Dureem; Amer, Hassaan; Aslam, Rabya Materials for Renewable and Sustainable Energy, Vol. 9, Issue 2 https://doi.org/10.1007/s40243-020-00169-3	journal	April 2020
Hydrogenolysis of n-heptane over unsupported metals Carter, J. Journal of Catalysis, Vol. 20, Issue 2 https://doi.org/10.1016/0021-9517(71)90083-2	journal	February 1971
Fischer-Tropsch synthesis on cobalt and ruthenium. Metal dispersion and support effects on reaction rate and selectivity Iglesia, E. Journal of Catalysis, Vol. 137, Issue 1 https://doi.org/10.1016/0021-9517(92)90150-G	journal	September 1992
Infrared and Raman study of WO₃ tungsten trioxides and WO₃, xH₂O tungsten trioxide tydrates Daniel, M. F.; Desbat, B.; Lassegues, J. C. Journal of Solid State Chemistry, Vol. 67, Issue 2, p. 235-247 https://doi.org/10.1016/0022-4596(87)90359-8	journal	April 1987
Infrared and Raman spectroscopies of rf sputtered tungsten oxide films Daniel, M. F.; Desbat, B.; Lassegues, J. C. Journal of Solid State Chemistry, Vol. 73, Issue 1 https://doi.org/10.1016/0022-4596(88)90062-X	journal	March 1988
The structure of the p(√3 × √3)R30° bilayer of D2O on Ru(001) Held, G.; Menzel, D. Surface Science, Vol. 316, Issue 1-2 https://doi.org/10.1016/0039-6028(94)91131-2	journal	September 1994
Catalytic and structural properties of ruthenium bimetallic catalysts: Preparation and characterization Coq, Bernard; Crabb, Eleanor; Warawdekar, Mayukh Journal of Molecular Catalysis, Vol. 92, Issue 1 https://doi.org/10.1016/0304-5102(94)85006-2	journal	August 1994
Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set Kresse, G.; Furthmüller, J. Computational Materials Science, Vol. 6, Issue 1, p. 15-50 https://doi.org/10.1016/0927-0256(96)00008-0	journal	July 1996
Selective isomerization of alkanes on supported tungsten oxide acids Iglesia, Enrique; Barton, David G.; Soled, Stuart L. Studies in Surface Science and Catalysis, Vol. 101, p. 533-542 https://doi.org/10.1016/S0167-2991(96)80264-3	book	January 1996
Pd-modified beta zeolite for modulated hydro-cracking of low-density polyethylene into a paraffinic-rich hydrocarbon fuel Pyra, Kamila; Tarach, Karolina A.; Śrębowata, Anna Applied Catalysis B: Environmental, Vol. 277 https://doi.org/10.1016/j.apcatb.2020.119070	journal	November 2020
Low-temperature catalytic upgrading of waste polyolefinic plastics into liquid fuels and waxes Nakaji, Yosuke; Tamura, Masazumi; Miyaoka, Shuhei Applied Catalysis B: Environmental, Vol. 285 https://doi.org/10.1016/j.apcatb.2020.119805	journal	May 2021
Single Pot Catalyst Strategy to Branched Products via Adhesive Isomerization and Hydrocracking of Polyethylene over Platinum Tungstated Zirconia Vance, Brandon C.; Kots, Pavel A.; Wang, Cong Applied Catalysis B: Environmental https://doi.org/10.1016/j.apcatb.2021.120483	journal	June 2021
Deconstruction of high-density polyethylene into liquid hydrocarbon fuels and lubricants by hydrogenolysis over Ru catalyst Jia, Chuhua; Xie, Shaoqu; Zhang, Wanli Chem Catalysis, Vol. 1, Issue 2 https://doi.org/10.1016/j.checat.2021.04.002	journal	July 2021
Catalytic activity of zeolitic and mesostructured catalysts in the cracking of pure and waste polyolefins Aguado, J.; Serrano, D. P.; Miguel, G. San Journal of Analytical and Applied Pyrolysis, Vol. 78, Issue 1 https://doi.org/10.1016/j.jaap.2006.06.004	journal	January 2007
New insights into the nature of the acidic catalytic active sites present in ZrO2-supported tungsten oxide catalysts Rossmedgaarden, E.; Knowles, W.; Kim, T. Journal of Catalysis, Vol. 256, Issue 1 https://doi.org/10.1016/j.jcat.2008.03.003	journal	May 2008
Low temperature synthesis of nanocrystalline WO3 films by sol–gel process Djaoued, Y.; Priya, S.; Balaji, S. Journal of Non-Crystalline Solids, Vol. 354, Issue 2-9 https://doi.org/10.1016/j.jnoncrysol.2007.07.090	journal	January 2008
Hydrocracking of virgin and post-consumer polymers Jumah, Abdulrahman bin; Tedstone, Aleksander A.; Garforth, Arthur A. Microporous and Mesoporous Materials, Vol. 315 https://doi.org/10.1016/j.micromeso.2021.110912	journal	February 2021
Drawing behavior and mechanical properties of ultra-high molecular weight polyethylene blends with a linear polyethylene wax Shen, Lihua; Severn, John; Bastiaansen, Cees W. M. Polymer, Vol. 153 https://doi.org/10.1016/j.polymer.2018.01.083	journal	September 2018
The kinetics of H2 adsorption on supported ruthenium catalysts Lin, Hsin-Yu; Chen, Yu-Wen Thermochimica Acta, Vol. 419, Issue 1-2 https://doi.org/10.1016/j.tca.2004.03.007	journal	September 2004
Catalytic hydrocracking of synthetic polymers into grid-compatible gas streams Lee, Wei-Tse; Bobbink, Felix D.; van Muyden, Antoine P. Cell Reports Physical Science, Vol. 2, Issue 2 https://doi.org/10.1016/j.xcrp.2021.100332	journal	February 2021
Oxidation Behavior and Kinetics of Eight C ₂₀ –C ₅₄ n -Alkanes by High Pressure Differential Scanning Calorimetry (HP-DSC) Yuan, Chengdong; Emelianov, Dmitrii A.; Varfolomeev, Mikhail A. Energy & Fuels, Vol. 32, Issue 7 https://doi.org/10.1021/acs.energyfuels.8b01401	journal	June 2018
Trash to Treasure: Microwave-Assisted Conversion of Polyethylene to Functional Chemicals Bäckström, Eva; Odelius, Karin; Hakkarainen, Minna Industrial & Engineering Chemistry Research, Vol. 56, Issue 50 https://doi.org/10.1021/acs.iecr.7b04091	journal	December 2017
Catalyzing the Hydrocracking of Low Density Polyethylene Bin Jumah, Abdulrahman; Anbumuthu, Vanithasri; Tedstone, Aleksander A. Industrial & Engineering Chemistry Research, Vol. 58, Issue 45 https://doi.org/10.1021/acs.iecr.9b04263	journal	October 2019
Nature of Catalytically Active Sites in the Supported WO ₃ /ZrO ₂ Solid Acid System: A Current Perspective Zhou, Wu; Soultanidis, Nikolaos; Xu, Hui ACS Catalysis, Vol. 7, Issue 3 https://doi.org/10.1021/acscatal.6b03697	journal	February 2017
Mechanistic Study of the Direct Hydrodeoxygenation of m -Cresol over WO _x -Decorated Pt/C Catalysts Wang, Cong; Mironenko, Alexander V.; Raizada, Abhishek ACS Catalysis, Vol. 8, Issue 9 https://doi.org/10.1021/acscatal.8b01746	journal	July 2018
Catalytic Hydrogenolysis of Polyolefins into Alkanes Sánchez-Rivera, Kevin L.; Huber, George W. ACS Central Science, Vol. 7, Issue 1 https://doi.org/10.1021/acscentsci.0c01637	journal	December 2020
Upcycling Single-Use Polyethylene into High-Quality Liquid Products Celik, Gokhan; Kennedy, Robert M.; Hackler, Ryan A. ACS Central Science, Vol. 5, Issue 11 https://doi.org/10.1021/acscentsci.9b00722	journal	September 2019
Tandem Heterogeneous Catalysis for Polyethylene Depolymerization via an Olefin-Intermediate Process Ellis, Lucas D.; Orski, Sara V.; Kenlaw, Grace A. ACS Sustainable Chemistry & Engineering, Vol. 9, Issue 2 https://doi.org/10.1021/acssuschemeng.0c07612	journal	January 2021
Nonstoichiometric Tungsten Oxide Based on Hexagonal WO ₃ Solonin, Yu. M.; Khyzhun, O. Yu.; Graivoronskaya, E. A. Crystal Growth & Design, Vol. 1, Issue 6 https://doi.org/10.1021/cg015545z	journal	November 2001
Hydrogen Spillover. Facts and Fiction Prins, R. Chemical Reviews, Vol. 112, Issue 5 https://doi.org/10.1021/cr200346z	journal	February 2012
Developing Advanced Catalysts for the Conversion of Polyolefinic Waste Plastics into Fuels and Chemicals Serrano, D. P.; Aguado, J.; Escola, J. M. ACS Catalysis, Vol. 2, Issue 9 https://doi.org/10.1021/cs3003403	journal	August 2012
Catalytic Conversion of Polyolefins into Liquid Fuels over MCM-41: Comparison with ZSM-5 and Amorphous SiO ₂ −Al ₂ O ₃ Aguado, J.; Sotelo, J. L.; Serrano, D. P. Energy & Fuels, Vol. 11, Issue 6 https://doi.org/10.1021/ef970055v	journal	November 1997
Investigation of the Catalytic Pyrolysis of High-Density Polyethylene over a HZSM-5 Catalyst in a Laboratory Fluidized-Bed Reactor Sharratt, P. N.; Lin, Y. -H.; Garforth, A. A. Industrial & Engineering Chemistry Research, Vol. 36, Issue 12 https://doi.org/10.1021/ie970348b	journal	December 1997
Metal-Catalyzed C–C Bond Cleavage in Alkanes: Effects of Methyl Substitution on Transition-State Structures and Stability Flaherty, David W.; Hibbitts, David D.; Iglesia, Enrique Journal of the American Chemical Society, Vol. 136, Issue 27 https://doi.org/10.1021/ja5037429	journal	June 2014
Conversion of Polyolefin Waste to Liquid Alkanes with Ru-Based Catalysts under Mild Conditions Rorrer, Julie E.; Beckham, Gregg T.; Román-Leshkov, Yuriy JACS Au, Vol. 1, Issue 1 https://doi.org/10.1021/jacsau.0c00041	journal	December 2020
Structural Determination of Bulk and Surface Tungsten Oxides with UV−vis Diffuse Reflectance Spectroscopy and Raman Spectroscopy Ross-Medgaarden, Elizabeth I.; Wachs, Israel E. The Journal of Physical Chemistry C, Vol. 111, Issue 41 https://doi.org/10.1021/jp074219c	journal	September 2007
Hydrogen Adsorption on Ru/ZrO ₂ Studied by FT-IR Ishikawa, Hiroyuki; Kondo, Junko N.; Domen, Kazunari The Journal of Physical Chemistry B, Vol. 103, Issue 16 https://doi.org/10.1021/jp9842852	journal	April 1999
Identification of active Zr–WOx clusters on a ZrO2 support for solid acid catalysts Zhou, Wu; Ross-Medgaarden, Elizabeth I.; Knowles, William V. Nature Chemistry, Vol. 1, Issue 9 https://doi.org/10.1038/nchem.433	journal	November 2009
Catalytic upcycling of high-density polyethylene via a processive mechanism Tennakoon, Akalanka; Wu, Xun; Paterson, Alexander L. Nature Catalysis, Vol. 3, Issue 11 https://doi.org/10.1038/s41929-020-00519-4	journal	October 2020
The relationship between the degree of branching and glass transition temperature of branched polyethylene: experiment and simulation Luo, Xiang; Xie, Shijie; Liu, Jun Polym. Chem., Vol. 5, Issue 4 https://doi.org/10.1039/C3PY00896G	journal	January 2014
Heterogeneous catalytic hydrogenation of CO ₂ by metal oxides: defect engineering – perfecting imperfection Jia, Jia; Qian, Chenxi; Dong, Yuchan Chemical Society Reviews, Vol. 46, Issue 15 https://doi.org/10.1039/C7CS00026J	journal	January 2017
Synthesis of Mo and Ru solid-solution alloy NPs and their hydrogen evolution reaction activity Okazoe, Shinya; Kusada, Kohei; Wu, Dongshuang Chemical Communications, Vol. 56, Issue 92 https://doi.org/10.1039/D0CC05958G	journal	January 2020
A consistent and accurate ab initio parametrization of density functional dispersion correction (DFT-D) for the 94 elements H-Pu Grimme, Stefan; Antony, Jens; Ehrlich, Stephan The Journal of Chemical Physics, Vol. 132, Issue 15 https://doi.org/10.1063/1.3382344	journal	April 2010
Crystal structure and paramagnetic behaviour of Salje, Ekhard K. H.; Rehmann, Stephan; Pobell, Frank Journal of Physics: Condensed Matter, Vol. 9, Issue 31 https://doi.org/10.1088/0953-8984/9/31/010	journal	August 1997
Special points for Brillouin-zone integrations Monkhorst, Hendrik J.; Pack, James D. Physical Review B, Vol. 13, Issue 12, p. 5188-5192 https://doi.org/10.1103/PhysRevB.13.5188	journal	June 1976
Ab initiomolecular dynamics for liquid metals Kresse, G.; Hafner, J. Physical Review B, Vol. 47, Issue 1, p. 558-561 https://doi.org/10.1103/PhysRevB.47.558	journal	January 1993
Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set Kresse, G.; Furthmüller, J. Physical Review B, Vol. 54, Issue 16, p. 11169-11186 https://doi.org/10.1103/PhysRevB.54.11169	journal	October 1996
From ultrasoft pseudopotentials to the projector augmented-wave method Kresse, G.; Joubert, D. Physical Review B, Vol. 59, Issue 3, p. 1758-1775 https://doi.org/10.1103/PhysRevB.59.1758	journal	January 1999
ATHENA , ARTEMIS , HEPHAESTUS : data analysis for X-ray absorption spectroscopy using IFEFFIT Ravel, B.; Newville, M. Journal of Synchrotron Radiation, Vol. 12, Issue 4 https://doi.org/10.1107/S0909049505012719	journal	June 2005
Production, use, and fate of all plastics ever made Geyer, Roland; Jambeck, Jenna R.; Law, Kara Lavender Science Advances, Vol. 3, Issue 7 https://doi.org/10.1126/sciadv.1700782	journal	July 2017
Plastic waste to fuels by hydrocracking at mild conditions Liu, Sibao; Kots, Pavel A.; Vance, Brandon C. Science Advances, Vol. 7, Issue 17 https://doi.org/10.1126/sciadv.abf8283	journal	April 2021
Catalytic Alkane Metathesis by Tandem Alkane Dehydrogenation-Olefin Metathesis Goldman, Alan S.; Roy, Amy H.; Huang, Zheng Science, Vol. 312, Issue 5771, p. 257-261 https://doi.org/10.1126/science.1123787	journal	April 2006
Polyethylene upcycling to long-chain alkylaromatics by tandem hydrogenolysis/aromatization Zhang, Fan; Zeng, Manhao; Yappert, Ryan D. Science, Vol. 370, Issue 6515 https://doi.org/10.1126/science.abc5441	journal	October 2020
CRC Handbook of Chemistry and Physics Haynes, William M. CRC Press https://doi.org/10.1201/b17118	book	June 2014
The Determination of The Homologous Purity of Higher Normal Alkanes up to Dohectane with Capillary Gas Chromatography Urabe, Yoshiko; Takamizawa, Kanichiro Polymer Journal, Vol. 26, Issue 3 https://doi.org/10.1295/polymj.26.283	journal	March 1994
A Characterization Study of Reactive Sites in ALD-Synthesized WOx/ZrO2 Catalysts Wang, Cong; Mao, Xinyu; Lee, Jennifer Catalysts, Vol. 8, Issue 7 https://doi.org/10.3390/catal8070292	journal	July 2018
Nanoparticle size evaluation of catalysts by EXAFS: Advantages and limitations Marinkovic, Nebojsa; Sasaki, Kotaro; Adzic, Radoslav Zastita materijala, Vol. 57, Issue 1 https://doi.org/10.5937/ZasMat1601101M	journal	January 2016

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
catalysts
cluster chemistry
hydrocarbons
hydrogen
hydrogen spillover
hydrogenolysis
low-density polyethylene
plastic waste
redox reactions
ruthenium
tungstated zirconia

Title: Polyethylene Hydrogenolysis at Mild Conditions over Ruthenium on Tungstated Zirconia

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