Trisulfur radical anion S 3 •− —A major carrier for platinum in hydrothermal fluids

Xu, Hongwu

doi:10.1073/pnas.2112956118

Title: Trisulfur radical anion S ₃ ^•− —A major carrier for platinum in hydrothermal fluids

Journal Article · 29 August 2021 · Proceedings of the National Academy of Sciences of the United States of America

DOI: https://doi.org/10.1073/pnas.2112956118 · OSTI ID:1817801

Xu, Hongwu ^[1]

Earth and Environmental Sciences Division, Los Alamos National Laboratory, Los Alamos, NM 87545

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Sponsoring Organization:: USDOE

OSTI ID:: 1817801

Journal Information:: Proceedings of the National Academy of Sciences of the United States of America, Journal Name: Proceedings of the National Academy of Sciences of the United States of America Journal Issue: 36 Vol. 118; ISSN 0027-8424

Publisher:: Proceedings of the National Academy of SciencesCopyright Statement

Country of Publication:: United States

Language:: English

References (18)

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Experimental investigation of the hydrothermal geochemistry of platinum and palladium: II. The solubility of PtS and PdS in aqueous sulfide solutions to 300°C Gammons, C. H.; Bloom, M. S. Geochimica et Cosmochimica Acta, Vol. 57, Issue 11 https://doi.org/10.1016/0016-7037(93)90409-P	journal	June 1993
Hydrothermal diamond anvil cell for XAFS studies of first-row transition elements in aqueous solution up to supercritical conditions Bassett, William A.; Anderson, Alan J.; Mayanovic, Robert A. Chemical Geology, Vol. 167, Issue 1-2 https://doi.org/10.1016/S0009-2541(99)00196-5	journal	June 2000
Solubility and transport of platinum-group elements in supercritical fluids: summary and estimates of thermodynamic properties for ruthenium, rhodium, palladium, and platinum solids, aqueous ions, and complexes to 1000°C and 5 kbar Sassani, David C.; Shock, Everett L. Geochimica et Cosmochimica Acta, Vol. 62, Issue 15 https://doi.org/10.1016/S0016-7037(98)00049-0	journal	August 1998
The solubility of cooperite PtS(cr) at 25 – 450 °C, Psat – 1000 bar and hydrosulfide complexing of platinum in hydrothermal fluids Filimonova, Olga N.; Tagirov, Boris R.; Zotov, Alexander V. Chemical Geology, Vol. 559 https://doi.org/10.1016/j.chemgeo.2020.119968	journal	January 2021
Structure, stability and geochemical role of palladium chloride complexes in hydrothermal fluids Bazarkina, Elena F.; Pokrovski, Gleb S.; Hazemann, Jean-Louis Geochimica et Cosmochimica Acta, Vol. 146 https://doi.org/10.1016/j.gca.2014.09.024	journal	December 2014
Platinum transport in chloride-bearing fluids and melts: Insights from in situ X-ray absorption spectroscopy and thermodynamic modeling Tagirov, Boris R.; Filimonova, Olga N.; Trigub, Alexander L. Geochimica et Cosmochimica Acta, Vol. 254 https://doi.org/10.1016/j.gca.2019.03.023	journal	June 2019
The Structure of Yb ³⁺ Aquo Ion and Chloro Complexes in Aqueous Solutions at Up to 500 °C and 270 MPa Mayanovic, Robert A.; Jayanetti, Sumedha; Anderson, Alan J. The Journal of Physical Chemistry A, Vol. 106, Issue 28 https://doi.org/10.1021/jp020140q	journal	June 2002
Ubiquitous trisulfur radical anion: fundamentals and applications in materials science, electrochemistry, analytical chemistry and geochemistry Chivers, Tristram; Elder, Philip J. W. Chemical Society Reviews, Vol. 42, Issue 14 https://doi.org/10.1039/c3cs60119f	journal	January 2013
Design of a containment apparatus for synchrotron XAS measurements of radioactive fluid samples under high temperatures and pressures Dhakal, Diwash; Mayanovic, Robert A.; Baker, Jason L. Review of Scientific Instruments, Vol. 90, Issue 8 https://doi.org/10.1063/1.5100887	journal	August 2019
Sulfur radical species form gold deposits on Earth Pokrovski, Gleb S.; Kokh, Maria A.; Guillaume, Damien Proceedings of the National Academy of Sciences, Vol. 112, Issue 44 https://doi.org/10.1073/pnas.1506378112	journal	October 2015
The trisulfur radical ion S ₃ ^•− controls platinum transport by hydrothermal fluids Pokrovski, Gleb S.; Kokh, Maria A.; Desmaele, Elsa Proceedings of the National Academy of Sciences, Vol. 118, Issue 34 https://doi.org/10.1073/pnas.2109768118	journal	August 2021
CRC Handbook of Chemistry and Physics Haynes, W. M.; Lide, David R.; Bruno, Thomas J. CRC press https://doi.org/10.1201/9781315380476	book	June 2016
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