Colloidal synthesis and charge carrier dynamics of Cs4Cd1-xCuxSb2Cl12 (0 ≤ x ≤ 1) layered double perovskite nanocrystals

Cai, Tong; Shi, Wenwu; Gosztola, David J.; Kobbekaduwa, Kanishka; Yang, Hanjun; Jin, Na; Nagaoka, Yasutaka; Dube, Lacie; Schneider, Jeremy; Hwang, Sooyeon; Gao, Jianbo; Ma, Xuedan; Chen, Ou

doi:10.1016/j.matt.2021.07.018

Title: Colloidal synthesis and charge carrier dynamics of Cs₄Cd_1-xCu_xSb₂Cl₁₂ (0 ≤ x ≤ 1) layered double perovskite nanocrystals

Journal Article · 31 August 2021 · Matter (Online)

DOI: https://doi.org/10.1016/j.matt.2021.07.018 · OSTI ID:1817202

^[1]; Shi, Wenwu ^[2];

^[3];

^[4]; Yang, Hanjun ^[1]; Jin, Na ^[1];

^[1]; Dube, Lacie ^[1];

^[1];

^[5]; Gao, Jianbo ^[4]; Ma, Xuedan ^[3];

^[1]

Brown Univ., Providence, RI (United States)
Brown Univ., Providence, RI (United States); Shenzhen Inst. of Information Technology (China)
Argonne National Lab. (ANL), Argonne, IL (United States)
Clemson Univ., SC (United States)
Brookhaven National Lab. (BNL), Upton, NY (United States)

The toxicity and instability of lead-based metal halide perovskites are the two main obstacles that prevent perovskite materials from implementation in applications. Recently, layered double perovskites (LDPs) emerge as a new family of perovskite materials which provide a new route to solve these problems by lead-component replacement and reduction of crystal structure dimensionality. However, LDP nanocrystals (NCs) have been rarely studied, limiting the further property exploration and application realization. In this work, we report the colloidal synthesis of a series of Cs₄Cd_1-xCu_xSb₂Cl₁₂ (0 ≤ x ≤ 1) LDP NCs by tuning the stoichiometry of metal precursors. The composition-structure-property relationships of the resulting LDP NCs are studied through materials characterizations, density functional theory calculations, and transient-absorption spectroscopy. In addition, we demonstrate that high-performance high-speed photodetectors can be fabricated using the colloidal LDP NCs through solution-processing. This work premises further expansion of such LDP-based materials for both fundamental studies and application integrations.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States); Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Organization:: Brown University; National Science Foundation (NSF); USDOE; USDOE Office of Science (SC); USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities Division

Grant/Contract Number:: AC02-06CH11357; SC0012704

OSTI ID:: 1817202

Report Number(s):: BNL--222044-2021-JAAM

Journal Information:: Matter (Online), Journal Name: Matter (Online) Journal Issue: 9 Vol. 4; ISSN 2590-2385

Publisher:: Cell Press/ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

References (73)

Prediction of Novel p -Type Transparent Conductors in Layered Double Perovskites: A First-Principles Study Xu, Jian; Liu, Jian-Bo; Wang, Jianfeng Advanced Functional Materials, Vol. 28, Issue 26 https://doi.org/10.1002/adfm.201800332	journal	April 2018
p‐Type Transparent Quadruple Perovskite Halide Conductors: Fact or Fiction? Hu, Sanlue; Xia, Bing; Lin, Yang‐Peng Advanced Functional Materials, Vol. 30, Issue 31 https://doi.org/10.1002/adfm.201909906	journal	June 2020
Response to Comment on “Prediction of Novel p‐Type Transparent Conductors in Layered Double Perovskites: A First‐Principles Study” Xu, Jian; Liu, Jian‐Bo; Wang, Jianfeng Advanced Functional Materials, Vol. 30, Issue 31 https://doi.org/10.1002/adfm.202003149	journal	June 2020
Quantum Dot Light-Emitting Diodes Based on Inorganic Perovskite Cesium Lead Halides (CsPbX ₃ ) Song, Jizhong; Li, Jianhai; Li, Xiaoming Advanced Materials, Vol. 27, Issue 44 https://doi.org/10.1002/adma.201502567	journal	October 2015
Rich Chemistry in Inorganic Halide Perovskite Nanostructures Huang, Jianmei; Lai, Minliang; Lin, Jia Advanced Materials, Vol. 30, Issue 48 https://doi.org/10.1002/adma.201802856	journal	September 2018
Structural and Functional Diversity in Lead‐Free Halide Perovskite Materials Ning, Weihua; Gao, Feng Advanced Materials, Vol. 31, Issue 22 https://doi.org/10.1002/adma.201900326	journal	April 2019
Efficient Luminescent Halide Quadruple‐Perovskite Nanocrystals via Trap‐Engineering for Highly Sensitive Photodetectors Bai, Tianxin; Yang, Bin; Chen, Junsheng Advanced Materials, Vol. 33, Issue 8 https://doi.org/10.1002/adma.202007215	journal	January 2021
Mn ²⁺ /Yb ³⁺ Codoped CsPbCl ₃ Perovskite Nanocrystals with Triple‐Wavelength Emission for Luminescent Solar Concentrators Cai, Tong; Wang, Junyu; Li, Wenhao Advanced Science, Vol. 7, Issue 18 https://doi.org/10.1002/advs.202001317	journal	July 2020
ELF: The Electron Localization Function Savin, Andreas; Nesper, Reinhard; Wengert, Steffen Angewandte Chemie International Edition in English, Vol. 36, Issue 17 https://doi.org/10.1002/anie.199718081	journal	September 1997
Lead-Free, Air-Stable All-Inorganic Cesium Bismuth Halide Perovskite Nanocrystals Yang, Bin; Chen, Junsheng; Hong, Feng Angewandte Chemie International Edition, Vol. 56, Issue 41 https://doi.org/10.1002/anie.201704739	journal	August 2017
Colloidal Synthesis and Charge-Carrier Dynamics of Cs 2 AgSb 1− y Bi y X 6 (X: Br, Cl; 0 ≤ y ≤1) Double Perovskite Nanocrystals Yang, Bin; Hong, Feng; Chen, Junsheng Angewandte Chemie International Edition, Vol. 58, Issue 8 https://doi.org/10.1002/anie.201811610	journal	January 2019
Lead‐Free Halide Perovskite Nanocrystals: Crystal Structures, Synthesis, Stabilities, and Optical Properties Fan, Qianqian; Biesold‐McGee, Gill V.; Ma, Jianzhong Angewandte Chemie International Edition, Vol. 59, Issue 3 https://doi.org/10.1002/anie.201904862	journal	January 2020
Bi ³⁺ ‐Er ³⁺ and Bi ³⁺ ‐Yb ³⁺ Codoped Cs ₂ AgInCl ₆ Double Perovskite Near‐Infrared Emitters Arfin, Habibul; Kaur, Jagjit; Sheikh, Tariq Angewandte Chemie International Edition, Vol. 59, Issue 28 https://doi.org/10.1002/anie.202002721	journal	March 2020
Stereoselective C−C Oxidative Coupling Reactions Photocatalyzed by Zwitterionic Ligand Capped CsPbBr ₃ Perovskite Quantum Dots Yuan, Yucheng; Zhu, Hua; Hills‐Kimball, Katie Angewandte Chemie International Edition, Vol. 59, Issue 50 https://doi.org/10.1002/anie.202007520	journal	October 2020
Low-Bandgap Cs ₄ CuSb ₂ Cl ₁₂ Layered Double Perovskite: Synthesis, Reversible Thermal Changes, and Magnetic Interaction Singhal, Nancy; Chakraborty, Rayan; Ghosh, Prasenjit Chemistry - An Asian Journal, Vol. 13, Issue 16 https://doi.org/10.1002/asia.201800635	journal	July 2018
Revealing the Bonding Pattern from the Molecular Electron Density Using Single Exponential Decay Detector: An Orbital-Free Alternative to the Electron Localization Function de Silva, Piotr; Korchowiec, Jacek; Wesolowski, Tomasz A. ChemPhysChem, Vol. 13, Issue 15 https://doi.org/10.1002/cphc.201200500	journal	July 2012
Optical Properties and Electronic Structure of Amorphous Germanium Tauc, J.; Grigorovici, R.; Vancu, A. physica status solidi (b), Vol. 15, Issue 2 https://doi.org/10.1002/pssb.19660150224	journal	January 1966
Identification and Quantification of Copper Sites in Zeolites by Electron Paramagnetic Resonance Spectroscopy Godiksen, Anita; Vennestrøm, Peter N. R.; Rasmussen, Søren B. Topics in Catalysis, Vol. 60, Issue 1-2 https://doi.org/10.1007/s11244-016-0731-7	journal	September 2016
Synthesis and transformation of zero-dimensional Cs3BiX6 (X = Cl, Br) perovskite-analogue nanocrystals Yang, Hanjun; Cai, Tong; Liu, Exian Nano Research, Vol. 13, Issue 1 https://doi.org/10.1007/s12274-019-2611-5	journal	December 2019
Cesium Titanium(IV) Bromide Thin Films Based Stable Lead-free Perovskite Solar Cells Chen, Min; Ju, Ming-Gang; Carl, Alexander D. Joule, Vol. 2, Issue 3 https://doi.org/10.1016/j.joule.2018.01.009	journal	March 2018
All-Inorganic Lead-Free Heterometallic Cs4MnBi2Cl12 Perovskite Single Crystal with Highly Efficient Orange Emission Wei, Jun-Hua; Liao, Jin-Feng; Wang, Xu-Dong Matter, Vol. 3, Issue 3 https://doi.org/10.1016/j.matt.2020.05.018	journal	September 2020
Charge-Carrier Dynamics of Lead-Free Halide Perovskite Nanocrystals Yang, Bin; Han, Keli Accounts of Chemical Research, Vol. 52, Issue 11 https://doi.org/10.1021/acs.accounts.9b00422	journal	October 2019
Cs ₄ Cd _{1– x} Mn _x Bi ₂ Cl ₁₂ —A Vacancy-Ordered Halide Perovskite Phosphor with High-Efficiency Orange-Red Emission Holzapfel, Noah P.; Majher, Jackson D.; Strom, T. Amanda Chemistry of Materials, Vol. 32, Issue 8 https://doi.org/10.1021/acs.chemmater.0c00454	journal	March 2020
Enhanced Luminescence and Mechanistic Studies on Layered Double-Perovskite Phosphors: Cs ₄ Cd _{1– x} Mn _x Bi ₂ Cl ₁₂ Vargas, Brenda; Reyes-Castillo, Diana T.; Coutino-Gonzalez, Eduardo Chemistry of Materials, Vol. 32, Issue 21 https://doi.org/10.1021/acs.chemmater.0c03167	journal	October 2020
Exploring the Stability of Mixed-Halide Vacancy-Ordered Quadruple Perovskites Gray, Matthew B.; Majher, Jackson D.; Holzapfel, Noah P. Chemistry of Materials, Vol. 33, Issue 6 https://doi.org/10.1021/acs.chemmater.0c04951	journal	March 2021
Optical, Electronic, and Magnetic Engineering of ⟨111⟩ Layered Halide Perovskites Vargas, Brenda; Torres-Cadena, Raúl; Rodríguez-Hernández, Joelis Chemistry of Materials, Vol. 30, Issue 15 https://doi.org/10.1021/acs.chemmater.8b02099	journal	July 2018
Cu(II)-Doped Cs ₂ SbAgCl ₆ Double Perovskite: A Lead-Free, Low-Bandgap Material Karmakar, Abhoy; Dodd, Mya S.; Agnihotri, Satyam Chemistry of Materials, Vol. 30, Issue 22 https://doi.org/10.1021/acs.chemmater.8b03755	journal	October 2018
Chemical Diversity in Lead-Free, Layered Double Perovskites: A Combined Experimental and Computational Approach Vargas, Brenda; Torres-Cadena, Raúl; Reyes-Castillo, Diana T. Chemistry of Materials, Vol. 32, Issue 1 https://doi.org/10.1021/acs.chemmater.9b04021	journal	November 2019
Metal Halide Perovskite Nanocrystals: Synthesis, Post-Synthesis Modifications, and Their Optical Properties Shamsi, Javad; Urban, Alexander S.; Imran, Muhammad Chemical Reviews, Vol. 119, Issue 5 https://doi.org/10.1021/acs.chemrev.8b00644	journal	February 2019
An Undergraduate Experiment To Explore Cu(II) Coordination Environment in Multihistidine Compounds through Electron Spin Resonance Spectroscopy Wagner, Eugene P.; Gronborg, Kai C.; Ghosh, Shreya Journal of Chemical Education, Vol. 96, Issue 8 https://doi.org/10.1021/acs.jchemed.9b00190	journal	June 2019
Lead-Free Small-Bandgap Cs ₂ CuSbCl ₆ Double Perovskite Nanocrystals Zhou, Wei; Han, Peigeng; Zhang, Xirui The Journal of Physical Chemistry Letters, Vol. 11, Issue 15 https://doi.org/10.1021/acs.jpclett.0c01968	journal	July 2020
Bandgap Engineering of Lead-Free Double Perovskite Cs ₂ AgInCl ₆ Nanocrystals via Cu ²⁺ -Doping Liao, Qiaohui; Chen, Jielin; Zhou, Liya The Journal of Physical Chemistry Letters, Vol. 11, Issue 19 https://doi.org/10.1021/acs.jpclett.0c02553	journal	September 2020
Efficient Emission in Halide Layered Double Perovskites: The Role of Sb ³⁺ Substitution in Cs ₄ Cd _{1– x} Mn _x Bi ₂ Cl ₁₂ Phosphors Vargas, Brenda; Coutiño-Gonzalez, Eduardo; Ovalle-Encinia, Oscar The Journal of Physical Chemistry Letters, Vol. 11, Issue 24 https://doi.org/10.1021/acs.jpclett.0c02912	journal	November 2020
Layered Halide Double Perovskites Cs _{3+ n} M(II) _n Sb ₂ X _{9+3 n} (M = Sn, Ge) for Photovoltaic Applications Tang, Gang; Xiao, Zewen; Hosono, Hideo The Journal of Physical Chemistry Letters, Vol. 9, Issue 1 https://doi.org/10.1021/acs.jpclett.7b02829	journal	December 2017
Synthesis of All-Inorganic Cd-Doped CsPbCl ₃ Perovskite Nanocrystals with Dual-Wavelength Emission Cai, Tong; Yang, Hanjun; Hills-Kimball, Katie The Journal of Physical Chemistry Letters, Vol. 9, Issue 24 https://doi.org/10.1021/acs.jpclett.8b03412	journal	December 2018
Material Design and Optoelectronic Properties of Three-Dimensional Quadruple Perovskite Halides Lin, Yang-Peng; Hu, Sanlue; Xia, Bing The Journal of Physical Chemistry Letters, Vol. 10, Issue 17 https://doi.org/10.1021/acs.jpclett.9b01757	journal	August 2019
Colloidal Nanocrystals of Lead-Free Double-Perovskite (Elpasolite) Semiconductors: Synthesis and Anion Exchange To Access New Materials Creutz, Sidney E.; Crites, Evan N.; De Siena, Michael C. Nano Letters, Vol. 18, Issue 2 https://doi.org/10.1021/acs.nanolett.7b04659	journal	January 2018
The Making and Breaking of Lead-Free Double Perovskite Nanocrystals of Cesium Silver–Bismuth Halide Compositions Bekenstein, Yehonadav; Dahl, Jakob C.; Huang, Jianmei Nano Letters, Vol. 18, Issue 6 https://doi.org/10.1021/acs.nanolett.8b00560	journal	May 2018
The Emergence of Halide Layered Double Perovskites Vargas, Brenda; Rodrı́guez-López, Germán; Solis-Ibarra, Diego ACS Energy Letters, Vol. 5, Issue 11 https://doi.org/10.1021/acsenergylett.0c01867	journal	October 2020
Toward Lead-Free Perovskite Solar Cells Giustino, Feliciano; Snaith, Henry J. ACS Energy Letters, Vol. 1, Issue 6 https://doi.org/10.1021/acsenergylett.6b00499	journal	November 2016
Doped Halide Perovskite Nanocrystals for Reabsorption-Free Luminescent Solar Concentrators Meinardi, Francesco; Akkerman, Quinten A.; Bruni, Francesco ACS Energy Letters, Vol. 2, Issue 10 https://doi.org/10.1021/acsenergylett.7b00701	journal	September 2017
Quantum-Dot-Induced Cesium-Rich Surface Imparts Enhanced Stability to Formamidinium Lead Iodide Perovskite Solar Cells Que, Meidan; Dai, Zhenghong; Yang, Hanjun ACS Energy Letters, Vol. 4, Issue 8 https://doi.org/10.1021/acsenergylett.9b01262	journal	July 2019
High Quantum Yield Blue Emission from Lead-Free Inorganic Antimony Halide Perovskite Colloidal Quantum Dots Zhang, Jian; Yang, Ying; Deng, Hui ACS Nano, Vol. 11, Issue 9 https://doi.org/10.1021/acsnano.7b04683	journal	September 2017
Efficient Light-Emitting Diodes Based on in Situ Fabricated FAPbBr ₃ Nanocrystals: The Enhancing Role of the Ligand-Assisted Reprecipitation Process Han, Dengbao; Imran, Muhammad; Zhang, Mengjiao ACS Nano, Vol. 12, Issue 8 https://doi.org/10.1021/acsnano.8b05172	journal	July 2018
Tutorial on Powder X-ray Diffraction for Characterizing Nanoscale Materials Holder, Cameron F.; Schaak, Raymond E. ACS Nano, Vol. 13, Issue 7 https://doi.org/10.1021/acsnano.9b05157	journal	July 2019
Lead-Free Cs ₄ CuSb ₂ Cl ₁₂ Layered Double Perovskite Nanocrystals Cai, Tong; Shi, Wenwu; Hwang, Sooyeon Journal of the American Chemical Society, Vol. 142, Issue 27 https://doi.org/10.1021/jacs.0c04919	journal	June 2020
A Bismuth-Halide Double Perovskite with Long Carrier Recombination Lifetime for Photovoltaic Applications Slavney, Adam H.; Hu, Te; Lindenberg, Aaron M. Journal of the American Chemical Society, Vol. 138, Issue 7 https://doi.org/10.1021/jacs.5b13294	journal	February 2016
A CsPbBr ₃ Perovskite Quantum Dot/Graphene Oxide Composite for Photocatalytic CO ₂ Reduction Xu, Yang-Fan; Yang, Mu-Zi; Chen, Bai-Xue Journal of the American Chemical Society, Vol. 139, Issue 16 https://doi.org/10.1021/jacs.7b00489	journal	April 2017
A Direct Bandgap Copper–Antimony Halide Perovskite Vargas, Brenda; Ramos, Estrella; Pérez-Gutiérrez, Enrique Journal of the American Chemical Society, Vol. 139, Issue 27 https://doi.org/10.1021/jacs.7b04119	journal	June 2017
Benzoyl Halides as Alternative Precursors for the Colloidal Synthesis of Lead-Based Halide Perovskite Nanocrystals Imran, Muhammad; Caligiuri, Vincenzo; Wang, Mengjiao Journal of the American Chemical Society, Vol. 140, Issue 7 https://doi.org/10.1021/jacs.7b13477	journal	January 2018
Lead-Free Direct Band Gap Double-Perovskite Nanocrystals with Bright Dual-Color Emission Yang, Bin; Mao, Xin; Hong, Feng Journal of the American Chemical Society, Vol. 140, Issue 49 https://doi.org/10.1021/jacs.8b07424	journal	November 2018
Colloidal Synthesis of Double Perovskite Cs ₂ AgInCl ₆ and Mn-Doped Cs ₂ AgInCl ₆ Nanocrystals Locardi, Federico; Cirignano, Matilde; Baranov, Dmitry Journal of the American Chemical Society, Vol. 140, Issue 40 https://doi.org/10.1021/jacs.8b07983	journal	September 2018
Optical Nonlinearities and Ultrafast Carrier Dynamics in Semiconductor Nanocrystals Klimov, Victor I. The Journal of Physical Chemistry B, Vol. 104, Issue 26 https://doi.org/10.1021/jp9944132	journal	July 2000
Low-threshold amplified spontaneous emission and lasing from colloidal nanocrystals of caesium lead halide perovskites Yakunin, Sergii; Protesescu, Loredana; Krieg, Franziska Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms9056	journal	August 2015
Color-stable highly luminescent sky-blue perovskite light-emitting diodes Xing, Jun; Zhao, Yongbiao; Askerka, Mikhail Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-05909-8	journal	August 2018
Prediction of room-temperature half-metallicity in layered halide double perovskites Xu, Jian; Xu, Changsong; Liu, Jian-Bo npj Computational Materials, Vol. 5, Issue 1 https://doi.org/10.1038/s41524-019-0252-6	journal	November 2019
All-inorganic perovskite nanocrystal scintillators Chen, Qiushui; Wu, Jing; Ou, Xiangyu Nature, Vol. 561, Issue 7721 https://doi.org/10.1038/s41586-018-0451-1	journal	August 2018
The top-down synthesis of single-layered Cs ₄ CuSb ₂ Cl ₁₂ halide perovskite nanocrystals for photoelectrochemical application Wang, Xu-Dong; Miao, Nai-Hua; Liao, Jin-Feng Nanoscale, Vol. 11, Issue 12 https://doi.org/10.1039/C9NR00375D	journal	January 2019
Quantum-cutting Yb ³⁺ -doped perovskite nanocrystals for monolithic bilayer luminescent solar concentrators Cohen, Theodore A.; Milstein, Tyler J.; Kroupa, Daniel M. Journal of Materials Chemistry A, Vol. 7, Issue 15 https://doi.org/10.1039/C9TA01261C	journal	January 2019
Synthesis of lead-free Cs ₄ (Cd _1−x Mn _x )Bi ₂ Cl ₁₂ (0 ≤ x ≤ 1) layered double perovskite nanocrystals with controlled Mn–Mn coupling interaction Yang, Hanjun; Shi, Wenwu; Cai, Tong Nanoscale, Vol. 12, Issue 45 https://doi.org/10.1039/D0NR06771G	journal	January 2020
Hybrid functionals based on a screened Coulomb potential Heyd, Jochen; Scuseria, Gustavo E.; Ernzerhof, Matthias The Journal of Chemical Physics, Vol. 118, Issue 18 https://doi.org/10.1063/1.1564060	journal	May 2003
A simple measure of electron localization in atomic and molecular systems Becke, A. D.; Edgecombe, K. E. The Journal of Chemical Physics, Vol. 92, Issue 9 https://doi.org/10.1063/1.458517	journal	May 1990
The effects of monovalent metal cations on the crystal and electronic structures of Cs ₂ MBiCl ₆ (M = Ag, Cu, Na, K, Rb, and Cs) perovskites Shi, Wenwu; Cai, Tong; Wang, Zhiguo The Journal of Chemical Physics, Vol. 153, Issue 14 https://doi.org/10.1063/5.0021238	journal	October 2020
High-throughput first-principles screening of layered magnetic double perovskites Cs ₄ MSb ₂ X ₁₂ for spintronic applications Han, Dan; Zhang, Tao; Chen, Shiyou Journal of Physics: Condensed Matter, Vol. 32, Issue 22 https://doi.org/10.1088/1361-648X/ab7576	journal	March 2020
Spinon excitations in the quasi-one-dimensional S = 1 2 chain compound C s 4 CuS b 2 C l 12 Tran, Thao T.; Pocs, Chris A.; Zhang, Yubo Physical Review B, Vol. 101, Issue 23 https://doi.org/10.1103/PhysRevB.101.235107	journal	June 2020
Projector augmented-wave method Blöchl, P. E. Physical Review B, Vol. 50, Issue 24, p. 17953-17979 https://doi.org/10.1103/PhysRevB.50.17953	journal	December 1994
Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set Kresse, G.; Furthmüller, J. Physical Review B, Vol. 54, Issue 16, p. 11169-11186 https://doi.org/10.1103/PhysRevB.54.11169	journal	October 1996
From ultrasoft pseudopotentials to the projector augmented-wave method Kresse, G.; Joubert, D. Physical Review B, Vol. 59, Issue 3, p. 1758-1775 https://doi.org/10.1103/PhysRevB.59.1758	journal	January 1999
First-principles study of electronic and structural properties of CuO Himmetoglu, Burak; Wentzcovitch, Renata M.; Cococcioni, Matteo Physical Review B, Vol. 84, Issue 11 https://doi.org/10.1103/PhysRevB.84.115108	journal	September 2011
Band structure and phase stability of the copper oxides Cu 2 O, CuO, and Cu 4 O 3 Heinemann, Markus; Eifert, Bianca; Heiliger, Christian Physical Review B, Vol. 87, Issue 11 https://doi.org/10.1103/PhysRevB.87.115111	journal	March 2013
Generalized Gradient Approximation Made Simple Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868 https://doi.org/10.1103/PhysRevLett.77.3865	journal	October 1996
Quantum dot-induced phase stabilization of -CsPbI3 perovskite for high-efficiency photovoltaics Swarnkar, A.; Marshall, A. R.; Sanehira, E. M. Science, Vol. 354, Issue 6308 https://doi.org/10.1126/science.aag2700	journal	October 2016
Properties and potential optoelectronic applications of lead halide perovskite nanocrystals Kovalenko, Maksym V.; Protesescu, Loredana; Bodnarchuk, Maryna I. Science, Vol. 358, Issue 6364 https://doi.org/10.1126/science.aam7093	journal	November 2017

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Title: Colloidal synthesis and charge carrier dynamics of Cs4Cd1-xCuxSb2Cl12 (0 ≤ x ≤ 1) layered double perovskite nanocrystals

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Title: Colloidal synthesis and charge carrier dynamics of Cs₄Cd_1-xCu_xSb₂Cl₁₂ (0 ≤ x ≤ 1) layered double perovskite nanocrystals