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Title: Intrinsic volumetric negative thermal expansion in the “rigid” calcium squarate

Journal Article · · ChemComm
DOI: https://doi.org/10.1039/D1CC03105H · OSTI ID:1814657
ORCiD logo [1];  [1]; ORCiD logo [1]; ORCiD logo [2]
  1. School of Materials Science and Engineering, China University of Petroleum (East China), Qingdao, Shandong, 266580, China
  2. Beijing Advanced Innovation Center for Materials Genome Engineering, Institute of Solid State Chemistry, University of Science and Technology Beijing, Beijing, 100083, China

A strong volumetric negative thermal expansion was found to exist in a rigid MOF without carboxylate like buffering units.

Sponsoring Organization:
USDOE
Grant/Contract Number:
NONE; AC02-06CH11357
OSTI ID:
1814657
Journal Information:
ChemComm, Journal Name: ChemComm Journal Issue: 74 Vol. 57; ISSN CHCOFS; ISSN 1359-7345
Publisher:
Royal Society of Chemistry (RSC)Copyright Statement
Country of Publication:
United Kingdom
Language:
English

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