Viscoelasticity in associating oligomers and polymers: experimental test of the bond lifetime renormalization model

Ge, Sirui; Tress, Martin; Xing, Kunyue; Cao, Peng-Fei; Saito, Tomonori; Sokolov, Alexei P.

doi:10.1039/c9sm01930h

Title: Viscoelasticity in associating oligomers and polymers: experimental test of the bond lifetime renormalization model

Journal Article · 15 December 2019 · Soft Matter

DOI: https://doi.org/10.1039/c9sm01930h · OSTI ID:1813271

Ge, Sirui ^[1];

^[1]; Xing, Kunyue ^[1];

^[2];

^[3]

Univ. of Tennessee, Knoxville, TN (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Univ. of Tennessee, Knoxville, TN (United States); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Recent findings that the association bond lifetimes τ_α* in associating polymers diverge from their supramolecular network relaxation times τ_c challenge past theories. The bond lifetime renormalization proposed by Rubinstein and coworkers [Stukalin et al., Macromolecules, 2013, 46, 7525] provides a promising explanation. To examine systematically its applicability, we employ shear rheology and dielectric spectroscopy to study telechelic associating polymers with different main chain (polypropylene glycol and polydimethylsiloxane), molecular weight (below entanglement molecular weight) and end groups (amide, and carboxylic acid) which form dimeric associations by hydrogen bonding. The separation between τ_c (probed by rheology) and τ_α* (probed by dielectric spectroscopy) strongly increases with chain length as qualitatively predicted by the model. However, to describe the increase quantitatively, a transition from Rouse to reptation dynamics must be assumed. This suggests that dynamics of super-chains must be considered to properly describe the transient network.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1813271

Journal Information:: Soft Matter, Journal Name: Soft Matter Journal Issue: 2 Vol. 16; ISSN 1744-683X

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

References (55)

Superstretchable, Self-Healing Polymeric Elastomers with Tunable Properties Cao, Peng-Fei; Li, Bingrui; Hong, Tao Advanced Functional Materials, Vol. 28, Issue 22 https://doi.org/10.1002/adfm.201800741	journal	April 2018
Shape-Memory Effects in Polymer Networks Containing Reversibly Associating Side-Groups Li, J.; Viveros, J. A.; Wrue, M. H. Advanced Materials, Vol. 19, Issue 19 https://doi.org/10.1002/adma.200602260	journal	October 2007
A correlation between critical end-to-end distance for entanglements and molecular chain diameter of polymers Zang, Yong-Hua; Carreau, Pierre J. Journal of Applied Polymer Science, Vol. 42, Issue 7 https://doi.org/10.1002/app.1991.070420721	journal	April 1991
Easy Access to the Characteristic Ratio of Polymers Using Ion-Mobility Mass Spectrometry Kokubo, Shinsuke; Vana, Philipp Macromolecular Chemistry and Physics, Vol. 218, Issue 1 https://doi.org/10.1002/macp.201600373	journal	October 2016
Self-Healing in Supramolecular Polymers Campanella, Antonella; Döhler, Diana; Binder, Wolfgang H. Macromolecular Rapid Communications, Vol. 39, Issue 17 https://doi.org/10.1002/marc.201700739	journal	January 2018
Network Formation and Mechanical Properties of Telechelic Associating Polymers with Fixed Junction Multiplicity Ozaki, Hiroto; Koga, Tsuyoshi Macromolecular Theory and Simulations, Vol. 26, Issue 2 https://doi.org/10.1002/mats.201600076	journal	November 2016
Structural and rheological properties of hydrophobically modified alkali-soluble emulsion solutions Knaebel, A.; Skouri, R.; Munch, J. P. Journal of Polymer Science Part B: Polymer Physics, Vol. 40, Issue 18 https://doi.org/10.1002/polb.10249	journal	August 2002
Comment on the dynamic bead size and Kuhn segment length in polymers: Example of polystyrene Ding, Y.; Sokolov, A. P. Journal of Polymer Science Part B: Polymer Physics, Vol. 42, Issue 18 https://doi.org/10.1002/polb.20235	journal	January 2004
The molecular dynamics of thermoreversible networks as studied by broadband dielectric spectroscopy M�ller, M.; Fischer, E. W.; Kremer, F. Colloid & Polymer Science, Vol. 273, Issue 1 https://doi.org/10.1007/BF00655672	journal	January 1995
A complex plane representation of dielectric and mechanical relaxation processes in some polymers Havriliak, S.; Negami, S. Polymer, Vol. 8 https://doi.org/10.1016/0032-3861(67)90021-3	journal	January 1967
Viscoelastic properties of physically crosslinked networks Tanaka, F.; Edwards, S. F. Journal of Non-Newtonian Fluid Mechanics, Vol. 43, Issue 2-3 https://doi.org/10.1016/0377-0257(92)80027-U	journal	July 1992
Analysis of complex dielectric spectra. I. One-dimensional derivative techniques and three-dimensional modelling Wübbenhorst, Michael; van Turnhout, Jan Journal of Non-Crystalline Solids, Vol. 305, Issue 1-3 https://doi.org/10.1016/S0022-3093(02)01086-4	journal	July 2002
Rheological properties of hydrophobic ethoxylated urethane (HEUR) in the presence of methylated β-cyclodextrin Liao, Dongsheng; Dai, Sheng; Tam, Kam Chiu Polymer, Vol. 45, Issue 25 https://doi.org/10.1016/j.polymer.2004.10.016	journal	November 2004
Synthesis of linear polyglycerols with tailored degree of methylation by copolymerization and the effect on thermorheological behavior Schubert, Christian; Dreier, Philip; Nguyen, Thong Polymer, Vol. 121 https://doi.org/10.1016/j.polymer.2017.05.030	journal	July 2017
Vibrational study of anharmonicity, supramolecular structure, and hydrogen bonding in two octanol isomers Bauer, S.; Stern, J.; Böhm, F. Vibrational Spectroscopy, Vol. 79 https://doi.org/10.1016/j.vibspec.2015.05.001	journal	July 2015
How Supramolecular Assemblies Control Dynamics of Associative Polymers: Toward a General Picture Goldansaz, Hadi; Fustin, Charles-André; Wübbenhorst, Michael Macromolecules, Vol. 49, Issue 5 https://doi.org/10.1021/acs.macromol.5b01535	journal	February 2016
Field-Cycling Relaxometry as a Molecular Rheology Technique: Common Analysis of NMR, Shear Modulus and Dielectric Loss Data of Polymers vs Dendrimers Hofmann, M.; Gainaru, C.; Cetinkaya, B. Macromolecules, Vol. 48, Issue 20 https://doi.org/10.1021/acs.macromol.5b01805	journal	October 2015
Star Telechelic Poly( l -lactide) Ionomers Kulkarni, Amruta; Lele, Ashish; Sivaram, Swaminathan Macromolecules, Vol. 48, Issue 18 https://doi.org/10.1021/acs.macromol.5b01854	journal	September 2015
Association Behavior, Diffusion, and Viscosity of End-Functionalized Supramolecular Poly(ethylene glycol) in the Melt State Krutyeva, M.; Brás, A. R.; Antonius, W. Macromolecules, Vol. 48, Issue 24 https://doi.org/10.1021/acs.macromol.5b02060	journal	November 2015
Linear Viscoelastic and Dielectric Relaxation Response of Unentangled UPy-Based Supramolecular Networks Shabbir, Aamir; Javakhishvili, Irakli; Cerveny, Silvina Macromolecules, Vol. 49, Issue 10 https://doi.org/10.1021/acs.macromol.6b00122	journal	May 2016
Impact of Hydrogen Bonding on Dynamics of Hydroxyl-Terminated Polydimethylsiloxane Xing, Kunyue; Chatterjee, Sabornie; Saito, Tomonori Macromolecules, Vol. 49, Issue 8 https://doi.org/10.1021/acs.macromol.6b00262	journal	April 2016
Relaxation Processes in Supramolecular Metallogels Based on Histidine–Nickel Coordination Bonds Tang, Shengchang; Olsen, Bradley D. Macromolecules, Vol. 49, Issue 23 https://doi.org/10.1021/acs.macromol.6b01618	journal	November 2016
The Role of Chain-End Association Lifetime in Segmental and Chain Dynamics of Telechelic Polymers Xing, Kunyue; Tress, Martin; Cao, Peng-Fei Macromolecules, Vol. 51, Issue 21 https://doi.org/10.1021/acs.macromol.8b01210	journal	October 2018
Importance of Compact Random Walks for the Rheology of Transient Networks Gold, B. J.; Hövelmann, C. H.; Lühmann, N. ACS Macro Letters, Vol. 6, Issue 2 https://doi.org/10.1021/acsmacrolett.6b00880	journal	January 2017
Supramolecular Polymers Brunsveld, L.; Folmer, B. J. B.; Meijer, E. W. Chemical Reviews, Vol. 101, Issue 12 https://doi.org/10.1021/cr990125q	journal	December 2001
Equilibrium and Non-Equilibrium Type β-Relaxations: d -Sorbitol versus o -Terphenyl Wagner, Hermann; Richert, Ranko The Journal of Physical Chemistry B, Vol. 103, Issue 20 https://doi.org/10.1021/jp9838947	journal	May 1999
Viscoelastic properties of physically crosslinked networks. 1. Transient network theory Tanaka, F.; Edwards, S. F. Macromolecules, Vol. 25, Issue 5 https://doi.org/10.1021/ma00031a024	journal	September 1992
Model Transient Networks from Strongly Hydrogen-Bonded Polymers Feldman, Kathleen E.; Kade, Matthew J.; Meijer, E. W. Macromolecules, Vol. 43, Issue 7 https://doi.org/10.1021/ma1004327	journal	March 2010
Aggregation and Chain Dynamics in Supramolecular Polymers by Dynamic Rheology: Cluster Formation and Self-Aggregation Herbst, Florian; Schröter, Klaus; Gunkel, Ilja Macromolecules, Vol. 43, Issue 23 https://doi.org/10.1021/ma101962y	journal	December 2010
Model Transient Networks from Strongly Hydrogen-Bonded Polymers Feldman, Kathleen E.; Kade, Matthew J.; Meijer, E. W. Macromolecules, Vol. 44, Issue 13 https://doi.org/10.1021/ma201245h	journal	June 2011
Self-Healing of Unentangled Polymer Networks with Reversible Bonds Stukalin, Evgeny B.; Cai, Li-Heng; Kumar, N. Arun Macromolecules, Vol. 46, Issue 18 https://doi.org/10.1021/ma401111n	journal	September 2013
Viscoelasticity of Reversible Gelation for Ionomers Chen, Quan; Huang, Chongwen; Weiss, R. A. Macromolecules, Vol. 48, Issue 4 https://doi.org/10.1021/ma502280g	journal	January 2015
Model Transient Networks from Strongly Hydrogen-Bonded Polymers Feldman, Kathleen E.; Kade, Matthew J.; Meijer, E. W. Macromolecules, Vol. 42, Issue 22 https://doi.org/10.1021/ma901668w	journal	November 2009
Dynamics of Linear and Star Poly(oxypropylene) Studied by Dielectric Spectroscopy and Rheology Nicolai, Taco; Floudas, George Macromolecules, Vol. 31, Issue 8 https://doi.org/10.1021/ma9714068	journal	April 1998
Dynamics of Poly(propylene sulfide) Studied by Dynamic Mechanical Measurements and Dielectric Spectroscopy Nicol, Erwan; Nicolai, Taco; Durand, Dominique Macromolecules, Vol. 32, Issue 22 https://doi.org/10.1021/ma990853f	journal	November 1999
Self-healing and thermoreversible rubber from supramolecular assembly Cordier, Philippe; Tournilhac, François; Soulié-Ziakovic, Corinne Nature, Vol. 451, Issue 7181, p. 977-980 https://doi.org/10.1038/nature06669	journal	February 2008
Hydrogen-bond strength changes network dynamics in associating telechelic PDMS Xing, Kunyue; Tress, Martin; Cao, Pengfei Soft Matter, Vol. 14, Issue 7 https://doi.org/10.1039/C7SM01805C	journal	January 2018
Advanced supramolecular polymers constructed by orthogonal self-assembly Li, Shao-Lu; Xiao, Tangxin; Lin, Chen Chemical Society Reviews, Vol. 41, Issue 18 https://doi.org/10.1039/c2cs35099h	journal	January 2012
Design and properties of supramolecular polymer gels Noro, Atsushi; Hayashi, Mikihiro; Matsushita, Yushu Soft Matter, Vol. 8, Issue 24 https://doi.org/10.1039/c2sm25144b	journal	January 2012
Self-reinforced polyethylene blend for artificial joint application Huang, Yan-Fei; Xu, Jia-Zhuang; Xu, Jun-Yi Journal of Materials Chemistry B, Vol. 2, Issue 8 https://doi.org/10.1039/c3tb21231a	journal	January 2014
Rheological study of transient networks with junctions of limited multiplicity Indei, Tsutomu The Journal of Chemical Physics, Vol. 127, Issue 14 https://doi.org/10.1063/1.2747607	journal	October 2007
Rheological study of transient networks with junctions of limited multiplicity. II. Sol/gel transition and rheology Indei, Tsutomu The Journal of Chemical Physics, Vol. 127, Issue 14 https://doi.org/10.1063/1.2747610	journal	October 2007
Structure of Model Telechelic Polymer Melts by Computer Simulation Manassero, Carlo; Raos, Guido; Allegra, Giuseppe Journal of Macromolecular Science, Part B, Vol. 44, Issue 6 https://doi.org/10.1080/00222340500364759	journal	November 2005
Telechelic Melt Polymer's Structure Variation Depending on Shear Deformation Manassero, Carlo; Castellano, Carlo Journal of Macromolecular Science, Part B, Vol. 52, Issue 10 https://doi.org/10.1080/00222348.2013.771019	journal	January 2013
Molecular View on Supramolecular Chain and Association Dynamics Monkenbusch, M.; Krutyeva, M.; Pyckhout-Hintzen, W. Physical Review Letters, Vol. 117, Issue 14 https://doi.org/10.1103/PhysRevLett.117.147802	journal	September 2016
Rheology of telechelic associative polymers in aqueous solutions Meng, Xiao-Xia; Russel, William B. Journal of Rheology, Vol. 50, Issue 2 https://doi.org/10.1122/1.2167467	journal	March 2006
Ionomer dynamics and the sticky Rouse model Chen, Quan; Tudryn, Gregory J.; Colby, Ralph H. Journal of Rheology, Vol. 57, Issue 5 https://doi.org/10.1122/1.4818868	journal	September 2013
Viscoelasticity of entangled random polystyrene ionomers Chen, Quan; Zhang, Zhijie; Colby, Ralph H. Journal of Rheology, Vol. 60, Issue 6 https://doi.org/10.1122/1.4955432	journal	November 2016
Association energy in strongly associative polymers Zhang, Zhijie; Huang, Chongwen; Weiss, R. A. Journal of Rheology, Vol. 61, Issue 6 https://doi.org/10.1122/1.4997586	journal	November 2017
A new stochastic simulation for the rheology of telechelic associating polymers Park, Gun Woo; Ianniruberto, Giovanni Journal of Rheology, Vol. 61, Issue 6 https://doi.org/10.1122/1.4997592	journal	November 2017
Decoding the linear viscoelastic properties of model telechelic metallo-supramolecular polymers Zhuge, Flanco; Hawke, Laurence G. D.; Fustin, Charles-Andre Journal of Rheology, Vol. 61, Issue 6 https://doi.org/10.1122/1.4997593	journal	November 2017
The microscopic origin of the rheology in supramolecular entangled polymer networks Gold, B. J.; Hövelmann, C. H.; Lühmann, N. Journal of Rheology, Vol. 61, Issue 6 https://doi.org/10.1122/1.4998159	journal	November 2017
Lifetime and network relaxation time of a HEUR-C20 associative polymer system Ng, W. K.; Tam, K. C.; Jenkins, R. D. Journal of Rheology, Vol. 44, Issue 1 https://doi.org/10.1122/1.551078	journal	January 2000
Mechanically robust, readily repairable polymers via tailored noncovalent cross-linking Yanagisawa, Yu; Nan, Yiling; Okuro, Kou Science, Vol. 359, Issue 6371 https://doi.org/10.1126/science.aam7588	journal	December 2017
Rheological Study of Transient Networks with Junctions of Limited Multiplicity II. Sol/Gel Transition and Rheology Indei, Tsutomu arXiv https://doi.org/10.48550/arxiv.cond-mat/0612449	text	January 2006

Similar Records

The Role of Chain-End Association Lifetime in Segmental and Chain Dynamics of Telechelic Polymers

Journal Article · 2018 · Macromolecules · OSTI ID:1493982

Xing, Kunyue; Tress, Martin; Cao, Peng-Fei; +4 more

Impact of hydrogen bonding on dynamics of hydroxyl-terminated polydimethylsiloxane

Journal Article · 2016 · Macromolecules · OSTI ID:1342694

Xing, Kunyue; Chatterjee, Sabornie; Saito, Tomonori; +2 more

Effect of Diphenyl Content on Viscoelasticity of Poly(dimethyl-co-diphenyl)siloxane Melt and Network

Journal Article · 2023 · ACS Applied Polymer Materials · OSTI ID:2007293

Xian, Weikang; Liu, Chung-Hao; Kangarlou, Behrad; +9 more

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Title: Viscoelasticity in associating oligomers and polymers: experimental test of the bond lifetime renormalization model

Citation Formats

References (55)

Similar Records

Related Subjects