Photoluminescence of Pentavalent Uranyl Amide Complexes

Ortu, Fabrizio; Randall, Simon; Moulding, David J.; Woodward, Adam W.; Kerridge, Andrew; Meyer, Karsten; La Pierre, Henry S.; Natrajan, Louise S.

doi:10.1021/jacs.1c05184

Title: Photoluminescence of Pentavalent Uranyl Amide Complexes

Journal Article · 12 August 2021 · Journal of the American Chemical Society

DOI: https://doi.org/10.1021/jacs.1c05184 · OSTI ID:1813077

^[1]; Randall, Simon ^[2]; Moulding, David J. ^[2]; Woodward, Adam W. ^[3];

^[4];

^[5];

^[6];

^[3]

Centre for Radiochemistry Resesarch, Department of Chemistry, School of Natural Sciences, The University of Manchester, Oxford Road, Manchester M13 9PL, U.K., School of Chemistry, University of Leicester, University Road, Leicester LE1 7RH, U.K.
Centre for Radiochemistry Resesarch, Department of Chemistry, School of Natural Sciences, The University of Manchester, Oxford Road, Manchester M13 9PL, U.K.
Centre for Radiochemistry Resesarch, Department of Chemistry, School of Natural Sciences, The University of Manchester, Oxford Road, Manchester M13 9PL, U.K., Photon Science Institute, The University of Manchester, Oxford Road, Manchester M13 9PL, U.K.
Department of Chemistry, Lancaster University, Lancaster LA1 4YB, U.K.
Friedrich-Alexander-University Erlangen-Nürnberg (FAU), Department of Chemistry and Pharmacy, Inorganic Chemistry, Egerlandstr. 1, 91058 Erlangen, Germany
Friedrich-Alexander-University Erlangen-Nürnberg (FAU), Department of Chemistry and Pharmacy, Inorganic Chemistry, Egerlandstr. 1, 91058 Erlangen, Germany, School of Chemistry and Biochemistry, Georgia Institute of Technology, Atlanta, Georgia 30332-0400, United States, Nuclear and Radiological Engineering and Medical Physics Program, School of Mechanical Engineering, Georgia Institute of Technology, Atlanta, Georgia 30332-0400, United States

Not Available

View Journal Article

Cite

Export

Save

Research Organization:: Univ. of Manchester (United Kingdom)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0019385

OSTI ID:: 1813077

Journal Information:: Journal of the American Chemical Society, Journal Name: Journal of the American Chemical Society Journal Issue: 33 Vol. 143; ISSN 0002-7863

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

References (78)

Cation-Cation Interactions, Magnetic Communication, and Reactivity of the Pentavalent Uranium Ion [U(N t Bu) ₂ ] ⁺ Spencer, Liam P.; Schelter, Eric J.; Yang, Ping Angewandte Chemie, Vol. 121, Issue 21 https://doi.org/10.1002/ange.200806190	journal	May 2009
Isolation of a Uranyl [UO2] Species: Crystallographic Comparison of the Dioxouranium(V) and (VI) Compounds [UO2(OPPh3)4](OTf)n (n=1, 2) Berthet, Jean-Claude; Nierlich, Martine; Ephritikhine, Michel Angewandte Chemie International Edition, Vol. 42, Issue 17 https://doi.org/10.1002/anie.200250506	journal	April 2003
The Renaissance of Non-Aqueous Uranium Chemistry Liddle, Stephen T. Angewandte Chemie International Edition, Vol. 54, Issue 30 https://doi.org/10.1002/anie.201412168	journal	June 2015
Synthesis and Characterization of Water Stable Uranyl(V) Complexes Faizova, Radmila; Fadaei‐Tirani, Farzaneh; Chauvin, Anne‐Sophie Angewandte Chemie International Edition, Vol. 60, Issue 15 https://doi.org/10.1002/anie.202016123	journal	March 2021
Cation-Cation Complexes of Pentavalent Uranyl: From Disproportionation Intermediates to Stable Clusters Mougel, Victor; Horeglad, Pawel; Nocton, Grégory Chemistry - A European Journal, Vol. 16, Issue 48 https://doi.org/10.1002/chem.201001929	journal	November 2010
Stabilization of uranium(IV) in heteropoly anions* Termes, Silvia C.; Pope, Michael T. Transition Metal Chemistry, Vol. 3, Issue 1 https://doi.org/10.1007/BF01393519	journal	December 1978
Spectroscopic properties and electronic structure of uranyl complex compounds (Review) Syt’ko, V. V.; Umreiko, D. S. Journal of Applied Spectroscopy, Vol. 65, Issue 6 https://doi.org/10.1007/BF02675741	journal	November 1998
Auxiliary basis sets for main row atoms and transition metals and their use to approximate Coulomb potentials Eichkorn, Karin; Weigend, Florian; Treutler, Oliver Theoretical Chemistry Accounts: Theory, Computation, and Modeling (Theoretica Chimica Acta), Vol. 97, Issue 1-4 https://doi.org/10.1007/s002140050244	journal	October 1997
Density functional theory investigation of nonsymmetrically substituted uranyl–salophen complexes Li, Xiao-Long; Luo, Juan; Lin, Ying-Wu Journal of Radioanalytical and Nuclear Chemistry, Vol. 307, Issue 1 https://doi.org/10.1007/s10967-015-4326-8	journal	July 2015
The preparation and spectrum of uranium(V) ions in aqueous solutions Cohen, Donald Journal of Inorganic and Nuclear Chemistry, Vol. 32, Issue 11 https://doi.org/10.1016/0022-1902(70)80160-9	journal	November 1970
Pentavalent uranyl complexes Arnold, Polly L.; Love, Jason B.; Patel, Dipti Coordination Chemistry Reviews, Vol. 253, Issue 15-16 https://doi.org/10.1016/j.ccr.2009.03.014	journal	August 2009
Oxo ligand functionalization in the uranyl ion (UO22+) Fortier, Skye; Hayton, Trevor W. Coordination Chemistry Reviews, Vol. 254, Issue 3-4 https://doi.org/10.1016/j.ccr.2009.06.003	journal	February 2010
Developments in the photophysics and photochemistry of actinide ions and their coordination compounds Natrajan, Louise S. Coordination Chemistry Reviews, Vol. 256, Issue 15-16 https://doi.org/10.1016/j.ccr.2012.03.029	journal	August 2012
Redox and environmentally relevant aspects of actinide(IV) coordination chemistry Natrajan, Louise S.; Swinburne, Adam N.; Andrews, Michael B. Coordination Chemistry Reviews, Vol. 266-267 https://doi.org/10.1016/j.ccr.2013.12.021	journal	May 2014
Luminescence spectrum of uranyl(V) in 2-propanol perchlorate solution Steudtner, Robin; Arnold, Thuro; Großmann, Kay Inorganic Chemistry Communications, Vol. 9, Issue 9 https://doi.org/10.1016/j.inoche.2006.06.001	journal	September 2006
Fluorescence properties of a uranyl(V)-carbonate species [U(V)O2(CO3)3]5− at low temperature Grossmann, Kay; Arnold, Thuro; Ikeda-Ohno, Atsushi Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, Vol. 72, Issue 2 https://doi.org/10.1016/j.saa.2008.10.041	journal	March 2009
Segmented contraction scheme for small-core actinide pseudopotential basis sets Cao, Xiaoyan; Dolg, Michael Journal of Molecular Structure: THEOCHEM, Vol. 673, Issue 1-3 https://doi.org/10.1016/j.theochem.2003.12.015	journal	March 2004
Iron Vacancies Accommodate Uranyl Incorporation into Hematite McBriarty, Martin E.; Kerisit, Sebastien; Bylaska, Eric J. Environmental Science & Technology, Vol. 52, Issue 11 https://doi.org/10.1021/acs.est.8b00297	journal	May 2018
Multiple Lines of Evidence Identify U(V) as a Key Intermediate during U(VI) Reduction by Shewanella oneidensis MR1 Vettese, Gianni F.; Morris, Katherine; Natrajan, Louise S. Environmental Science & Technology, Vol. 54, Issue 4 https://doi.org/10.1021/acs.est.9b05285	journal	January 2020
Uranium(V) Incorporation Mechanisms and Stability in Fe(II)/Fe(III) (oxyhydr)Oxides Roberts, Hannah E.; Morris, Katherine; Law, Gareth T. W. Environmental Science & Technology Letters, Vol. 4, Issue 10 https://doi.org/10.1021/acs.estlett.7b00348	journal	September 2017
Physicochemical Properties of Near-Linear Lanthanide(II) Bis(silylamide) Complexes (Ln = Sm, Eu, Tm, Yb) Goodwin, Conrad A. P.; Chilton, Nicholas F.; Vettese, Gianni F. Inorganic Chemistry, Vol. 55, Issue 20 https://doi.org/10.1021/acs.inorgchem.6b00808	journal	May 2016
Uranyl-tri- bis (silyl)amide Alkali Metal Contact and Separated Ion Pair Complexes Cobb, Philip J.; Moulding, David J.; Ortu, Fabrizio Inorganic Chemistry, Vol. 57, Issue 11 https://doi.org/10.1021/acs.inorgchem.8b00715	journal	May 2018
Magnetic Susceptibility of Uranium Complexes Kindra, Douglas R.; Evans, William J. Chemical Reviews, Vol. 114, Issue 18 https://doi.org/10.1021/cr500242w	journal	August 2014
Chemistry of uranium (V) Selbin, Joel; Ortego, J. D. Chemical Reviews, Vol. 69, Issue 5 https://doi.org/10.1021/cr60261a004	journal	October 1969
Synthesis and x-ray crystal structure of the divalent [bis(trimethylsilyl)amido] samarium complexes [(Me3Si)2N]2Sm(THF)2 and {[(Me3Si)2N]Sm(.mu.-I)(DME)(THF)}2 Evans, William J.; Drummond, Donald K.; Zhang, Hongming Inorganic Chemistry, Vol. 27, Issue 3 https://doi.org/10.1021/ic00276a027	journal	February 1988
Electronic Spectra of Pure Uranyl(V) Complexes: Characteristic Absorption Bands Due to a U ^V O ₂ ⁺ Core in Visible and Near-Infrared Regions ¹ Mizuoka, Koichiro; Tsushima, Satoru; Hasegawa, Miki Inorganic Chemistry, Vol. 44, Issue 18 https://doi.org/10.1021/ic0503838	journal	September 2005
A Theoretical Study of the Inner-Sphere Disproportionation Reaction Mechanism of the Pentavalent Actinyl Ions Steele, Helen; Taylor, Robin J. Inorganic Chemistry, Vol. 46, Issue 16 https://doi.org/10.1021/ic070235c	journal	August 2007
Electronic Spectra and Excited States of Neptunyl and Its [NpO ₂ Cl ₄ ] ^2– Complex Su, Jing; Schwarz, W. H. E.; Li, Jun Inorganic Chemistry, Vol. 51, Issue 5 https://doi.org/10.1021/ic202712p	journal	February 2012
Uranium–Ligand Multiple Bonding in Uranyl Analogues, [L═U═L] ^{n +} , and the Inverse Trans Influence La Pierre, Henry S.; Meyer, Karsten Inorganic Chemistry, Vol. 52, Issue 2 https://doi.org/10.1021/ic302412j	journal	December 2012
Structural and Vibrational Properties of U(VI)O ₂ Cl ₄ ^2- and Pu(VI)O ₂ Cl ₄ ^2- Complexes Schnaars, David D.; Wilson, Richard E. Inorganic Chemistry, Vol. 52, Issue 24 https://doi.org/10.1021/ic401991n	journal	November 2013
Electronic spectral studies of some uranium(V) compounds Selbin, Joel; Ortego, James D.; Gritzner, G. Inorganic Chemistry, Vol. 7, Issue 5 https://doi.org/10.1021/ic50063a027	journal	May 1968
Anomalous One-Electron Processes in the Chemistry of Uranium Nitrogen Multiple Bonds Mullane, Kimberly C.; Lewis, Andrew J.; Yin, Haolin Inorganic Chemistry, Vol. 53, Issue 17 https://doi.org/10.1021/ic501149u	journal	August 2014
Kinetics and mechanism of the disproportionation of uranium(V) Ekstrom, A. Inorganic Chemistry, Vol. 13, Issue 9 https://doi.org/10.1021/ic50139a035	journal	September 1974
Tris((hexamethyldisilyl)amido)uranium(III): preparation and coordination chemistry Andersen, Richard A. Inorganic Chemistry, Vol. 18, Issue 6 https://doi.org/10.1021/ic50196a021	journal	June 1979
Mixed-Ligand Uranyl(V) β-Diketiminate/β-Diketonate Complexes: Synthesis and Characterization Hayton, Trevor W.; Wu, Guang Inorganic Chemistry, Vol. 47, Issue 16 https://doi.org/10.1021/ic800778j	journal	August 2008
X-ray Absorption Spectroscopy of Tricarbonatodioxouranate(V), [UO ₂ (CO ₃ ) ₃ ] ⁵ ^- , in Aqueous Solution Docrat, T. I.; Mosselmans, J. F. W.; Charnock, J. M. Inorganic Chemistry, Vol. 38, Issue 8 https://doi.org/10.1021/ic9814423	journal	April 1999
Uranium(VI) organoimido complexes Burns, Carol J.; Smith, Wayne H.; Huffman, John C. Journal of the American Chemical Society, Vol. 112, Issue 8 https://doi.org/10.1021/ja00164a069	journal	April 1990
Tertiary phosphine complexes of the f-block metals. Crystal structure of Yb[N(SiMe3)2]2[Me2PCH2CH2PMe2]: evidence for a ytterbium-.gamma.-carbon interaction Tilley, T. Don; Andersen, Richard A.; Zalkin, Allan Journal of the American Chemical Society, Vol. 104, Issue 13 https://doi.org/10.1021/ja00377a033	journal	June 1982
Synthesis and Structure of a Stable Pentavalent-Uranyl Coordination Polymer Natrajan, Louise; Burdet, Fabien; Pécaut, Jacques Journal of the American Chemical Society, Vol. 128, Issue 22 https://doi.org/10.1021/ja0609809	journal	June 2006
Luminescence from Neptunyl(VI) Species in Solution Talbot-Eeckelaers, Catherine; Pope, Simon J. A.; Hynes, Amanda J. Journal of the American Chemical Society, Vol. 129, Issue 9 https://doi.org/10.1021/ja068522n	journal	March 2007
Synthesis, Characterization, and Reactivity of a Uranyl β-Diketiminate Complex Hayton, Trevor W.; Wu, Guang Journal of the American Chemical Society, Vol. 130, Issue 6 https://doi.org/10.1021/ja077538q	journal	February 2008
A Direct Route to Bis(imido)uranium(V) Halides via Metathesis of Uranium Tetrachloride Jilek, Robert E.; Spencer, Liam P.; Lewis, Richard A. Journal of the American Chemical Society, Vol. 134, Issue 24 https://doi.org/10.1021/ja2108432	journal	June 2012
Synthesis of a Uranium(VI)-Carbene: Reductive Formation of Uranyl(V)-Methanides, Oxidative Preparation of a [R ₂ C═U═O] ²⁺ Analogue of the [O═U═O] ²⁺ Uranyl Ion (R = Ph ₂ PNSiMe ₃ ), and Comparison of the Nature of U ^IV ═C, U ^V ═C, and U ^VI ═C Double Bonds Mills, David P.; Cooper, Oliver J.; Tuna, Floriana Journal of the American Chemical Society, Vol. 134, Issue 24 https://doi.org/10.1021/ja301333f	journal	June 2012
Polynuclear Cation−Cation Complexes of Pentavalent Uranyl: Relating Stability and Magnetic Properties to Structure Nocton, Grégory; Horeglad, Pawel; Pécaut, Jacques Journal of the American Chemical Society, Vol. 130, Issue 49 https://doi.org/10.1021/ja804766r	journal	December 2008
Synthesis, Structure, and Bonding of Stable Complexes of Pentavalent Uranyl Nocton, Grégory; Horeglad, Pawel; Vetere, Valentina Journal of the American Chemical Society, Vol. 132, Issue 2 https://doi.org/10.1021/ja9037164	journal	December 2009
Synthesis and Characterization of a Water Stable Uranyl(V) Complex Faizova, Radmila; Scopelliti, Rosario; Chauvin, Anne-Sophie Journal of the American Chemical Society, Vol. 140, Issue 42 https://doi.org/10.1021/jacs.8b07885	journal	September 2018
Intensities in the Spectra of Actinyl Ions Matsika, Spiridoula; Pitzer, Russell M.; Reed, Donald T. The Journal of Physical Chemistry A, Vol. 104, Issue 51 https://doi.org/10.1021/jp002580s	journal	December 2000
Electronic Structure and Bonding in Actinyl Ions and their Analogs Denning, Robert G. The Journal of Physical Chemistry A, Vol. 111, Issue 20 https://doi.org/10.1021/jp071061n	journal	May 2007
An ab Initio Theoretical Study of the Electronic Structure of UO ₂ ⁺ and [UO ₂ (CO ₃ ) ₃ ] ⁵⁻ Ruipérez, Fernando; Danilo, Cécile; Réal, Florent The Journal of Physical Chemistry A, Vol. 113, Issue 8 https://doi.org/10.1021/jp809108h	journal	February 2009
Application of Relativistic Quantum Chemistry to the Electronic Energy Levels of the Uranyl Ion Zhang, Zhiyong; Pitzer, Russell M. The Journal of Physical Chemistry A, Vol. 103, Issue 34 https://doi.org/10.1021/jp991867q	journal	August 1999
Reduction and selective oxo group silylation of the uranyl dication Arnold, Polly L.; Patel, Dipti; Wilson, Claire Nature, Vol. 451, Issue 7176 https://doi.org/10.1038/nature06467	journal	January 2008
Strongly coupled binuclear uranium–oxo complexes from uranyl oxo rearrangement and reductive silylation Arnold, Polly L.; Jones, Guy M.; Odoh, Samuel O. Nature Chemistry, Vol. 4, Issue 3 https://doi.org/10.1038/nchem.1270	journal	February 2012
Uranium and manganese assembled in a wheel-shaped nanoscale single-molecule magnet with high spin-reversal barrier Mougel, Victor; Chatelain, Lucile; Pécaut, Jacques Nature Chemistry, Vol. 4, Issue 12 https://doi.org/10.1038/nchem.1494	journal	November 2012
Easy access to stable pentavalent uranyl complexes Berthet, Jean-Claude; Siffredi, Gérald; Thuéry, Pierre Chem. Commun., Issue 30 https://doi.org/10.1039/B605710A	journal	January 2006
Multi-electron reduction facilitated by a trianionic pyridine(diimine) ligand Cladis, Dennis P.; Kiernicki, John J.; Fanwick, Phillip E. Chem. Commun., Vol. 49, Issue 39 https://doi.org/10.1039/C2CC37193F	journal	January 2013
A homoleptic tetravalent cerium silylamide Crozier, Alan R.; Bienfait, Andre M.; Maichle-Mössmer, Cäcilia Chem. Commun., Vol. 49, Issue 1 https://doi.org/10.1039/C2CC37404H	journal	January 2013
Neptunyl( vi ) centred visible LMCT emission directly observable in the presence of uranyl( vi ) Woodall, Sean D.; Swinburne, Adam N.; lal Banik, Nidhu Chemical Communications, Vol. 51, Issue 25 https://doi.org/10.1039/C4CC08718F	journal	January 2015
Catalytic one-electron reduction of uranyl( vi ) to Group 1 uranyl( v ) complexes via Al( iii ) coordination Zegke, Markus; Nichol, Gary S.; Arnold, Polly L. Chemical Communications, Vol. 51, Issue 27 https://doi.org/10.1039/C5CC00867K	journal	January 2015
Fluorescence spectroscopy and microscopy as tools for monitoring redox transformations of uranium in biological systems Jones, Debbie L.; Andrews, Michael B.; Swinburne, Adam N. Chemical Science, Vol. 6, Issue 9 https://doi.org/10.1039/C5SC00661A	journal	January 2015
Understanding the origins of O _yl –U–O _yl bending in the uranyl (UO ₂ ²⁺ ) ion Hayton, Trevor W. Dalton Transactions, Vol. 47, Issue 4 https://doi.org/10.1039/C7DT04123C	journal	January 2018
Isolation of U( ii ) compounds using strong donor ligands, C ₅ Me ₄ H and N(SiMe ₃ ) ₂ , including a three-coordinate U( ii ) complex Ryan, Austin J.; Angadol, Mary A.; Ziller, Joseph W. Chemical Communications, Vol. 55, Issue 16 https://doi.org/10.1039/C8CC08767A	journal	January 2019
Stabilization of uranyl( v ) by dipicolinic acid in aqueous medium Agarwal, Rahul; Dumpala, Rama Mohana Rao; Sharma, Manoj K. Dalton Transactions, Vol. 50, Issue 4 https://doi.org/10.1039/D0DT03961F	journal	January 2021
Pentavalent uranium chemistry—synthetic pursuit of a rare oxidation state Graves, Christopher R.; Kiplinger, Jaqueline L. Chemical Communications, Issue 26 https://doi.org/10.1039/b902969a	journal	January 2009
Pentavalent uranium trans-dihalides and -pseudohalides Lewis, Andrew J.; Nakamaru-Ogiso, Eiko; Kikkawa, James M. Chemical Communications, Vol. 48, Issue 41 https://doi.org/10.1039/c2cc31601c	journal	January 2012
Magnetic communication and reactivity of a stable homometallic cation–cation trimer of pentavalent uranyl Chatelain, Lucile; Mougel, Victor; Pécaut, Jacques Chemical Science, Vol. 3, Issue 4 https://doi.org/10.1039/c2sc00782g	journal	January 2012
Raman and infrared spectroscopic studies of the uranyl ion: the symmetric stretching frequency, force constants, and bond lengths Bullock, J. I. Journal of the Chemical Society A: Inorganic, Physical, Theoretical https://doi.org/10.1039/j19690000781	journal	January 1969
400. The determination of the paramagnetic susceptibility of substances in solution by nuclear magnetic resonance Evans, D. F. Journal of the Chemical Society (Resumed) https://doi.org/10.1039/jr9590002003	journal	January 1959
Electronic structure and spectrum of UO22+ and UO2Cl42− Pierloot, Kristine; van Besien, Els The Journal of Chemical Physics, Vol. 123, Issue 20 https://doi.org/10.1063/1.2121608	journal	November 2005
A Fock space coupled cluster study on the electronic structure of the UO2, UO2+, U4+, and U5+ species Infante, Ivan; Eliav, Ephraim; Vilkas, Marius J. The Journal of Chemical Physics, Vol. 127, Issue 12 https://doi.org/10.1063/1.2770699	journal	September 2007
Spectroscopy of the UO2+ cation and the delayed ionization of UO2 Merritt, Jeremy M.; Han, Jiande; Heaven, Michael C. The Journal of Chemical Physics, Vol. 128, Issue 8 https://doi.org/10.1063/1.2830260	journal	February 2008
Energy‐adjusted pseudopotentials for the actinides. Parameter sets and test calculations for thorium and thorium monoxide Küchle, W.; Dolg, M.; Stoll, H. The Journal of Chemical Physics, Vol. 100, Issue 10 https://doi.org/10.1063/1.466847	journal	May 1994
Fully optimized contracted Gaussian basis sets of triple zeta valence quality for atoms Li to Kr Schäfer, Ansgar; Huber, Christian; Ahlrichs, Reinhart The Journal of Chemical Physics, Vol. 100, Issue 8 https://doi.org/10.1063/1.467146	journal	April 1994
Toward reliable density functional methods without adjustable parameters: The PBE0 model Adamo, Carlo; Barone, Vincenzo The Journal of Chemical Physics, Vol. 110, Issue 13 https://doi.org/10.1063/1.478522	journal	April 1999
The electronic structure of the uranyl ion: III. Theory Denning, R. G.; Snellgrove, T. R.; Woodwark, D. R. Molecular Physics, Vol. 37, Issue 4 https://doi.org/10.1080/00268977900100841	journal	April 1979
Study on Redox Equilibrium of UO ₂ ²⁺ /U ₂ ⁺ in Molten NaCl-2CsCl by UV-Vis Spectrophotometry Nagai, Takayuki; Fujii, Toshiyuki; Shirai, Osamu Journal of Nuclear Science and Technology, Vol. 41, Issue 6 https://doi.org/10.1080/18811248.2004.9715534	journal	June 2004
Generalized Gradient Approximation Made Simple Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868 https://doi.org/10.1103/PhysRevLett.77.3865	journal	October 1996
Tris[bis(trimethylsilyl)amido](trimethylsilylimido)uranium(V) Zalkin, A.; Brennan, J. G.; Andersen, R. A. Acta Crystallographica Section C Crystal Structure Communications, Vol. 44, Issue 9 https://doi.org/10.1107/S0108270188005116	journal	September 1988
Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides Shannon, R. D. Acta Crystallographica Section A, Vol. 32, Issue 5, p. 751-767 https://doi.org/10.1107/S0567739476001551	journal	September 1976

Similar Records

Amide complexes of uranium tetrahalides and uranyl chloride

Journal Article · 1972 · J. Chem. Soc., Dalton Trans., no. 23, pp. 2682-2686 · OSTI ID:4363435

Bagnall, K W; Du Preez, J G.H.; Bajorek, J; +3 more

A molecular orbital study of bonding and ionization energies in pentavalent uranium imide/amide complexes

Journal Article · 1992 · Inorganic Chemistry; (United States) · OSTI ID:7226907

Bowmaker, G A; Goerling, A; Haeberlen, O; +3 more

COMPLEXES OF URANYL CHLORIDE AND THORIUM AND URANIUM TETRACHLORIDES WITH DICARBOXYLIC ACID AMIDES

Journal Article · 1965 · Journal of the Chemical Society (England) Divided into J. Chem. Soc. A, J. Chem. Soc. B, etc. · OSTI ID:4519959

Bagnall, K W; Brown, D; Jones, P J

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Cations
Crystals
Energy
Nuclear magnetic resonance spectroscopy
Vinyl

Title: Photoluminescence of Pentavalent Uranyl Amide Complexes

Citation Formats

References (78)

Similar Records

Related Subjects