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Title: Dynamics of Ion Pairing in Dilute Aqueous HCl Solutions by Spectroscopic Measurements of Hydroxyl Radical Conversion into Dichloride Radical Anions

Journal Article · · Journal of Physical Chemistry. B
 [1];  [2];  [3]; ORCiD logo [1]
  1. Institute of Applied Radiation Chemistry, Faculty of Chemistry, Lodz University of Technology, Zeromskiego 116, Lodz 90-924, Poland
  2. Radiation Laboratory, University of Notre Dame, Notre Dame, Indiana 46556, United States
  3. Institute of Applied Radiation Chemistry, Faculty of Chemistry, Lodz University of Technology, Wroblewskiego 15, Lodz 93-590, Poland

Not Available

Research Organization:
Lodz Univ. of Technology (Poland)
Sponsoring Organization:
USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES)
Grant/Contract Number:
FC02-04ER15533
OSTI ID:
1812974
Journal Information:
Journal of Physical Chemistry. B, Journal Name: Journal of Physical Chemistry. B Journal Issue: 33 Vol. 125; ISSN 1520-6106
Publisher:
American Chemical SocietyCopyright Statement
Country of Publication:
United States
Language:
English

References (34)

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The enthalpy of dilution of HCl(aq) to 648 K and 40 MPa thermodynamic properties journal August 1987
The radical ion complex IOH−: Spectrum and reactions studied by pulse radiolysis of aqueous iodide solutions journal August 1976
Molecular dynamics studies on the structure of methanol-water solutions of NaCl journal June 1995
Effect of a solute on water properties — MD simulation studies journal April 2000
Multiple time scales in pulse radiolysis. Application to bromide solutions and dipeptides journal June 1999
Evaluation of the criteria of hydrogen bonding in highly associated liquids journal December 2007
On the kinetics and mechanism of the oxidation of I− by OH/O− in alkaline aqueous solution journal April 2006
Photolysis and photocatalysis of haloacetic acids in water: A review of kinetics, influencing factors, products, pathways, and mechanisms journal June 2020
Photochemical origin of reactive radicals and halogenated organic substances in natural waters: A review journal January 2021
Temperature dependence of the rate constant for the bimolecular recombination of Cl−2 in water—A pulse radiolysis study journal April 2014
Temperature dependence of the rate constant for hydrogen atom reaction with Cl 2 −• in water by pulse radiolysis of aqueous HCl solution journal December 2015
Chlorine photolysis and subsequent OH radical production during UV treatment of chlorinated water journal July 2007
Medium pressure UV combined with chlorine advanced oxidation for trichloroethylene destruction in a model water journal October 2012
Pulse radiolysis studies on Br- in aqueous solution. Mechanism of Br2 formation journal June 1972
Mechanistic Insight into the Reactivity of Chlorine-Derived Radicals in the Aqueous-Phase UV–Chlorine Advanced Oxidation Process: Quantum Mechanical Calculations journal June 2017
Ionic-Equilibrium-Based Mechanism of OH Conversion to Dichloride Radical Anion in Aqueous Acidic Solutions by Kinetic and Theoretical Studies journal December 2018
Oxidation of aqueous bromide ions by hydroxyl radicals. Pulse radiolytic investigation journal February 1972
Pulse Radiolysis Studies of Aqueous Sodium Chloride Solutions 1 journal December 1964
Structure of Hydronium (H 3 O + )/Chloride (Cl ) Contact Ion Pairs in Aqueous Hydrochloric Acid Solution: A Zundel-like Local Configuration journal September 2010
Densities and Apparent Molar Volumes of Atmospherically Important Electrolyte Solutions. 1. The Solutes H 2 SO 4 , HNO 3 , HCl, Na 2 SO 4 , NaNO 3 , NaCl, (NH 4 ) 2 SO 4 , NH 4 NO 3 , and NH 4 Cl from 0 to 50 °C, Including Extrapolations to Very Low Temperature and to the Pure Liquid State, and NaHSO 4 , NaOH, and NH 3 at 25 °C journal April 2011
Picosecond Pulse Radiolysis of Direct and Indirect Radiolytic Effects in Highly Concentrated Halide Aqueous Solutions journal August 2011
Hemibonding of Hydroxyl Radical and Halide Anion in Aqueous Solution journal December 2011
Oxidation of Bromide Ions by Hydroxyl Radicals: Spectral Characterization of the Intermediate BrOH •– journal January 2013
Persistent Ion Pairing in Aqueous Hydrochloric Acid journal June 2014
Sequential radiation chemical reactions in aqueous bromide solutions: pulse radiolysis experiment and spur model simulation journal January 2015
Evaluation of the stability constant of Cl 2 ˙ in neutral aqueous solution journal January 1995
Reactivity of chlorine atoms in aqueous solution Part 1The equilibrium ClMNsbd+Cl-Cl2- journal January 1998
A density functional theory based study of the microscopic structure and dynamics of aqueous HCl solutions journal January 2006
Pressure and temperature dependence of self-diffusion in water journal January 1978
Some simple, highly reactive, inorganic chlorine derivatives in aqueous solution. Their formation using pulses of radiation and their role in the mechanism of the Fricke dosimeter
  • Jayson, G. G.; Parsons, B. J.; Swallow, A. J.
  • Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, Vol. 69, Issue 0 https://doi.org/10.1039/f19736901597
journal January 1973
Re-evaluation of the thiocyanate dosimeter for pulse radiolysis journal January 1995
Transition from patchlike to clusterlike inhomogeneity arising from hydrogen bonding in water journal February 2011
Density and temperature effect on hydrogen-bonded clusters in water - MD simulation study journal December 2008

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