Energy storage mechanisms in vacancy-ordered Wadsley–Roth layered niobates

McColl, Kit; Griffith, Kent J.; Dally, Rebecca L.; Li, Runze; Douglas, Jason E.; Poeppelmeier, Kenneth R.; Corà, Furio; Levin, Igor; Butala, Megan M.

doi:10.1039/D1TA02992D

Title: Energy storage mechanisms in vacancy-ordered Wadsley–Roth layered niobates

Journal Article · 14 September 2021 · Journal of Materials Chemistry. A

DOI: https://doi.org/10.1039/D1TA02992D · OSTI ID:1812831

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^[3]; Li, Runze ^[4]; Douglas, Jason E. ^[5];

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^[1]; Levin, Igor ^[6];

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Department of Chemistry, University College London, London, WC1H 0AJ, UK
Department of Chemistry, Northwestern University, Evanston, IL 60208, USA
NIST Center for Neutron Research, National Institute of Standards and Technology, Gaithersburg, MD 20899, USA
Department of Materials Science and Engineering, University of Florida, Gainesville, FL 32611, USA
Materials Science and Engineering Division, National Institute of Standards and Technology, Gaithersburg, MD 20899, USA
Materials Measurement Science Division, National Institute of Standards and Technology, Gaithersburg, MD 20899, USA
Department of Materials Science and Engineering, University of Florida, Gainesville, FL 32611, USA, Materials Measurement Science Division, National Institute of Standards and Technology, Gaithersburg, MD 20899, USA

Layered niobates with vacancy-ordered Wadsley–Roth structures were investigated as Li-ion battery anodes. Using operando and ex situ methods and DFT, we identify an intercalation mechanism dominated by Li-diffusion kinetics and layer evolution.

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Sponsoring Organization:: USDOE

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1812831

Journal Information:: Journal of Materials Chemistry. A, Journal Name: Journal of Materials Chemistry. A Journal Issue: 35 Vol. 9; ISSN JMCAET; ISSN 2050-7488

Publisher:: Royal Society of Chemistry (RSC)Copyright Statement

Country of Publication:: United Kingdom

Language:: English

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