Process modeling, techno-economic assessment, and life cycle assessment of the electrochemical reduction of CO2: a review
Abstract
The electrochemical reduction of CO2 has emerged as a promising alternative to traditional fossil-based technologies for the synthesis of chemicals. Its industrial implementation could lead to a reduction in the carbon footprint of chemicals and the mitigation of climate change impacts caused by hard-to-decarbonize industrial applications, among other benefits. However, the current low technology readiness levels of such emerging technologies make it hard to predict their performance at industrial scales. During the past few years, researchers have developed diverse techniques to model and assess the electrochemical reduction of CO2 toward its industrial implementation. The aim of this literature review is to provide a comprehensive overview of techno-economic and life cycle assessment methods and pave the way for future assessment approaches. First, we identify which modeling approaches have been conducted to extend analysis to the production scale. Next, we explore the metrics used to evaluate such systems, regarding technical, environmental, and economic aspects. Finally, we assess the challenges and research opportunities for the industrial implementation of CO2 reduction via electrolysis.
- Authors:
-
- Univ. of Colorado, Boulder, CO (United States). Renewable and Sustainable Energy Inst.
- National Renewable Energy Lab. (NREL), Golden, CO (United States)
- Univ. of Colorado, Boulder, CO (United States). Renewable and Sustainable Energy Inst.; National Renewable Energy Lab. (NREL), Golden, CO (United States)
- Publication Date:
- Research Org.:
- National Renewable Energy Lab. (NREL), Golden, CO (United States)
- Sponsoring Org.:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE)
- OSTI Identifier:
- 1812705
- Report Number(s):
- NREL/JA-5C00-80633
Journal ID: ISSN 2589-0042; MainId:66364;UUID:1d233076-9350-4a30-a6e0-a3040f8e1579;MainAdminID:48439
- Grant/Contract Number:
- AC36-08GO28308
- Resource Type:
- Accepted Manuscript
- Journal Name:
- iScience
- Additional Journal Information:
- Journal Volume: 24; Journal Issue: 7; Journal ID: ISSN 2589-0042
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 54 ENVIRONMENTAL SCIENCES; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; electrochemistry; energy engineering; energy policy; energy resources; energy sustainability; energy systems
Citation Formats
Somoza-Tornos, Ana, Guerra, Omar J., Crow, Allison M., Smith, Wilson A., and Hodge, Bri-Mathias. Process modeling, techno-economic assessment, and life cycle assessment of the electrochemical reduction of CO2: a review. United States: N. p., 2021.
Web. doi:10.1016/j.isci.2021.102813.
Somoza-Tornos, Ana, Guerra, Omar J., Crow, Allison M., Smith, Wilson A., & Hodge, Bri-Mathias. Process modeling, techno-economic assessment, and life cycle assessment of the electrochemical reduction of CO2: a review. United States. https://doi.org/10.1016/j.isci.2021.102813
Somoza-Tornos, Ana, Guerra, Omar J., Crow, Allison M., Smith, Wilson A., and Hodge, Bri-Mathias. Thu .
"Process modeling, techno-economic assessment, and life cycle assessment of the electrochemical reduction of CO2: a review". United States. https://doi.org/10.1016/j.isci.2021.102813. https://www.osti.gov/servlets/purl/1812705.
@article{osti_1812705,
title = {Process modeling, techno-economic assessment, and life cycle assessment of the electrochemical reduction of CO2: a review},
author = {Somoza-Tornos, Ana and Guerra, Omar J. and Crow, Allison M. and Smith, Wilson A. and Hodge, Bri-Mathias},
abstractNote = {The electrochemical reduction of CO2 has emerged as a promising alternative to traditional fossil-based technologies for the synthesis of chemicals. Its industrial implementation could lead to a reduction in the carbon footprint of chemicals and the mitigation of climate change impacts caused by hard-to-decarbonize industrial applications, among other benefits. However, the current low technology readiness levels of such emerging technologies make it hard to predict their performance at industrial scales. During the past few years, researchers have developed diverse techniques to model and assess the electrochemical reduction of CO2 toward its industrial implementation. The aim of this literature review is to provide a comprehensive overview of techno-economic and life cycle assessment methods and pave the way for future assessment approaches. First, we identify which modeling approaches have been conducted to extend analysis to the production scale. Next, we explore the metrics used to evaluate such systems, regarding technical, environmental, and economic aspects. Finally, we assess the challenges and research opportunities for the industrial implementation of CO2 reduction via electrolysis.},
doi = {10.1016/j.isci.2021.102813},
journal = {iScience},
number = 7,
volume = 24,
place = {United States},
year = {Thu Jul 01 00:00:00 EDT 2021},
month = {Thu Jul 01 00:00:00 EDT 2021}
}
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Works referenced in this record:
Environmental impacts of power-to-X systems - A review of technological and methodological choices in Life Cycle Assessments
journal, September 2019
- Koj, Jan Christian; Wulf, Christina; Zapp, Petra
- Renewable and Sustainable Energy Reviews, Vol. 112
Net-zero emissions energy systems
journal, June 2018
- Davis, Steven J.; Lewis, Nathan S.; Shaner, Matthew
- Science, Vol. 360, Issue 6396
Formic acid synthesis using CO2 as raw material: Techno-economic and environmental evaluation and market potential
journal, October 2016
- Pérez-Fortes, Mar; Schöneberger, Jan C.; Boulamanti, Aikaterini
- International Journal of Hydrogen Energy, Vol. 41, Issue 37
Terawatt-scale photovoltaics: Transform global energy
journal, May 2019
- Haegel, Nancy M.; Atwater, Harry; Barnes, Teresa
- Science, Vol. 364, Issue 6443
Techno-Economic Assessment Guidelines for CO2 Utilization
journal, January 2020
- Zimmermann, Arno W.; Wunderlich, Johannes; Müller, Leonard
- Frontiers in Energy Research, Vol. 8
Toward Technology-Sensitive Catching-Up Policies: Insights from Renewable Energy in China
journal, August 2017
- Binz, Christian; Gosens, Jorrit; Hansen, Teis
- World Development, Vol. 96
What would it take for renewably powered electrosynthesis to displace petrochemical processes?
journal, April 2019
- De Luna, Phil; Hahn, Christopher; Higgins, Drew
- Science, Vol. 364, Issue 6438
Integrating Nickel-Nitrogen Doped Carbon Catalyzed CO2 Electroreduction with Chlor-Alkali Process for CO, Cl2 and KHCO3 Production with Enhanced Techno-Economics
journal, October 2020
- Guo, Jin-Han; Sun, Wei-Yin
- Applied Catalysis B: Environmental, Vol. 275
Towards sustainable fuels and chemicals through the electrochemical reduction of CO 2 : lessons from water electrolysis
journal, January 2015
- Martín, Antonio J.; Larrazábal, Gastón O.; Pérez-Ramírez, Javier
- Green Chemistry, Vol. 17, Issue 12
An integrated electrochemical and biochemical system for sequential reduction of CO2 to methane
journal, May 2018
- Huang, Yu-Xi; Hu, Zhiqiang
- Fuel, Vol. 220
What Should We Make with CO2 and How Can We Make It?
journal, May 2018
- Bushuyev, Oleksandr S.; De Luna, Phil; Dinh, Cao Thang
- Joule, Vol. 2, Issue 5
Assessment of Solar-to-Fuels Strategies: Photocatalysis and Electrocatalytic Reduction
journal, June 2016
- Herron, Jeffrey A.; Maravelias, Christos T.
- Energy Technology, Vol. 4, Issue 11
A review on electrochemical synthesized copper-based catalysts for electrochemical reduction of CO2 to C2+ products
journal, June 2021
- Ye, Wangxiang; Guo, Xiaolin; Ma, Tingli
- Chemical Engineering Journal, Vol. 414
A review of technology and policy deep decarbonization pathway options for making energy-intensive industry production consistent with the Paris Agreement
journal, June 2018
- Bataille, Chris; Åhman, Max; Neuhoff, Karsten
- Journal of Cleaner Production, Vol. 187
First-Principles Based Microkinetic Modeling of CO 2 Reduction at the Ni/SDC Cathode of a Solid Oxide Electrolysis Cell
journal, August 2018
- Ren, Bohua; Li, Jingde; Wen, Guobin
- The Journal of Physical Chemistry C, Vol. 122, Issue 37
From Laboratory to Industrial Scale: A Prospective LCA for Electrochemical Reduction of CO 2 to Formic Acid
journal, October 2019
- Thonemann, Nils; Schulte, Anna
- Environmental Science & Technology, Vol. 53, Issue 21
Carbon-Based Materials for Electrochemical Reduction of CO 2 to C 2+ Oxygenates: Recent Progress and Remaining Challenges
journal, February 2021
- Zhao, Kun; Quan, Xie
- ACS Catalysis, Vol. 11, Issue 4
Comparative life cycle assessment of electrochemical upgrading of CO 2 to fuels and feedstocks
journal, January 2021
- Kibria Nabil, Shariful; McCoy, Sean; Kibria, Md Golam
- Green Chemistry, Vol. 23, Issue 2
A Guideline for Life Cycle Assessment of Carbon Capture and Utilization
journal, February 2020
- Müller, Leonard Jan; Kätelhön, Arne; Bachmann, Marvin
- Frontiers in Energy Research, Vol. 8
Influence of impact assessment methods in wastewater treatment LCA
journal, July 2008
- Renou, S.; Thomas, J. S.; Aoustin, E.
- Journal of Cleaner Production, Vol. 16, Issue 10
Hybridization of Fossil‐ and CO 2 ‐Based Routes for Ethylene Production using Renewable Energy
journal, August 2020
- Ioannou, Iasonas; D'Angelo, Sebastiano C.; Martín, Antonio J.
- ChemSusChem
Dimethyl ether synthesis via captured CO2 hydrogenation within the power to liquids concept: A techno-economic assessment
journal, March 2019
- Michailos, Stavros; McCord, Stephen; Sick, Volker
- Energy Conversion and Management, Vol. 184
CO 2 Electroreduction to Formate at a Partial Current Density of 930 mA cm –2 with InP Colloidal Quantum Dot Derived Catalysts
journal, December 2020
- Grigioni, Ivan; Sagar, Laxmi Kishore; Li, Yuguang C.
- ACS Energy Letters, Vol. 6, Issue 1
Production of Methane and Ethylene in Electrochemical Reduction of Carbon Dioxide at Copper Electrode in Aqueous Hydrogencarbonate Solution
journal, June 1986
- Hori, Yoshio; Kikuchi, Katsuhei; Murata, Akira
- Chemistry Letters, Vol. 15, Issue 6
Integrated design for electrocatalytic carbon dioxide reduction
journal, January 2020
- Zhao, Xin; Du, Lijie; You, Bo
- Catalysis Science & Technology, Vol. 10, Issue 9
Sustainable Conversion of Carbon Dioxide: An Integrated Review of Catalysis and Life Cycle Assessment
journal, December 2017
- Artz, Jens; Müller, Thomas E.; Thenert, Katharina
- Chemical Reviews, Vol. 118, Issue 2
A Robust, Scalable Platform for the Electrochemical Conversion of CO 2 to Formate: Identifying Pathways to Higher Energy Efficiencies
journal, May 2020
- Chen, Yingying; Vise, Ashlee; Klein, W. Ellis
- ACS Energy Letters, Vol. 5, Issue 6
General technoeconomic analysis for electrochemical coproduction coupling carbon dioxide reduction with organic oxidation
journal, November 2019
- Na, Jonggeol; Seo, Bora; Kim, Jeongnam
- Nature Communications, Vol. 10, Issue 1
Modeling of solid oxide electrolysis cell for syngas generation with detailed surface chemistry
journal, September 2012
- Xie, Yuanyuan; Xue, Xingjian
- Solid State Ionics, Vol. 224
Experimental Validation of Two-Dimensional H 2 O and CO 2 Co-Electrolysis Modeling
journal, June 2014
- Aicart, J.; Laurencin, J.; Petitjean, M.
- Fuel Cells, Vol. 14, Issue 3
The influence of impact assessment methods on materials selection for eco-design
journal, January 2006
- Bovea, M. D.; Gallardo, A.
- Materials & Design, Vol. 27, Issue 3
Selecting emerging CO2 utilization products for short- to mid-term deployment
journal, February 2019
- Chauvy, Remi; Meunier, Nicolas; Thomas, Diane
- Applied Energy, Vol. 236
Modeling CO2 electrolysis in solid oxide electrolysis cell
journal, May 2013
- Narasimhaiah, Geetha; Janardhanan, Vinod M.
- Journal of Solid State Electrochemistry, Vol. 17, Issue 8
An outlook towards 2030: Optimization and design of a CCUS supply chain in Germany
journal, June 2019
- Leonzio, Grazia; Foscolo, Pier Ugo; Zondervan, Edwin
- Computers & Chemical Engineering, Vol. 125
Electrochemical CO 2 Reduction into Chemical Feedstocks: From Mechanistic Electrocatalysis Models to System Design
journal, December 2018
- Kibria, Md Golam; Edwards, Jonathan P.; Gabardo, Christine M.
- Advanced Materials, Vol. 31, Issue 31
Input–Output Surrogate Models for Efficient Economic Evaluation of Amine Scrubbing CO 2 Capture Processes
journal, September 2020
- Chung, Wonsuk; Lee, Jay H.
- Industrial & Engineering Chemistry Research, Vol. 59, Issue 42
An analysis of research hotspots and modeling techniques on carbon capture and storage
journal, October 2019
- Li, Hui; Jiang, Hong-Dian; Yang, Bo
- Science of The Total Environment, Vol. 687
Electrification and Decarbonization of the Chemical Industry
journal, September 2017
- Schiffer, Zachary J.; Manthiram, Karthish
- Joule, Vol. 1, Issue 1
Assessing the feasibility of carbon dioxide mitigation options in terms of energy usage
journal, July 2020
- Babacan, Oytun; De Causmaecker, Sven; Gambhir, Ajay
- Nature Energy, Vol. 5, Issue 9
CO2 Utilization Pathways: Techno-Economic Assessment and Market Opportunities
journal, January 2014
- Pérez-Fortes, Mar; Bocin-Dumitriu, Andrei; Tzimas, Evangelos
- Energy Procedia, Vol. 63
High-Pressure Electrochemical Reduction of CO 2 to Formic Acid/Formate: Effect of pH on the Downstream Separation Process and Economics
journal, November 2019
- Ramdin, Mahinder; Morrison, Andrew R. T.; de Groen, Mariette
- Industrial & Engineering Chemistry Research, Vol. 58, Issue 51
Economics of CO2 Utilization: A Critical Analysis
journal, September 2020
- Centi, Gabriele; Perathoner, Siglinda; Salladini, Annarita
- Frontiers in Energy Research, Vol. 8
Recent advances in innovative strategies for the CO 2 electroreduction reaction
journal, January 2021
- Tan, Xinyi; Yu, Chang; Ren, Yongwen
- Energy & Environmental Science, Vol. 14, Issue 2
Modeling gas-diffusion electrodes for CO 2 reduction
journal, January 2018
- Weng, Lien-Chun; Bell, Alexis T.; Weber, Adam Z.
- Physical Chemistry Chemical Physics, Vol. 20, Issue 25
Early-stage evaluation of emerging CO 2 utilization technologies at low technology readiness levels
journal, January 2020
- Roh, Kosan; Bardow, André; Bongartz, Dominik
- Green Chemistry, Vol. 22, Issue 12
Carbon monoxide electroreduction as an emerging platform for carbon utilization
journal, December 2019
- Jouny, Matthew; Hutchings, Gregory S.; Jiao, Feng
- Nature Catalysis, Vol. 2, Issue 12
Techno-economic evaluation of indirect carbonation for CO2 emissions capture in cement industry: A system dynamics approach
journal, August 2020
- Proaño, Laura; Sarmiento, Alfonso T.; Figueredo, Manuel
- Journal of Cleaner Production, Vol. 263
A Simple Framework for Quantifying Electrochemical CO2 Fixation
journal, April 2018
- Chen, Anqi; Lin, Bo-Lin
- Joule, Vol. 2, Issue 4
Bringing value to the chemical industry from capture, storage and use of CO2: A dynamic LCA of formic acid production
journal, May 2019
- Aldaco, Rubén; Butnar, Isabela; Margallo, María
- Science of The Total Environment, Vol. 663
Co-electrolysis of CO2 and glycerol as a pathway to carbon chemicals with improved technoeconomics due to low electricity consumption
journal, April 2019
- Verma, Sumit; Lu, Shawn; Kenis, Paul J. A.
- Nature Energy, Vol. 4, Issue 6
Life Cycle Assessment of Carbon Dioxide-Based Production of Methane and Methanol and Derived Polymers: LCA of CO 2 -based chemicals
journal, April 2017
- Hoppe, Wieland; Thonemann, Nils; Bringezu, Stefan
- Journal of Industrial Ecology, Vol. 22, Issue 2
General Techno-Economic Analysis of CO 2 Electrolysis Systems
journal, February 2018
- Jouny, Matthew; Luc, Wesley; Jiao, Feng
- Industrial & Engineering Chemistry Research, Vol. 57, Issue 6
Formic Acid Manufacture: Carbon Dioxide Utilization Alternatives
journal, June 2018
- Rumayor, Marta; Dominguez-Ramos, Antonio; Irabien, Angel
- Applied Sciences, Vol. 8, Issue 6
Uncertainty Quantification in CO 2 Sequestration Using Surrogate Models from Polynomial Chaos Expansion
journal, June 2012
- Zhang, Yan; Sahinidis, Nikolaos V.
- Industrial & Engineering Chemistry Research, Vol. 52, Issue 9
Global warming footprint of the electrochemical reduction of carbon dioxide to formate
journal, October 2015
- Dominguez-Ramos, A.; Singh, B.; Zhang, X.
- Journal of Cleaner Production, Vol. 104
Renewable energy investment risk: An investigation of changes over time and the underlying drivers
journal, May 2020
- Egli, Florian
- Energy Policy, Vol. 140
Transforming the carbon economy: challenges and opportunities in the convergence of low-cost electricity and reductive CO 2 utilization
journal, January 2020
- Grim, R. Gary; Huang, Zhe; Guarnieri, Michael T.
- Energy & Environmental Science, Vol. 13, Issue 2
Elementary reaction modeling of CO 2 /H 2 O co-electrolysis cell considering effects of cathode thickness
journal, December 2013
- Li, Wenying; Shi, Yixiang; Luo, Yu
- Journal of Power Sources, Vol. 243
Environmental life cycle assessment of reverse osmosis desalination: The influence of different life cycle impact assessment methods on the characterization results
journal, December 2011
- Zhou, Jin; Chang, Victor W. -C.; Fane, Anthony G.
- Desalination, Vol. 283
Along the Channel Gradients Impact on the Spatioactivity of Gas Diffusion Electrodes at High Conversions during CO 2 Electroreduction
journal, January 2021
- Kas, Recep; Star, Andrew G.; Yang, Kailun
- ACS Sustainable Chemistry & Engineering, Vol. 9, Issue 3
Grand challenges in the science of wind energy
journal, October 2019
- Veers, Paul; Dykes, Katherine; Lantz, Eric
- Science, Vol. 366, Issue 6464
Environmental and economic assessment of the formic acid electrochemical manufacture using carbon dioxide: Influence of the electrode lifetime
journal, April 2019
- Rumayor, M.; Dominguez-Ramos, A.; Irabien, A.
- Sustainable Production and Consumption, Vol. 18
Comprehensive modeling of tubular solid oxide electrolysis cell for co-electrolysis of steam and carbon dioxide
journal, June 2014
- Luo, Yu; Shi, Yixiang; Li, Wenying
- Energy, Vol. 70
Advances and challenges in understanding the electrocatalytic conversion of carbon dioxide to fuels
journal, September 2019
- Birdja, Yuvraj Y.; Pérez-Gallent, Elena; Figueiredo, Marta C.
- Nature Energy, Vol. 4, Issue 9
The technological and economic prospects for CO2 utilization and removal
journal, November 2019
- Hepburn, Cameron; Adlen, Ella; Beddington, John
- Nature, Vol. 575, Issue 7781
Environmental impacts of CO2-based chemical production: A systematic literature review and meta-analysis
journal, April 2020
- Thonemann, Nils
- Applied Energy, Vol. 263
CO 2 electrolysis to multicarbon products at activities greater than 1 A cm −2
journal, February 2020
- García de Arquer, F. Pelayo; Dinh, Cao-Thang; Ozden, Adnan
- Science, Vol. 367, Issue 6478
Life cycle assessment of CO 2 -based C1-chemicals
journal, January 2017
- Sternberg, André; Jens, Christian M.; Bardow, André
- Green Chemistry, Vol. 19, Issue 9
The path towards sustainable energy
journal, December 2016
- Chu, Steven; Cui, Yi; Liu, Nian
- Nature Materials, Vol. 16, Issue 1
Integrating CO 2 Electrolysis into the Gas-to-Liquids–Power-to-Liquids Process
journal, July 2020
- van Bavel, Svetlana; Verma, Sumit; Negro, Emanuela
- ACS Energy Letters, Vol. 5, Issue 8
Carbon capture by physical adsorption: Materials, experimental investigations and numerical modeling and simulations – A review
journal, January 2016
- Ben-Mansour, R.; Habib, M. A.; Bamidele, O. E.
- Applied Energy, Vol. 161
Towards membrane-electrode assembly systems for CO 2 reduction: a modeling study
journal, January 2019
- Weng, Lien-Chun; Bell, Alexis T.; Weber, Adam Z.
- Energy & Environmental Science, Vol. 12, Issue 6
Optimization of CCUS Supply Chains for Some European Countries under the Uncertainty
journal, August 2020
- Leonzio, Grazia; Foscolo, Pier Ugo; Zondervan, Edwin
- Processes, Vol. 8, Issue 8
Modeling and Upscaling Analysis of Gas Diffusion Electrode-Based Electrochemical Carbon Dioxide Reduction Systems
journal, December 2020
- Yang, Ziming; Li, Da; Xing, Lei
- ACS Sustainable Chemistry & Engineering, Vol. 9, Issue 1
Greenhouse Gas Emissions, Energy Efficiency, and Cost of Synthetic Fuel Production Using Electrochemical CO 2 Conversion and the Fischer–Tropsch Process
journal, June 2016
- Li, Xuping; Anderson, Paul; Jhong, Huei-Ru Molly
- Energy & Fuels, Vol. 30, Issue 7
Carbon Capture Simulation Initiative: A Case Study in Multiscale Modeling and New Challenges
journal, June 2014
- Miller, David C.; Syamlal, Madhava; Mebane, David S.
- Annual Review of Chemical and Biomolecular Engineering, Vol. 5, Issue 1
Process systems engineering – The generation next?
journal, April 2021
- Pistikopoulos, E. N.; Barbosa-Povoa, Ana; Lee, Jay H.
- Computers & Chemical Engineering, Vol. 147
Spurring low-carbon electrosynthesis through energy and innovation policy
journal, February 2021
- Schmidt, Tobias S.
- iScience, Vol. 24, Issue 2
Demonstrating Large Scale Industrial CCS through CCU – A Case Study for Methanol Production
journal, July 2017
- Collodi, Guido; Azzaro, Giuliana; Ferrari, Noemi
- Energy Procedia, Vol. 114
Modeling of a solid oxide electrolysis cell for carbon dioxide electrolysis
journal, October 2010
- Ni, Meng
- Chemical Engineering Journal, Vol. 164, Issue 1
Prospects of CO2 Utilization via Direct Heterogeneous Electrochemical Reduction
journal, December 2010
- Whipple, Devin T.; Kenis, Paul J. A.
- The Journal of Physical Chemistry Letters, Vol. 1, Issue 24, p. 3451-3458
The Electrochemical Reduction of Carbon Dioxide to Formate/Formic Acid: Engineering and Economic Feasibility
journal, September 2011
- Agarwal, Arun S.; Zhai, Yumei; Hill, Davion
- ChemSusChem, Vol. 4, Issue 9
Mathematical modeling and numerical investigation of carbon capture by adsorption: Literature review and case study
journal, July 2018
- Li, Shuangjun; Deng, Shuai; Zhao, Li
- Applied Energy, Vol. 221
CO 2 Electrolysis to CO and O 2 at High Selectivity, Stability and Efficiency Using Sustainion Membranes
journal, January 2018
- Liu, Zengcai; Yang, Hongzhou; Kutz, Robert
- Journal of The Electrochemical Society, Vol. 165, Issue 15