Heterogeneous Nature of Electrocatalytic CO/CO2 Reduction by Cobalt Phthalocyanines
Abstract
Abstract Molecular catalysts for electrochemical CO 2 reduction have traditionally been studied in their dissolved states. However, the heterogenization of molecular catalysts has the potential to deliver much higher reaction rates and enable the reduction of CO 2 by more than two electrons. In light of the recently discovered reactivity of heterogenized cobalt phthalocyanine molecules to catalyze CO 2 reduction into methanol, direct comparison is needed to uncover the distinct catalytic activity and selectivity in homogeneous catalysis versus heterogeneous catalysis. Herein, soluble cobalt phthalocyanine derivatives were synthesized, and their catalytic activities in the homogeneous solutions were evaluated. The results show that the observed catalytic activities for both CO 2 ‐to‐CO and CO‐to‐methanol conversions in aqueous solutions of the cobalt phthalocyanines are predominantly heterogeneous in nature through the adsorbed species on the electrode.
- Publication Date:
- Research Org.:
- Yale Univ., New Haven, CT (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences & Biosciences Division; National Science Foundation (NSF); USDOE
- OSTI Identifier:
- 1812300
- Alternate Identifier(s):
- OSTI ID: 1644141
- Grant/Contract Number:
- FG02-07ER15909; CHE-1651717
- Resource Type:
- Accepted Manuscript
- Journal Name:
- ChemSusChem
- Additional Journal Information:
- Journal Volume: 13; Journal Issue: 23; Journal ID: ISSN 1864-5631
- Publisher:
- ChemPubSoc Europe
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Wu, Yueshen, Hu, Gongfang, Rooney, Conor L., Brudvig, Gary W., and Wang, Hailiang. Heterogeneous Nature of Electrocatalytic CO/CO2 Reduction by Cobalt Phthalocyanines. United States: N. p., 2020.
Web. doi:10.1002/cssc.202001396.
Wu, Yueshen, Hu, Gongfang, Rooney, Conor L., Brudvig, Gary W., & Wang, Hailiang. Heterogeneous Nature of Electrocatalytic CO/CO2 Reduction by Cobalt Phthalocyanines. United States. https://doi.org/10.1002/cssc.202001396
Wu, Yueshen, Hu, Gongfang, Rooney, Conor L., Brudvig, Gary W., and Wang, Hailiang. Wed .
"Heterogeneous Nature of Electrocatalytic CO/CO2 Reduction by Cobalt Phthalocyanines". United States. https://doi.org/10.1002/cssc.202001396. https://www.osti.gov/servlets/purl/1812300.
@article{osti_1812300,
title = {Heterogeneous Nature of Electrocatalytic CO/CO2 Reduction by Cobalt Phthalocyanines},
author = {Wu, Yueshen and Hu, Gongfang and Rooney, Conor L. and Brudvig, Gary W. and Wang, Hailiang},
abstractNote = {Abstract Molecular catalysts for electrochemical CO 2 reduction have traditionally been studied in their dissolved states. However, the heterogenization of molecular catalysts has the potential to deliver much higher reaction rates and enable the reduction of CO 2 by more than two electrons. In light of the recently discovered reactivity of heterogenized cobalt phthalocyanine molecules to catalyze CO 2 reduction into methanol, direct comparison is needed to uncover the distinct catalytic activity and selectivity in homogeneous catalysis versus heterogeneous catalysis. Herein, soluble cobalt phthalocyanine derivatives were synthesized, and their catalytic activities in the homogeneous solutions were evaluated. The results show that the observed catalytic activities for both CO 2 ‐to‐CO and CO‐to‐methanol conversions in aqueous solutions of the cobalt phthalocyanines are predominantly heterogeneous in nature through the adsorbed species on the electrode.},
doi = {10.1002/cssc.202001396},
journal = {ChemSusChem},
number = 23,
volume = 13,
place = {United States},
year = {Wed Jul 15 00:00:00 EDT 2020},
month = {Wed Jul 15 00:00:00 EDT 2020}
}
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