Accelerating the insertion reactions of (NHC)Cu–H via remote ligand functionalization

Speelman, Amy L.; Tran, Ba L.; Erickson, Jeremy D.; Vasiliu, Monica; Dixon, David A.; Bullock, R. Morris

doi:10.1039/D1SC01911B

Title: Accelerating the insertion reactions of (NHC)Cu–H via remote ligand functionalization

Journal Article · 31 August 2021 · Chemical Science

DOI: https://doi.org/10.1039/D1SC01911B · OSTI ID:1811591

^[1]; Tran, Ba L. ^[1]; Erickson, Jeremy D. ^[1]; Vasiliu, Monica ^[2];

^[2];

^[1]

Institute for Integrated Catalysis, Pacific Northwest National Laboratory, Richland, WA 99352, USA
Department of Chemistry and Biochemistry, University of Alabama, Tuscaloosa, AL 35487, USA

Remote modification of an N-heterocyclic carbene ligand with bulky or electron-rich groups in [(NHC)Cu(μ-H)] ₂ increases the rate of substrate insertion, which kinetics studies suggest arises from changes in the Cu–H monomer–dimer equilibrium.

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Research Organization:: Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)

Sponsoring Organization:: USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences & Biosciences Division

Grant/Contract Number:: AC05-76RL01830

OSTI ID:: 1811591

Report Number(s):: PNNL-SA-160159

Journal Information:: Chemical Science, Journal Name: Chemical Science Journal Issue: 34 Vol. 12; ISSN 2041-6520; ISSN CSHCBM

Publisher:: Royal Society of Chemistry (RSC)Copyright Statement

Country of Publication:: United Kingdom

Language:: English

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Carbene ligands
Copper
Cu hydride
Hydride ligands
Ligand effects

Title: Accelerating the insertion reactions of (NHC)Cu–H via remote ligand functionalization

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