Mechanically robust hydrophobized double network hydrogels and their fundamental salt transport properties

Allen, Marshall J.; Sujanani, Rahul; Chamseddine, Alyssa; Freeman, Benny D.; Page, Zachariah A.

doi:10.1002/pol.20210260

Title: Mechanically robust hydrophobized double network hydrogels and their fundamental salt transport properties

Abstract

Abstract Water swollen polymer networks are attractive for applications ranging from tissue regeneration to water purification. For water purification, charged polymers provide excellent ion separation properties. However, many ion exchange membranes (IEMs) are brittle, necessitating the use of thick support materials that ultimately decrease throughput. To this end, novel double network hydrogels (DNHs) with variable water content are prepared and characterized in terms of mechanical and ion transport properties to evaluate their potential utility as tough membrane materials. The first network contains fixed anionic charges, while the other is comprised of a copolymer with varied ratios of hydrophobic ethyl acrylate (EA) and hydrophilic dimethyl acrylamide (DMA) repeat units. Characterization of freestanding DNH films reveals a reduction in water content from 88 to 53 wt% and a simultaneous increase in ultimate stress and strain by ~3.5× and ~4.5×, respectively, for 95%/5% EA/DMA, relative to 100% DMA. Fundamental salt transport properties relevant to water purification, including permeability, solubility, and diffusivity, are measured and systematically compared with conventional membrane materials to inform the development of DNHs for membrane applications. The ability to simultaneously reduce water content and increase mechanical integrity highlights the potential of DNHs as a synthetic platform for future membrane applications.

Authors:

^[1];

^[2]; Chamseddine, Alyssa ^[2];

^[2];

^[3]

Department of Chemistry The University of Texas Austin Texas USA, McKetta Department of Chemical Engineering The University of Texas Austin Texas USA
McKetta Department of Chemical Engineering The University of Texas Austin Texas USA
Department of Chemistry The University of Texas Austin Texas USA

Publication Date:: Mon Jul 26 00:00:00 EDT 2021

Sponsoring Org.:: USDOE

OSTI Identifier:: 1810209

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Journal of Polymer Science

Additional Journal Information:: Journal Name: Journal of Polymer Science Journal Volume: 59 Journal Issue: 21; Journal ID: ISSN 2642-4150

Publisher:: Wiley Blackwell (John Wiley & Sons)

Country of Publication:: United States

Language:: English

Citation Formats


                    Allen, Marshall J., Sujanani, Rahul, Chamseddine, Alyssa, Freeman, Benny D., and Page, Zachariah A. Mechanically robust hydrophobized double network hydrogels and their fundamental salt transport properties.  United States: N. p., 2021. 
Web.  doi:10.1002/pol.20210260.

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                    Allen, Marshall J., Sujanani, Rahul, Chamseddine, Alyssa, Freeman, Benny D., & Page, Zachariah A. Mechanically robust hydrophobized double network hydrogels and their fundamental salt transport properties.  United States.  https://doi.org/10.1002/pol.20210260

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                    Allen, Marshall J., Sujanani, Rahul, Chamseddine, Alyssa, Freeman, Benny D., and Page, Zachariah A. Mon .  
"Mechanically robust hydrophobized double network hydrogels and their fundamental salt transport properties".  United States.  https://doi.org/10.1002/pol.20210260.

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@article{osti_1810209,

  title        = {Mechanically robust hydrophobized double network hydrogels and their fundamental salt transport properties},

  author       = {Allen, Marshall J. and Sujanani, Rahul and Chamseddine, Alyssa and Freeman, Benny D. and Page, Zachariah A.},

  abstractNote = {Abstract Water swollen polymer networks are attractive for applications ranging from tissue regeneration to water purification. For water purification, charged polymers provide excellent ion separation properties. However, many ion exchange membranes (IEMs) are brittle, necessitating the use of thick support materials that ultimately decrease throughput. To this end, novel double network hydrogels (DNHs) with variable water content are prepared and characterized in terms of mechanical and ion transport properties to evaluate their potential utility as tough membrane materials. The first network contains fixed anionic charges, while the other is comprised of a copolymer with varied ratios of hydrophobic ethyl acrylate (EA) and hydrophilic dimethyl acrylamide (DMA) repeat units. Characterization of freestanding DNH films reveals a reduction in water content from 88 to 53 wt% and a simultaneous increase in ultimate stress and strain by ~3.5× and ~4.5×, respectively, for 95%/5% EA/DMA, relative to 100% DMA. Fundamental salt transport properties relevant to water purification, including permeability, solubility, and diffusivity, are measured and systematically compared with conventional membrane materials to inform the development of DNHs for membrane applications. The ability to simultaneously reduce water content and increase mechanical integrity highlights the potential of DNHs as a synthetic platform for future membrane applications.},

  doi          = {10.1002/pol.20210260},

  journal      = {Journal of Polymer Science},

  number       = 21,

  volume       = 59,

  place        = {United States},

  year         = {Mon Jul 26 00:00:00 EDT 2021},

  month        = {Mon Jul 26 00:00:00 EDT 2021}

}

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Works referenced in this record:

Mechanical properties of Nafion™ electrolyte membranes under hydrated conditions
journal, November 2005

Kundu, Sumit; Simon, Leonardo C.; Fowler, Michael
Polymer, Vol. 46, Issue 25, p. 11707-11715
DOI: 10.1016/j.polymer.2005.09.059

Engineering of Tough Double Network Hydrogels
journal, April 2016

Chen, Qiang; Chen, Hong; Zhu, Lin
Macromolecular Chemistry and Physics, Vol. 217, Issue 9
DOI: 10.1002/macp.201600038

Fundamental salt and water transport properties in directly copolymerized disulfonated poly(arylene ether sulfone) random copolymers
journal, April 2011

Xie, Wei; Cook, Joe; Park, Ho Bum
Polymer, Vol. 52, Issue 9
DOI: 10.1016/j.polymer.2011.02.006

Fabrication of Tough and Stretchable Hybrid Double-Network Elastomers Using Ionic Dissociation of Polyelectrolyte in Nonaqueous Media
journal, April 2019

Matsuda, Takahiro; Nakajima, Tasuku; Gong, Jian Ping
Chemistry of Materials, Vol. 31, Issue 10
DOI: 10.1021/acs.chemmater.9b00871

Proton exchange membranes with cross-linked interpenetrating network of sulfonated polyvinyl alcohol and poly(2-acrylamido-2-methyl-1-propanesulfonic acid): Excellent relative selectivity
journal, February 2020

Li, Hai Qiang; Liu, Xue Jiao; Wang, Hui
Journal of Membrane Science, Vol. 595
DOI: 10.1016/j.memsci.2019.117511

Application of a novel PUB enhanced semi‐interpenetrating chitosan‐based anion exchange membrane
journal, December 2019

Zhou, Tianchi; Cai, Lu; Qiao, Jinli
International Journal of Energy Research, Vol. 44, Issue 3
DOI: 10.1002/er.4972

Design and applications of interpenetrating polymer network hydrogels. A review
journal, May 2014

Dragan, Ecaterina Stela
Chemical Engineering Journal, Vol. 243
DOI: 10.1016/j.cej.2014.01.065

Ionomeric membranes for proton exchange membrane fuel cell (PEMFC): sulfonated polysulfone associated with phosphatoantimonic acid
journal, April 2001

Genova-Dimitrova, P.; Baradie, B.; Foscallo, D.
Journal of Membrane Science, Vol. 185, Issue 1
DOI: 10.1016/S0376-7388(00)00634-7

Toughening Elastomers with Sacrificial Bonds and Watching Them Break
journal, April 2014

Ducrot, E.; Chen, Y.; Bulters, M.
Science, Vol. 344, Issue 6180
DOI: 10.1126/science.1248494

Double-Network Hydrogels with Extremely High Mechanical Strength
journal, July 2003

Gong, J. P.; Katsuyama, Y.; Kurokawa, T.
Advanced Materials, Vol. 15, Issue 14
DOI: 10.1002/adma.200304907

Hydrogen bond-reinforced double-network hydrogels with ultrahigh elastic modulus and shape memory property: COMMUNICATIONS
journal, May 2018

Wang, Yan Jie; Li, Chen Yu; Wang, Zhi Jian
Journal of Polymer Science Part B: Polymer Physics, Vol. 56, Issue 19
DOI: 10.1002/polb.24620

Toughening of Epoxy Systems with Interpenetrating Polymer Network (IPN): A Review
journal, August 2020

Farooq, Ujala; Teuwen, Julie; Dransfeld, Clemens
Polymers, Vol. 12, Issue 9
DOI: 10.3390/polym12091908

Mechanically Tough and Chemically Stable Anion Exchange Membranes from Rigid-Flexible Semi-Interpenetrating Networks
journal, September 2015

Pan, Jing; Zhu, Liang; Han, Juanjuan
Chemistry of Materials, Vol. 27, Issue 19
DOI: 10.1021/acs.chemmater.5b02557

Tough, Swelling-Resistant, Self-Healing, and Adhesive Dual-Cross-Linked Hydrogels Based on Polymer–Tannic Acid Multiple Hydrogen Bonds
journal, February 2018

Fan, Hailong; Wang, Jiahui; Jin, Zhaoxia
Macromolecules, Vol. 51, Issue 5
DOI: 10.1021/acs.macromol.7b02653

Predicting Salt Permeability Coefficients in Highly Swollen, Highly Charged Ion Exchange Membranes
journal, January 2017

Kamcev, Jovan; Paul, Donald R.; Manning, Gerald S.
ACS Applied Materials & Interfaces, Vol. 9, Issue 4
DOI: 10.1021/acsami.6b14902

Tough Double Network Hydrogel and Its Biomedical Applications
journal, June 2021

Nonoyama, Takayuki; Gong, Jian Ping
Annual Review of Chemical and Biomolecular Engineering, Vol. 12, Issue 1
DOI: 10.1146/annurev-chembioeng-101220-080338

Double Network Hydrogels that Mimic the Modulus, Strength, and Lubricity of Cartilage
journal, April 2019

Means, A. Kristen; Shrode, Courtney S.; Whitney, Lauren V.
Biomacromolecules, Vol. 20, Issue 5
DOI: 10.1021/acs.biomac.9b00237

Rapid reprogramming of tumour cells into cancer stem cells on double-network hydrogels
journal, March 2021

Suzuka, Jun; Tsuda, Masumi; Wang, Lei
Nature Biomedical Engineering, Vol. 5, Issue 8
DOI: 10.1038/s41551-021-00692-2

Physically Cross-Linked Double-Network Hydrogel for High-Performance Oil–Water Separation Mesh
journal, October 2019

Liu, Yong; Xia, Meng; Wu, Lili
Industrial & Engineering Chemistry Research, Vol. 58, Issue 47
DOI: 10.1021/acs.iecr.9b03747

Swelling of polyelectrolyte networks
journal, April 2005

Mann, Bernward A.; Holm, Christian; Kremer, Kurt
The Journal of Chemical Physics, Vol. 122, Issue 15
DOI: 10.1063/1.1882275

Double network hydrogel of sodium alginate/polyacrylamide cross-linked with POSS: Swelling, dye removal and mechanical properties
journal, May 2019

Bahrami, Zahra; Akbari, Ali; Eftekhari-Sis, Bagher
International Journal of Biological Macromolecules, Vol. 129
DOI: 10.1016/j.ijbiomac.2019.02.046

Amino-functionalized alginate/graphene double-network hydrogel beads for emerging contaminant removal from aqueous solution
journal, February 2020

Sun, Yiran; Zhou, Tao; Li, Weiying
Chemosphere, Vol. 241
DOI: 10.1016/j.chemosphere.2019.125110

Biomedical Applications of Interpenetrating Polymer Network System
journal, October 2015

Qadri, Mohd Fuzail; Malviya, Rishabha; Sharma, Pramod Kumar
Open Pharmaceutical Sciences Journal, Vol. 2, Issue 1
DOI: 10.2174/1874844901502010021

Water purification by membranes: The role of polymer science
journal, June 2010

Geise, Geoffrey M.; Lee, Hae-Seung; Miller, Daniel J.
Journal of Polymer Science Part B: Polymer Physics, Vol. 48, Issue 15
DOI: 10.1002/polb.22037

Synthesis of cation exchange membranes based on sulfonated polyether sulfone with different sulfonation degrees
journal, October 2018

Zhao, Jinli; Guo, Lin; Wang, Jianyou
Journal of Membrane Science, Vol. 563
DOI: 10.1016/j.memsci.2018.05.023

Efficient Removal of Heavy Metal Ions with An EDTA Functionalized Chitosan/Polyacrylamide Double Network Hydrogel
journal, December 2016

Ma, Jianhong; Zhou, Guiyin; Chu, Lin
ACS Sustainable Chemistry & Engineering, Vol. 5, Issue 1
DOI: 10.1021/acssuschemeng.6b02181

UV-mediated synthesis of pNIPAM-crosslinked double-network alginate hydrogels: Enhanced mechanical and shape-memory properties by metal ions and temperature
journal, August 2018

Choi, Eun Jung; Ha, Seonggyun; Lee, Jookyeong
Polymer, Vol. 149
DOI: 10.1016/j.polymer.2018.06.080

Super tough double network hydrogels and their application as biomaterials
journal, April 2012

Haque, Md. Anamul; Kurokawa, Takayuki; Gong, Jian Ping
Polymer, Vol. 53, Issue 9
DOI: 10.1016/j.polymer.2012.03.013

Anion Exchange Membranes with Dynamic Redox-Responsive Properties
journal, July 2019

Capparelli, Clara; Fernandez Pulido, Carlos R.; Lopez-Hallman, Raymond
ACS Applied Materials & Interfaces, Vol. 11, Issue 32
DOI: 10.1021/acsami.9b04622

Why are double network hydrogels so tough?
journal, January 2010

Gong, Jian Ping
Soft Matter, Vol. 6, Issue 12
DOI: 10.1039/b924290b

Water Treatment: Are Membranes the Panacea?
journal, June 2020

Landsman, Matthew R.; Sujanani, Rahul; Brodfuehrer, Samuel H.
Annual Review of Chemical and Biomolecular Engineering, Vol. 11, Issue 1
DOI: 10.1146/annurev-chembioeng-111919-091940

Characterization of sodium chloride and water transport in crosslinked poly(ethylene oxide) hydrogels
journal, August 2010

Ju, Hao; Sagle, Alyson C.; Freeman, Benny D.
Journal of Membrane Science, Vol. 358, Issue 1-2
DOI: 10.1016/j.memsci.2010.04.035

Interpenetrating polymer networks: So happy together?
journal, October 2020

Silverstein, Michael S.
Polymer, Vol. 207
DOI: 10.1016/j.polymer.2020.122929

Mechanically robust semi-interpenetrating polymer network via thiol-ene chemistry with enhanced conductivity for anion exchange membranes
journal, March 2021

Yang, Weihong; Xu, Peng; Li, Xuezhuang
International Journal of Hydrogen Energy, Vol. 46, Issue 17
DOI: 10.1016/j.ijhydene.2020.12.145

Double network hydrophobic starch based amphoteric hydrogel as an effective adsorbent for both cationic and anionic dyes
journal, August 2020

Sarmah, Dimpee; Karak, Niranjan
Carbohydrate Polymers, Vol. 242
DOI: 10.1016/j.carbpol.2020.116320

New amphiphilic semi-interpenetrating networks based on polysulfone for anion-exchange membrane fuel cells with improved alkaline and mechanical stabilities
journal, June 2021

Ureña, Nieves; Pérez-Prior, María Teresa; Rio, Carmen del
Polymer, Vol. 226
DOI: 10.1016/j.polymer.2021.123824

Removal of Al(III) Ions Using Gellan Gum-Acrylic Acid Double Network Hydrogel
journal, December 2019

Özkahraman, Bengi; Özbaş, Zehra
Journal of Polymers and the Environment, Vol. 28, Issue 2
DOI: 10.1007/s10924-019-01636-3

Semi-Interpenetrating Network-Type Cross-Linked Amphoteric Ion-Exchange Membrane Based on Styrene Sulfonate and Vinyl Benzyl Chloride for Vanadium Redox Flow Battery
journal, August 2018

Sharma, Prem P.; Paul, Anirban; Srivastava, Divesh N.
ACS Omega, Vol. 3, Issue 8
DOI: 10.1021/acsomega.8b01215

Anion Exchange Membrane Based on Interpenetrating Polymer Network with Ultrahigh Ion Conductivity and Excellent Stability for Alkaline Fuel Cell
journal, May 2020

Zeng, Lingping; He, Qian; Liao, Yunchuan
Research, Vol. 2020
DOI: 10.34133/2020/4794706

Nanocomposite Anion Exchange Membranes with a Conductive Semi-Interpenetrating Silica Network
journal, April 2021

Sgreccia, Emanuela; Di Vona, Maria; Antonaroli, Simonetta
Membranes, Vol. 11, Issue 4
DOI: 10.3390/membranes11040260

Influence of water content on alkali metal chloride transport in cross-linked Poly(ethylene glycol) Diacrylate.1. Ion sorption
journal, September 2019

Jang, Eui-Soung; Kamcev, Jovan; Kobayashi, Kentaro
Polymer, Vol. 178
DOI: 10.1016/j.polymer.2019.121554

Ion exchange membranes: New developments and applications
journal, January 2017

Ran, Jin; Wu, Liang; He, Yubin
Journal of Membrane Science, Vol. 522
DOI: 10.1016/j.memsci.2016.09.033

Transport of Neutral and Charged Solutes in Imidazolium-Functionalized Poly(phenylene oxide) Membranes for Artificial Photosynthesis
journal, December 2019

Dischinger, Sarah M.; Gupta, Shubham; Carter, Blaine M.
Industrial & Engineering Chemistry Research, Vol. 59, Issue 12
DOI: 10.1021/acs.iecr.9b05628

Charged Polymer Membranes for Environmental/Energy Applications
journal, June 2016

Kamcev, Jovan; Freeman, Benny D.
Annual Review of Chemical and Biomolecular Engineering, Vol. 7, Issue 1
DOI: 10.1146/annurev-chembioeng-080615-033533

Viscoelastic properties of Nafion at elevated temperature and humidity: Stress Relaxation of Nafion
journal, November 2008

Satterfield, M. Barclay; Benziger, Jay B.
Journal of Polymer Science Part B: Polymer Physics, Vol. 47, Issue 1
DOI: 10.1002/polb.21608

Fundamental water and salt transport properties of polymeric materials
journal, January 2014

Geise, Geoffrey M.; Paul, Donald R.; Freeman, Benny D.
Progress in Polymer Science, Vol. 39, Issue 1
DOI: 10.1016/j.progpolymsci.2013.07.001

Facile fabrication of amphoteric semi-interpenetrating network ion-exchange membranes for electrodialysis applications
journal, July 2019

Liao, Junbin; Gao, Xing; Chen, Quan
Ionics, Vol. 26, Issue 1
DOI: 10.1007/s11581-019-03165-4

Ion Activity Coefficients in Ion Exchange Polymers: Applicability of Manning’s Counterion Condensation Theory
journal, October 2015

Kamcev, Jovan; Paul, Donald R.; Freeman, Benny D.
Macromolecules, Vol. 48, Issue 21
DOI: 10.1021/acs.macromol.5b01654

Fundamentals of double network hydrogels
journal, January 2015

Chen, Qiang; Chen, Hong; Zhu, Lin
Journal of Materials Chemistry B, Vol. 3, Issue 18
DOI: 10.1039/C5TB00123D

Permeability of solutes through hydrated polymer membranes. Part I. Diffusion of sodium chloride
journal, November 1968

Yasuda, H.; Lamaze, C. E.; Ikenberry, L. D.
Die Makromolekulare Chemie, Vol. 118, Issue 1, p. 19-35
DOI: 10.1002/macp.1968.021180102

Reformulation of the solution-diffusion theory of reverse osmosis
journal, October 2004

Paul, D.
Journal of Membrane Science, Vol. 241, Issue 2
DOI: 10.1016/j.memsci.2004.05.026

Semi-interpenetrating polymer networks by azide–alkyne cycloaddition as novel anion exchange membranes
journal, January 2018

Xue, Jiandang; Liu, Lei; Liao, Jiayou
Journal of Materials Chemistry A, Vol. 6, Issue 24
DOI: 10.1039/C8TA02177E

Rice husk derived double network hydrogel as efficient adsorbent for Pb(II), Cu(II) and Cd(II) removal in individual and multicomponent systems
journal, October 2019

Ma, Jianhong; Li, Tong; Liu, Yutang
Bioresource Technology, Vol. 290
DOI: 10.1016/j.biortech.2019.121793

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Title: Mechanically robust hydrophobized double network hydrogels and their fundamental salt transport properties

Abstract

Citation Formats

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Fundamental salt and water transport properties in directly copolymerized disulfonated poly(arylene ether sulfone) random copolymers journal, April 2011

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Reformulation of the solution-diffusion theory of reverse osmosis journal, October 2004

Semi-interpenetrating polymer networks by azide–alkyne cycloaddition as novel anion exchange membranes journal, January 2018

Rice husk derived double network hydrogel as efficient adsorbent for Pb(II), Cu(II) and Cd(II) removal in individual and multicomponent systems journal, October 2019

Mechanical properties of Nafion™ electrolyte membranes under hydrated conditions
journal, November 2005

Engineering of Tough Double Network Hydrogels
journal, April 2016

Fundamental salt and water transport properties in directly copolymerized disulfonated poly(arylene ether sulfone) random copolymers
journal, April 2011

Fabrication of Tough and Stretchable Hybrid Double-Network Elastomers Using Ionic Dissociation of Polyelectrolyte in Nonaqueous Media
journal, April 2019

Proton exchange membranes with cross-linked interpenetrating network of sulfonated polyvinyl alcohol and poly(2-acrylamido-2-methyl-1-propanesulfonic acid): Excellent relative selectivity
journal, February 2020

Application of a novel PUB enhanced semi‐interpenetrating chitosan‐based anion exchange membrane
journal, December 2019

Design and applications of interpenetrating polymer network hydrogels. A review
journal, May 2014

Ionomeric membranes for proton exchange membrane fuel cell (PEMFC): sulfonated polysulfone associated with phosphatoantimonic acid
journal, April 2001

Toughening Elastomers with Sacrificial Bonds and Watching Them Break
journal, April 2014

Double-Network Hydrogels with Extremely High Mechanical Strength
journal, July 2003

Hydrogen bond-reinforced double-network hydrogels with ultrahigh elastic modulus and shape memory property: COMMUNICATIONS
journal, May 2018

Toughening of Epoxy Systems with Interpenetrating Polymer Network (IPN): A Review
journal, August 2020

Mechanically Tough and Chemically Stable Anion Exchange Membranes from Rigid-Flexible Semi-Interpenetrating Networks
journal, September 2015

Tough, Swelling-Resistant, Self-Healing, and Adhesive Dual-Cross-Linked Hydrogels Based on Polymer–Tannic Acid Multiple Hydrogen Bonds
journal, February 2018

Predicting Salt Permeability Coefficients in Highly Swollen, Highly Charged Ion Exchange Membranes
journal, January 2017

Tough Double Network Hydrogel and Its Biomedical Applications
journal, June 2021

Double Network Hydrogels that Mimic the Modulus, Strength, and Lubricity of Cartilage
journal, April 2019

Rapid reprogramming of tumour cells into cancer stem cells on double-network hydrogels
journal, March 2021

Physically Cross-Linked Double-Network Hydrogel for High-Performance Oil–Water Separation Mesh
journal, October 2019

Swelling of polyelectrolyte networks
journal, April 2005

Double network hydrogel of sodium alginate/polyacrylamide cross-linked with POSS: Swelling, dye removal and mechanical properties
journal, May 2019

Amino-functionalized alginate/graphene double-network hydrogel beads for emerging contaminant removal from aqueous solution
journal, February 2020

Biomedical Applications of Interpenetrating Polymer Network System
journal, October 2015

Water purification by membranes: The role of polymer science
journal, June 2010

Synthesis of cation exchange membranes based on sulfonated polyether sulfone with different sulfonation degrees
journal, October 2018

Efficient Removal of Heavy Metal Ions with An EDTA Functionalized Chitosan/Polyacrylamide Double Network Hydrogel
journal, December 2016

UV-mediated synthesis of pNIPAM-crosslinked double-network alginate hydrogels: Enhanced mechanical and shape-memory properties by metal ions and temperature
journal, August 2018

Super tough double network hydrogels and their application as biomaterials
journal, April 2012

Anion Exchange Membranes with Dynamic Redox-Responsive Properties
journal, July 2019

Why are double network hydrogels so tough?
journal, January 2010

Water Treatment: Are Membranes the Panacea?
journal, June 2020

Characterization of sodium chloride and water transport in crosslinked poly(ethylene oxide) hydrogels
journal, August 2010

Interpenetrating polymer networks: So happy together?
journal, October 2020

Mechanically robust semi-interpenetrating polymer network via thiol-ene chemistry with enhanced conductivity for anion exchange membranes
journal, March 2021

Double network hydrophobic starch based amphoteric hydrogel as an effective adsorbent for both cationic and anionic dyes
journal, August 2020

New amphiphilic semi-interpenetrating networks based on polysulfone for anion-exchange membrane fuel cells with improved alkaline and mechanical stabilities
journal, June 2021

Removal of Al(III) Ions Using Gellan Gum-Acrylic Acid Double Network Hydrogel
journal, December 2019

Semi-Interpenetrating Network-Type Cross-Linked Amphoteric Ion-Exchange Membrane Based on Styrene Sulfonate and Vinyl Benzyl Chloride for Vanadium Redox Flow Battery
journal, August 2018

Anion Exchange Membrane Based on Interpenetrating Polymer Network with Ultrahigh Ion Conductivity and Excellent Stability for Alkaline Fuel Cell
journal, May 2020

Nanocomposite Anion Exchange Membranes with a Conductive Semi-Interpenetrating Silica Network
journal, April 2021

Influence of water content on alkali metal chloride transport in cross-linked Poly(ethylene glycol) Diacrylate.1. Ion sorption
journal, September 2019

Ion exchange membranes: New developments and applications
journal, January 2017

Transport of Neutral and Charged Solutes in Imidazolium-Functionalized Poly(phenylene oxide) Membranes for Artificial Photosynthesis
journal, December 2019

Charged Polymer Membranes for Environmental/Energy Applications
journal, June 2016

Viscoelastic properties of Nafion at elevated temperature and humidity: Stress Relaxation of Nafion
journal, November 2008

Fundamental water and salt transport properties of polymeric materials
journal, January 2014

Facile fabrication of amphoteric semi-interpenetrating network ion-exchange membranes for electrodialysis applications
journal, July 2019

Ion Activity Coefficients in Ion Exchange Polymers: Applicability of Manning’s Counterion Condensation Theory
journal, October 2015

Fundamentals of double network hydrogels
journal, January 2015

Permeability of solutes through hydrated polymer membranes. Part I. Diffusion of sodium chloride
journal, November 1968

Reformulation of the solution-diffusion theory of reverse osmosis
journal, October 2004

Semi-interpenetrating polymer networks by azide–alkyne cycloaddition as novel anion exchange membranes
journal, January 2018

Rice husk derived double network hydrogel as efficient adsorbent for Pb(II), Cu(II) and Cd(II) removal in individual and multicomponent systems
journal, October 2019