Fast and Scalable Synthesis of LiNi0.5Mn1.5O4 Cathode by Sol–Gel-Assisted Microwave Sintering
Abstract
High-voltage spinel LiNi0.5Mn1.5O4 (LNMO) is a promising cathode material for high-energy-density and high-power-density lithium-ion batteries (LIBs). The high cost of the currently available LIBs needs to be addressed urgently for wide application in the transport sector (electric vehicles, buses) and large-scale energy storage systems (ESS). Of significance, herein, novel fast and scalable microwave-assisted synthesis of LNMO is reported, which leads to a production cost cut. X-ray diffraction (XRD) analysis confirms the formation of the desired phase with high crystallinity. Field emission scanning (FE-SEM) and transmission electron microscopy (TEM) analyses indicate that the synthesized phase is of nanometric size (50–150 nm) due to an extremely short sintering time (20 min). The material synthesized at 750 °C shows a higher initial discharge capacity (130 mA h g-1) than that synthesized at 650 °C (115 mA h g-1). The materials heat treated at higher temperatures show better electrochemical performance in terms of initial capacity, rate capability, and improved cycling. The improved electrochemical performance of LNMO at 750 °C is attributed to the formation of a stable crystal structure, low charge transfer resistance at the electrode/electrolyte interface, high electrical conductivity due to the presence of a disorder structure, and improved ionic diffusivity.
- Authors:
-
- Qatar Univ., Doha (Qatar). Center for Advanced Materials (CAM)
- Hamad Bin Khalifa University, Qatar Foundation, Doha (Qatar). Qatar Environment and Energy Research Institute
- Qatar Univ., Doha (Qatar)
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Publication Date:
- Research Org.:
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE; Qatar University
- OSTI Identifier:
- 1808174
- Grant/Contract Number:
- AC05-00OR22725; NPRP11S-1225-170128
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Energy Technology
- Additional Journal Information:
- Journal Volume: 9; Journal Issue: 7; Journal ID: ISSN 2194-4288
- Publisher:
- Wiley
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; crystal structures; high-voltage spinel; LiNi0.5Mn1.5O4; lithium-ion batteries; microwave sintering
Citation Formats
Nisar, Umair, Al-Hail, Sara A., Kumar, Petla Ramesh, Abraham, Jeffin James, Mesallam, Saoud A., Shakoor, Rana Abdul, Amin, Ruhul, Essehli, Rachid, and Al-Qaradawi, Siham. Fast and Scalable Synthesis of LiNi0.5Mn1.5O4 Cathode by Sol–Gel-Assisted Microwave Sintering. United States: N. p., 2021.
Web. doi:10.1002/ente.202100085.
Nisar, Umair, Al-Hail, Sara A., Kumar, Petla Ramesh, Abraham, Jeffin James, Mesallam, Saoud A., Shakoor, Rana Abdul, Amin, Ruhul, Essehli, Rachid, & Al-Qaradawi, Siham. Fast and Scalable Synthesis of LiNi0.5Mn1.5O4 Cathode by Sol–Gel-Assisted Microwave Sintering. United States. https://doi.org/10.1002/ente.202100085
Nisar, Umair, Al-Hail, Sara A., Kumar, Petla Ramesh, Abraham, Jeffin James, Mesallam, Saoud A., Shakoor, Rana Abdul, Amin, Ruhul, Essehli, Rachid, and Al-Qaradawi, Siham. Tue .
"Fast and Scalable Synthesis of LiNi0.5Mn1.5O4 Cathode by Sol–Gel-Assisted Microwave Sintering". United States. https://doi.org/10.1002/ente.202100085. https://www.osti.gov/servlets/purl/1808174.
@article{osti_1808174,
title = {Fast and Scalable Synthesis of LiNi0.5Mn1.5O4 Cathode by Sol–Gel-Assisted Microwave Sintering},
author = {Nisar, Umair and Al-Hail, Sara A. and Kumar, Petla Ramesh and Abraham, Jeffin James and Mesallam, Saoud A. and Shakoor, Rana Abdul and Amin, Ruhul and Essehli, Rachid and Al-Qaradawi, Siham},
abstractNote = {High-voltage spinel LiNi0.5Mn1.5O4 (LNMO) is a promising cathode material for high-energy-density and high-power-density lithium-ion batteries (LIBs). The high cost of the currently available LIBs needs to be addressed urgently for wide application in the transport sector (electric vehicles, buses) and large-scale energy storage systems (ESS). Of significance, herein, novel fast and scalable microwave-assisted synthesis of LNMO is reported, which leads to a production cost cut. X-ray diffraction (XRD) analysis confirms the formation of the desired phase with high crystallinity. Field emission scanning (FE-SEM) and transmission electron microscopy (TEM) analyses indicate that the synthesized phase is of nanometric size (50–150 nm) due to an extremely short sintering time (20 min). The material synthesized at 750 °C shows a higher initial discharge capacity (130 mA h g-1) than that synthesized at 650 °C (115 mA h g-1). The materials heat treated at higher temperatures show better electrochemical performance in terms of initial capacity, rate capability, and improved cycling. The improved electrochemical performance of LNMO at 750 °C is attributed to the formation of a stable crystal structure, low charge transfer resistance at the electrode/electrolyte interface, high electrical conductivity due to the presence of a disorder structure, and improved ionic diffusivity.},
doi = {10.1002/ente.202100085},
journal = {Energy Technology},
number = 7,
volume = 9,
place = {United States},
year = {Tue Apr 13 00:00:00 EDT 2021},
month = {Tue Apr 13 00:00:00 EDT 2021}
}
Works referenced in this record:
Microwave Solid-State Synthesis of LiV 3 O 8 as Cathode Material for Lithium Batteries
journal, June 2005
- Yang, Gang; Wang, Guan; Hou, Wenhua
- The Journal of Physical Chemistry B, Vol. 109, Issue 22
Solid state synthesis of extra phase-pure Li4Ti5O12 spinel
journal, January 2011
- Veljkovic, I.; Poleti, D.; Karanovic, Lj.
- Science of Sintering, Vol. 43, Issue 3
Growth mechanism of Ni0.3Mn0.7CO3 precursor for high capacity Li-ion battery cathodes
journal, January 2011
- Wang, Dapeng; Belharouak, Ilias; Koenig, Gary M.
- Journal of Materials Chemistry, Vol. 21, Issue 25
Improvement of electrochemical properties of LiNi1/3Co1/3Mn1/3O2 by coating with V2O5 layer
journal, March 2013
- Liu, Xizheng; He, Ping; Li, Huiqiao
- Journal of Alloys and Compounds, Vol. 552
Ultrathin Spinel LiMn 2 O 4 Nanowires as High Power Cathode Materials for Li-Ion Batteries
journal, October 2010
- Lee, Hyun-Wook; Muralidharan, P.; Ruffo, Riccardo
- Nano Letters, Vol. 10, Issue 10
Enhanced storage property of LiNi0.8Co0.15Al0.05O2 coated with LiCoO2
journal, May 2013
- Liu, Wanmin; Hu, Guorong; Du, Ke
- Journal of Power Sources, Vol. 230
Effects of Metal Ions on the Structural and Thermal Stabilities of Li[Ni[sub 1−x−y]Co[sub x]Mn[sub y]]O[sub 2] (x+y≤0.5) Studied by In Situ High Temperature XRD
journal, January 2008
- Bang, Hyunjoo; Kim, Dong-Hui; Bae, Young Chan
- Journal of The Electrochemical Society, Vol. 155, Issue 12
The Impedance Response of a Porous Electrode Composed of Intercalation Particles
journal, January 2000
- Meyers, Jeremy P.; Doyle, Marc; Darling, Robert M.
- Journal of The Electrochemical Society, Vol. 147, Issue 8
LiNi0.8Co0.15Al0.05O2 cathode materials prepared by TiO2 nanoparticle coatings on Ni0.8Co0.15Al0.05(OH)2 precursors
journal, December 2010
- Cho, Younghyun; Lee, Yong-Seok; Park, Seul-A.
- Electrochimica Acta, Vol. 56, Issue 1
Development and challenges of LiFePO 4 cathode material for lithium-ion batteries
journal, January 2011
- Yuan, Li-Xia; Wang, Zhao-Hui; Zhang, Wu-Xing
- Energy Environ. Sci., Vol. 4, Issue 2
Li-ion battery materials: present and future
journal, June 2015
- Nitta, Naoki; Wu, Feixiang; Lee, Jung Tae
- Materials Today, Vol. 18, Issue 5
Microwave rapid preparation of LiNi0.5Mn1.5O4 and the improved high rate performance for lithium-ion batteries
journal, June 2013
- Gao, Po; Wang, Lu; Chen, Lin
- Electrochimica Acta, Vol. 100
Extreme fast charging characteristics of zirconia modified LiNi0.5Mn1.5O4 cathode for lithium ion batteries
journal, August 2018
- Nisar, Umair; Amin, Ruhul; Essehli, Rachid
- Journal of Power Sources, Vol. 396
Simplified co-precipitation synthesis of spinel LiNi0.5Mn1.5O4 with improved physical and electrochemical performance
journal, June 2014
- Zhang, Minghao; Liu, Yuanzhuang; Xia, Yonggao
- Journal of Alloys and Compounds, Vol. 598
Improvement of electrochemical properties of layered LiNi1/3Co1/3Mn1/3O2 positive electrode material by zirconium doping
journal, May 2011
- Ding, C. X.; Bai, Y. C.; Feng, X. Y.
- Solid State Ionics, Vol. 189, Issue 1
Impact of surface coating on electrochemical and thermal behaviors of a Li-rich Li 1.2 Ni 0.16 Mn 0.56 Co 0.08 O 2 cathode
journal, January 2020
- Nisar, Umair; Petla, Ramesh; Jassim Al-Hail, Sara Ahmad
- RSC Advances, Vol. 10, Issue 26
The effect of thermal stability for high-Ni-content layer-structured cathode materials, LiNi0.8Mn0.1−xCo0.1MoxO2 (x = 0, 0.02, 0.04)
journal, December 2013
- Konishi, Hiroaki; Yoshikawa, Masanori; Hirano, Tatsumi
- Journal of Power Sources, Vol. 244
Improved Li-ion diffusion and stability of a LiNi 0.5 Mn 1.5 O 4 cathode through in situ co-doping with dual-metal cations and incorporation of a superionic conductor
journal, January 2017
- Liu, Weijie; Shi, Qiang; Qu, Qunting
- Journal of Materials Chemistry A, Vol. 5, Issue 1
Review of 5-V electrodes for Li-ion batteries: status and trends
journal, May 2013
- Julien, C. M.; Mauger, A.
- Ionics, Vol. 19, Issue 7
Role of zirconium dopant on the structure and high voltage electrochemical performances of LiNi 0.5 Co 0.2 Mn 0.3 O 2 cathode materials for lithium ion batteries
journal, January 2016
- Wang, Ding; Li, Xinhai; Wang, Zhixing
- Electrochimica Acta, Vol. 188
Abundant nanoscale defects to eliminate voltage decay in Li-rich cathode materials
journal, January 2019
- Guo, Haocheng; Wei, Zhen; Jia, Kai
- Energy Storage Materials, Vol. 16
Prospective materials and applications for Li secondary batteries
journal, January 2011
- Jeong, Goojin; Kim, Young-Ugk; Kim, Hansu
- Energy & Environmental Science, Vol. 4, Issue 6
Microwave Synthesis of Spherical Li[Ni 0.4 Co 0.2 Mn 0.4 ]O 2 Powders as a Positive Electrode Material for Lithium Batteries
journal, May 2007
- Lee, Ki-Soo; Myung, Seung-Taek; Sun, Yang-Kook
- Chemistry of Materials, Vol. 19, Issue 11
Lithium-Ion-Transfer Kinetics of Single LiFePO 4 Particles
journal, August 2018
- Xu, Wei; Zhou, Yige; Ji, Xiaobo
- The Journal of Physical Chemistry Letters, Vol. 9, Issue 17
Na4MnV(PO4)3-rGO as Advanced cathode for aqueous and non-aqueous sodium ion batteries
journal, July 2019
- Ramesh Kumar, P.; Kheireddine, Aziz; Nisar, Umair
- Journal of Power Sources, Vol. 429
Part-II: Exchange current density and ionic diffusivity studies on the ordered and disordered spinel LiNi 0.5 Mn 1.5 O 4 cathode
journal, April 2017
- Amin, Ruhul; Belharouak, Ilias
- Journal of Power Sources, Vol. 348
Part I: Electronic and ionic transport properties of the ordered and disordered LiNi0.5Mn1.5O4 spinel cathode
journal, April 2017
- Amin, Ruhul; Belharouk, Ilias
- Journal of Power Sources, Vol. 348
High-Voltage LiNi 0.5 Mn 1.5 O 4- δ Spinel Material Synthesized by Microwave-Assisted Thermo-Polymerization: Some Insights into the Microwave-Enhancing Physico-Chemistry
journal, January 2017
- Kebede, Mesfin A.; Yannopoulos, Spyros N.; Sygellou, Labrini
- Journal of The Electrochemical Society, Vol. 164, Issue 13
Full microwave synthesis of advanced Li-rich manganese based cathode material for lithium ion batteries
journal, January 2017
- Shi, Shaojun; Zhang, Saisai; Wu, Zhijun
- Journal of Power Sources, Vol. 337
Reversible spinel to rock salt transition in LiCoMnOδ by oxygen (de) intercalation
journal, January 2001
- Reeves, Nik; Kirk, Caroline A.; West, Anthony R.
- Journal of Materials Chemistry, Vol. 11, Issue 2
Key challenges in future Li-battery research
journal, July 2010
- Tarascon, J. -M.
- Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences, Vol. 368, Issue 1923
Appropriate proportion truncated octahedron LiNi0.5Mn1.5O4 with excellent electrochemical properties for lithium-ion batteries prepared by graphite-assisted calcination method
journal, September 2020
- Wei, Yuan; Tuo, Kuanyou; Wang, Peng
- Ionics, Vol. 26, Issue 12
Excellent stability of spinel LiMn 2 O 4 -based cathode materials for lithium-ion batteries
journal, September 2015
- Wang, Hong-Qiang; Lai, Fei-Yan; Li, Yu
- Electrochimica Acta, Vol. 177
Microwave synthesis of cathode material Li x Mn2O4 for lithium-ion battery
journal, December 2002
- Hua, Hao; Han-xing, Liu; Shi-xi, Ouyang
- Journal of Wuhan University of Technology-Mater. Sci. Ed., Vol. 17, Issue 4
A Brief Review of Layered Rock Salt Cathode Materials for Lithium Ion Batteries
journal, September 2013
- Tan, T. Q.; Soo, S. P.; Rahmat, A.
- Advanced Materials Research, Vol. 795
The effects of sodium additive on Li1.17Ni0.10Co0.10Mn0.63O2 for lithium ion batteries
journal, January 2015
- Han, Enshan; Jing, Qiming; Zhu, Lingzhi
- Journal of Alloys and Compounds, Vol. 618
Building better batteries
journal, February 2008
- Armand, M.; Tarascon, J.-M.
- Nature, Vol. 451, Issue 7179, p. 652-657
Surface and Interface Issues in Spinel LiNi 0.5 Mn 1.5 O 4 : Insights into a Potential Cathode Material for High Energy Density Lithium Ion Batteries
journal, May 2016
- Ma, Jun; Hu, Pu; Cui, Guanglei
- Chemistry of Materials, Vol. 28, Issue 11
Understanding the Degradation Mechanisms of LiNi 0.5 Co 0.2 Mn 0.3 O 2 Cathode Material in Lithium Ion Batteries
journal, August 2013
- Jung, Sung-Kyun; Gwon, Hyeokjo; Hong, Jihyun
- Advanced Energy Materials, Vol. 4, Issue 1
Cobalt-Free Nickel Rich Layered Oxide Cathodes for Lithium-Ion Batteries
journal, October 2013
- Sun, Yang-Kook; Lee, Dong-Ju; Lee, Yun Jung
- ACS Applied Materials & Interfaces, Vol. 5, Issue 21
Influence of synthesis conditions on electrochemical properties of high-voltage Li1.02Ni0.5Mn1.5O4 spinel cathode material
journal, September 2009
- Hwang, B. J.; Wu, Y. W.; Venkateswarlu, M.
- Journal of Power Sources, Vol. 193, Issue 2
Synthesis, structural and electrical properties of spinel LiNi0.5Mn1.5O4 synthesized by sol–gel method
journal, July 2016
- Lobo, Laurel Simon; Kumar, A. Ruban
- Journal of Sol-Gel Science and Technology, Vol. 80, Issue 3
Towards greener and more sustainable batteries for electrical energy storage
journal, November 2014
- Larcher, D.; Tarascon, J-M.
- Nature Chemistry, Vol. 7, Issue 1
Morphological Evolution of High-Voltage Spinel LiNi 0.5 Mn 1.5 O 4 Cathode Materials for Lithium-Ion Batteries: The Critical Effects of Surface Orientations and Particle Size
journal, February 2016
- Liu, Haidong; Wang, Jun; Zhang, Xiaofei
- ACS Applied Materials & Interfaces, Vol. 8, Issue 7
Synthesis of Lithium and Manganese-Rich Cathode Materials via an Oxalate Co-Precipitation Method
journal, January 2013
- Wang, Dapeng; Belharouak, Ilias; Zhou, Guangwen
- Journal of The Electrochemical Society, Vol. 160, Issue 5
Synthetic optimization of Li[Ni1/3Co1/3Mn1/3]O2 via co-precipitation
journal, December 2004
- Lee, M. -H.; Kang, Y. -J.; Myung, S. -T.
- Electrochimica Acta, Vol. 50, Issue 4
Spinel–rock salt transformation in LiCoMnO 4− δ
journal, January 2016
- Reeves-McLaren, Nik; Sharp, Joanne; Beltrán-Mir, Héctor
- Proceedings of the Royal Society A: Mathematical, Physical and Engineering Sciences, Vol. 472, Issue 2185
LaPO 4 -coated Li 1.2 Mn 0.56 Ni 0.16 Co 0.08 O 2 as a cathode material with enhanced coulombic efficiency and rate capability for lithium ion batteries
journal, January 2015
- Xie, Qingliang; Zhao, Chenhao; Hu, Zhibiao
- RSC Advances, Vol. 5, Issue 94
Tailoring interfacial architecture of high-voltage cathode with lithium difluoro(bisoxalato) phosphate for high energy density battery
journal, April 2020
- Zhao, Dongni; Wang, Jie; Lu, Hongli
- Journal of Power Sources, Vol. 456
Synthesis and electrochemical characterization of Cr-doped lithium-rich Li1.2Ni0.16Mn0.56Co0.08-xCrxO2 cathodes
journal, October 2018
- Nisar, Umair; Amin, Ruhul; Shakoor, Abdul
- Emergent Materials, Vol. 1, Issue 3-4
Synthesis and performance evaluation of nanostructured NaFe x Cr 1−X (SO 4 ) 2 cathode materials in sodium ion batteries (SIBs)
journal, January 2018
- Nisar, Umair; Gulied, Mona Hersi; Shakoor, R. A.
- RSC Advances, Vol. 8, Issue 57
Facile synthesis and electrochemical performance of ordered LiNi0.5Mn1.5O4 nanorods as a high power positive electrode for rechargeable Li-ion batteries
journal, December 2011
- Lee, Hyun-Wook; Muralidharan, P.; Mari, Claudio M.
- Journal of Power Sources, Vol. 196, Issue 24
Structural Changes and Thermal Stability of Charged LiNi x Mn y Co z O 2 Cathode Materials Studied by Combined In Situ Time-Resolved XRD and Mass Spectroscopy
journal, December 2014
- Bak, Seong-Min; Hu, Enyuan; Zhou, Yongning
- ACS Applied Materials & Interfaces, Vol. 6, Issue 24
Fabrication of high tap density LiFe 0.6 Mn 0.4 PO 4 /C microspheres by a double carbon coating–spray drying method for high rate lithium ion batteries
journal, January 2013
- Liu, Wen; Gao, Ping; Mi, Yingying
- J. Mater. Chem. A, Vol. 1, Issue 7