DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Synthesis and thermodynamics of uranium-incorporated α-Fe2O3 nanoparticles

; ; ; ; ; ;
Publication Date:
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
Grant/Contract Number:  
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Journal of Nuclear Materials
Additional Journal Information:
Journal Name: Journal of Nuclear Materials Journal Volume: 556 Journal Issue: C; Journal ID: ISSN 0022-3115
Country of Publication:

Citation Formats

Lam, Andy, Hyler, Forrest, Stagg, Olwen, Morris, Katherine, Shaw, Samuel, Velázquez, Jesús M., and Navrotsky, Alexandra. Synthesis and thermodynamics of uranium-incorporated α-Fe2O3 nanoparticles. Netherlands: N. p., 2021. Web. doi:10.1016/j.jnucmat.2021.153172.
Lam, Andy, Hyler, Forrest, Stagg, Olwen, Morris, Katherine, Shaw, Samuel, Velázquez, Jesús M., & Navrotsky, Alexandra. Synthesis and thermodynamics of uranium-incorporated α-Fe2O3 nanoparticles. Netherlands.
Lam, Andy, Hyler, Forrest, Stagg, Olwen, Morris, Katherine, Shaw, Samuel, Velázquez, Jesús M., and Navrotsky, Alexandra. Wed . "Synthesis and thermodynamics of uranium-incorporated α-Fe2O3 nanoparticles". Netherlands.
title = {Synthesis and thermodynamics of uranium-incorporated α-Fe2O3 nanoparticles},
author = {Lam, Andy and Hyler, Forrest and Stagg, Olwen and Morris, Katherine and Shaw, Samuel and Velázquez, Jesús M. and Navrotsky, Alexandra},
abstractNote = {},
doi = {10.1016/j.jnucmat.2021.153172},
journal = {Journal of Nuclear Materials},
number = C,
volume = 556,
place = {Netherlands},
year = {2021},
month = {12}

Works referenced in this record:

Review of the Scientific Understanding of Radioactive Waste at the U.S. DOE Hanford Site
journal, January 2018

  • Peterson, Reid A.; Buck, Edgar C.; Chun, Jaehun
  • Environmental Science & Technology, Vol. 52, Issue 2
  • DOI: 10.1021/acs.est.7b04077

Uranium co-precipitation with iron oxide minerals
journal, October 2002

  • Duff, Martine C.; Coughlin, Jessica Urbanik; Hunter, Douglas B.
  • Geochimica et Cosmochimica Acta, Vol. 66, Issue 20
  • DOI: 10.1016/S0016-7037(02)00953-5

Renal effects of uranium in drinking water.
journal, April 2002

  • Kurttio, Päivi; Auvinen, Anssi; Salonen, Laina
  • Environmental Health Perspectives, Vol. 110, Issue 4
  • DOI: 10.1289/ehp.02110337

Nanoscale Size Effects on Uranium(VI) Adsorption to Hematite
journal, March 2009

  • Zeng, Hui; Singh, Abhas; Basak, Soubir
  • Environmental Science & Technology, Vol. 43, Issue 5
  • DOI: 10.1021/es802334e

Continuous hydrothermal crystallization of α–Fe 2 O 3 and Co 3 O 4 nanoparticles
journal, February 2003

Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides
journal, September 1976

Challenges with vitrification of Hanford High-Level Waste (HLW) to borosilicate glass – An overview
journal, December 2019

Using Atom Dynamics to Map the Defect Structure Around an Impurity in Nano-Hematite
journal, November 2020

  • Ilton, Eugene S.; Kovarik, Libor; Nakouzi, Elias
  • The Journal of Physical Chemistry Letters, Vol. 11, Issue 24
  • DOI: 10.1021/acs.jpclett.0c02798

A Variation of the F-Test for Determining Statistical Relevance of Particular Parameters in EXAFS Fits
conference, January 2007

  • Downward, L.; Booth, C. H.; Lukens, W. W.
  • X-RAY ABSORPTION FINE STRUCTURE - XAFS13: 13th International Conference, AIP Conference Proceedings
  • DOI: 10.1063/1.2644450

Incorporation of Uranium into Hematite during Crystallization from Ferrihydrite
journal, March 2014

  • Marshall, Timothy A.; Morris, Katherine; Law, Gareth T. W.
  • Environmental Science & Technology, Vol. 48, Issue 7
  • DOI: 10.1021/es500212a

Synchrotron X-ray study of the electron density in α-Fe 2 O 3
journal, August 1994

  • Maslen, E. N.; Streltsov, V. A.; Streltsova, N. R.
  • Acta Crystallographica Section B Structural Science, Vol. 50, Issue 4
  • DOI: 10.1107/S0108768194002284

Change in Sorption Characteristics of Uranium during Crystallization of Amorphous Iron Minerals
journal, December 1997

  • Ohnuki, Toshihiko; Isobe, Hiroshi; Yanase, Nobuyuki
  • Journal of Nuclear Science and Technology, Vol. 34, Issue 12
  • DOI: 10.1080/18811248.1997.9733805

The application of iron-based technologies in uranium remediation: A review
journal, January 2017

Human exposure to uranium in groundwater
journal, March 2004

Reduction of U(VI) Incorporated in the Structure of Hematite
journal, August 2012

  • Ilton, Eugene S.; Pacheco, Juan S. Lezama; Bargar, John R.
  • Environmental Science & Technology, Vol. 46, Issue 17
  • DOI: 10.1021/es3015502

Removal of heavy metal ions by iron oxide coated sewage sludge
journal, February 2011

  • Phuengprasop, Thapanapong; Sittiwong, Jarinya; Unob, Fuangfa
  • Journal of Hazardous Materials, Vol. 186, Issue 1
  • DOI: 10.1016/j.jhazmat.2010.11.065

Thermodynamics and crystal chemistry of the hematite-corundum solid solution and the FeAlO 3 phase
journal, September 2002

  • Majzlan, J.; Navrotsky, A.; Evans, B. J.
  • Physics and Chemistry of Minerals, Vol. 29, Issue 8
  • DOI: 10.1007/s00269-002-0261-7

Iron Vacancies Accommodate Uranyl Incorporation into Hematite
journal, May 2018

  • McBriarty, Martin E.; Kerisit, Sebastien; Bylaska, Eric J.
  • Environmental Science & Technology, Vol. 52, Issue 11
  • DOI: 10.1021/acs.est.8b00297

The sorption of uranyl species on a hematite sol
journal, May 1985

  • Ho, C. H.; Doern, D. C.
  • Canadian Journal of Chemistry, Vol. 63, Issue 5
  • DOI: 10.1139/v85-186

Effects of radiation on the leach rates of vitrified radioactive waste
journal, June 1982

Removal of uranium (VI) from aqueous solution by adsorption of hematite
journal, February 2009

Uranium fate during crystallization of magnetite from ferrihydrite in conditions relevant to the disposal of radioactive waste
journal, November 2015

Nanophase Transition Metal Oxides Show Large Thermodynamically Driven Shifts in Oxidation-Reduction Equilibria
journal, October 2010

  • Navrotsky, Alexandra; Ma, Chengcheng; Lilova, Kristina
  • Science, Vol. 330, Issue 6001
  • DOI: 10.1126/science.1195875

Structural environments of incompatible elements in silicate glass/melt systems: II. UIV, UV, and UVI
journal, December 1992

Uranium(VI) adsorption to ferrihydrite: Application of a surface complexation model
journal, December 1994

The crystal structure of Liebigite, Ca2UO2(CO3)3�?11H2O
journal, January 1982

  • Mereiter, K.
  • TMPM Tschermaks Mineralogische und Petrographische Mitteilungen, Vol. 30, Issue 4
  • DOI: 10.1007/BF01087173

Enthalpy of Water Adsorption and Surface Enthalpy of Goethite (α-FeOOH) and Hematite (α-Fe 2 O 3 )
journal, February 2007

  • Mazeina, Lena; Navrotsky, Alexandra
  • Chemistry of Materials, Vol. 19, Issue 4
  • DOI: 10.1021/cm0623817