Nonlinear photocarrier dynamics and the role of shallow traps in mixed-halide mixed-cation hybrid perovskites

Valverde-Chávez, David A.; Rojas-Gatjens, Esteban; Williamson, Jacob; Jariwala, Sarthak; Shi, Yangwei; McCarthy, Declan P.; Barlow, Stephen; Marder, Seth R.; Ginger, David S.; Silva-Acuña, Carlos

doi:10.1039/D1TC01492G

Title: Nonlinear photocarrier dynamics and the role of shallow traps in mixed-halide mixed-cation hybrid perovskites

Journal Article · 07 July 2021 · Journal of Materials Chemistry C

DOI: https://doi.org/10.1039/D1TC01492G · OSTI ID:1806354

^[1];

^[2];

^[3]; Shi, Yangwei ^[4]; McCarthy, Declan P. ^[1];

^[1]; Marder, Seth R. ^[5]; Ginger, David S. ^[6];

^[7]

School of Chemistry and Biochemistry, Georgia Institute of Technology, Atlanta, USA
School of Physics, Georgia Institute of Technology, Atlanta, USA
Department of Chemistry, University of Washington, Seattle, USA, Department of Materials Science and Engineering
Department of Chemistry, University of Washington, Seattle, USA, Molecular Engineering & Sciences Institute
School of Chemistry and Biochemistry, Georgia Institute of Technology, Atlanta, USA, School of Materials Science and Engineering
Department of Chemistry, University of Washington, Seattle, USA
School of Chemistry and Biochemistry, Georgia Institute of Technology, Atlanta, USA, School of Physics

We examine the role of surface passivation on carrier trapping and nonlinear recombination dynamics in hybrid metal-halide perovskites by means of excitation correlation photoluminescence (ECPL) spectroscopy.

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Research Organization:: Georgia Inst. of Technology, Atlanta, GA (United States); Univ. of Colorado, Boulder, CO (United States); Univ. of Washington, Seattle, WA (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE)

Grant/Contract Number:: EE0008747

OSTI ID:: 1806354

Journal Information:: Journal of Materials Chemistry C, Journal Name: Journal of Materials Chemistry C Journal Issue: 26 Vol. 9; ISSN JMCCCX; ISSN 2050-7526

Publisher:: Royal Society of Chemistry (RSC)Copyright Statement

Country of Publication:: United Kingdom

Language:: English

References (54)

Temperature-Dependent Charge-Carrier Dynamics in CH ₃ NH ₃ PbI ₃ Perovskite Thin Films Milot, Rebecca L.; Eperon, Giles E.; Snaith, Henry J. Advanced Functional Materials, Vol. 25, Issue 39 https://doi.org/10.1002/adfm.201502340	journal	September 2015
Optical Gain of Lead Halide Perovskites Measured via the Variable Stripe Length Method: What We Can Learn and How to Avoid Pitfalls Alvarado‐Leaños, Ada Lili; Cortecchia, Daniele; Folpini, Giulia Advanced Optical Materials https://doi.org/10.1002/adom.202001773	journal	January 2021
Halide Perovskite Light‐Emitting Diode Technologies Ji, Kangyu; Anaya, Miguel; Abfalterer, Anna Advanced Optical Materials https://doi.org/10.1002/adom.202002128	journal	March 2021
Intrinsic Thermal Instability of Methylammonium Lead Trihalide Perovskite Conings, Bert; Drijkoningen, Jeroen; Gauquelin, Nicolas Advanced Energy Materials, Vol. 5, Issue 15 https://doi.org/10.1002/aenm.201500477	journal	June 2015
The Role of Grain Boundaries in Perovskite Solar Cells Castro‐Méndez, Andrés‐Felipe; Hidalgo, Juanita; Correa‐Baena, Juan‐Pablo Advanced Energy Materials, Vol. 9, Issue 38 https://doi.org/10.1002/aenm.201901489	journal	August 2019
Picosecond correlation effects in the hot luminescence of GaAs von der Linde, D.; Kuhl, J.; Rosengart, E. Journal of Luminescence, Vol. 24-25 https://doi.org/10.1016/0022-2313(81)90068-5	journal	November 1981
Oxidative Passivation of Metal Halide Perovskites Godding, Julian S. W.; Ramadan, Alexandra J.; Lin, Yen-Hung Joule, Vol. 3, Issue 11 https://doi.org/10.1016/j.joule.2019.08.006	journal	November 2019
Local Crystal Misorientation Influences Non-radiative Recombination in Halide Perovskites Jariwala, Sarthak; Sun, Hongyu; Adhyaksa, Gede W. P. Joule, Vol. 3, Issue 12 https://doi.org/10.1016/j.joule.2019.09.001	journal	December 2019
Shallow Iodine Defects Accelerate the Degradation of α-Phase Formamidinium Perovskite Tan, Shaun; Yavuz, Ilhan; Weber, Marc H. Joule, Vol. 4, Issue 11 https://doi.org/10.1016/j.joule.2020.08.016	journal	November 2020
Revealing the internal luminescence quantum efficiency of perovskite films via accurate quantification of photon recycling Fassl, Paul; Lami, Vincent; Berger, Felix J. Matter, Vol. 4, Issue 4 https://doi.org/10.1016/j.matt.2021.01.019	journal	April 2021
High-Efficiency Perovskite Solar Cells Kim, Jin Young; Lee, Jin-Wook; Jung, Hyun Suk Chemical Reviews, Vol. 120, Issue 15 https://doi.org/10.1021/acs.chemrev.0c00107	journal	July 2020
Halide Perovskites: Is It All about the Interfaces? Schulz, Philip; Cahen, David; Kahn, Antoine Chemical Reviews, Vol. 119, Issue 5 https://doi.org/10.1021/acs.chemrev.8b00558	journal	March 2019
Charge-Carrier Recombination in Halide Perovskites: Focus Review deQuilettes, Dane W.; Frohna, Kyle; Emin, David Chemical Reviews, Vol. 119, Issue 20 https://doi.org/10.1021/acs.chemrev.9b00169	journal	September 2019
Delayed Luminescence in Lead Halide Perovskite Nanocrystals Chirvony, Vladimir S.; González-Carrero, Soranyel; Suárez, Isaac The Journal of Physical Chemistry C, Vol. 121, Issue 24 https://doi.org/10.1021/acs.jpcc.7b03771	journal	June 2017
Trap-Limited Dynamics of Excited Carriers and Interpretation of the Photoluminescence Decay Kinetics in Metal Halide Perovskites Chirvony, Vladimir S.; Martínez-Pastor, Juan P. The Journal of Physical Chemistry Letters, Vol. 9, Issue 17 https://doi.org/10.1021/acs.jpclett.8b01241	journal	August 2018
Relating Defect Luminescence and Nonradiative Charge Recombination in MAPbI ₃ Perovskite Films Dobrovolsky, Alexander; Merdasa, Aboma; Li, Jun The Journal of Physical Chemistry Letters, Vol. 11, Issue 5 https://doi.org/10.1021/acs.jpclett.9b03878	journal	February 2020
Thermal Stability of Mixed Cation Metal Halide Perovskites in Air Tan, Wanliang; Bowring, Andrea R.; Meng, Andrew C. ACS Applied Materials & Interfaces, Vol. 10, Issue 6 https://doi.org/10.1021/acsami.7b15263	journal	January 2018
Photoluminescence Lifetimes Exceeding 8 μs and Quantum Yields Exceeding 30% in Hybrid Perovskite Thin Films by Ligand Passivation deQuilettes, Dane W.; Koch, Susanne; Burke, Sven ACS Energy Letters, Vol. 1, Issue 2 https://doi.org/10.1021/acsenergylett.6b00236	journal	July 2016
Photoinduced Emissive Trap States in Lead Halide Perovskite Semiconductors Motti, Silvia G.; Gandini, Marina; Barker, Alex J. ACS Energy Letters, Vol. 1, Issue 4 https://doi.org/10.1021/acsenergylett.6b00355	journal	September 2016
Ultrafast Intraband Spectroscopy of Hot-Carrier Cooling in Lead-Halide Perovskites Hopper, Thomas R.; Gorodetsky, Andrei; Frost, Jarvist M. ACS Energy Letters, Vol. 3, Issue 9 https://doi.org/10.1021/acsenergylett.8b01227	journal	August 2018
Reducing Surface Recombination Velocities at the Electrical Contacts Will Improve Perovskite Photovoltaics Wang, Jian; Fu, Weifei; Jariwala, Sarthak ACS Energy Letters, Vol. 4, Issue 1 https://doi.org/10.1021/acsenergylett.8b02058	journal	December 2018
Perovskite Quantum Dot Lasing in a Gap-Plasmon Nanocavity with Ultralow Threshold Hsieh, Yu-Hung; Hsu, Bo-Wei; Peng, Kang-Ning ACS Nano, Vol. 14, Issue 9 https://doi.org/10.1021/acsnano.0c04224	journal	July 2020
Tracking Photoexcited Carriers in Hybrid Perovskite Semiconductors: Trap-Dominated Spatial Heterogeneity and Diffusion deQuilettes, Dane W.; Jariwala, Sarthak; Burke, Sven ACS Nano, Vol. 11, Issue 11 https://doi.org/10.1021/acsnano.7b06242	journal	September 2017
Electroabsorption Spectroscopy Measurements of the Exciton Binding Energy, Electron–Hole Reduced Effective Mass, and Band Gap in the Perovskite CH ₃ NH ₃ PbI ₃ Ziffer, Mark E.; Mohammed, Joseph C.; Ginger, David S. ACS Photonics, Vol. 3, Issue 6 https://doi.org/10.1021/acsphotonics.6b00139	journal	April 2016
Nonlinear Carrier Interactions in Lead Halide Perovskites and the Role of Defects Srimath Kandada, Ajay Ram; Neutzner, Stefanie; D’Innocenzo, Valerio Journal of the American Chemical Society, Vol. 138, Issue 41 https://doi.org/10.1021/jacs.6b06463	journal	October 2016
Thermally Activated Exciton Dissociation and Recombination Control the Carrier Dynamics in Organometal Halide Perovskite Savenije, Tom J.; Ponseca, Carlito S.; Kunneman, Lucas The Journal of Physical Chemistry Letters, Vol. 5, Issue 13 https://doi.org/10.1021/jz500858a	journal	June 2014
Low-temperature solution-processed wavelength-tunable perovskites for lasing Xing, Guichuan; Mathews, Nripan; Lim, Swee Sien Nature Materials, Vol. 13, Issue 5 https://doi.org/10.1038/nmat3911	journal	March 2014
Bright light-emitting diodes based on organometal halide perovskite Tan, Zhi-Kuang; Moghaddam, Reza Saberi; Lai, May Ling Nature Nanotechnology, Vol. 9, Issue 9 https://doi.org/10.1038/nnano.2014.149	journal	August 2014
Perovskite photonic sources Sutherland, Brandon R.; Sargent, Edward H. Nature Photonics, Vol. 10, Issue 5 https://doi.org/10.1038/nphoton.2016.62	journal	April 2016
In-situ observation of trapped carriers in organic metal halide perovskite films with ultra-fast temporal and ultra-high energetic resolutions Kobbekaduwa, Kanishka; Shrestha, Shreetu; Adhikari, Pan Nature Communications, Vol. 12, Issue 1 https://doi.org/10.1038/s41467-021-21946-2	journal	March 2021
Visualization and suppression of interfacial recombination for high-efficiency large-area pin perovskite solar cells Stolterfoht, Martin; Wolff, Christian M.; Márquez, José A. Nature Energy, Vol. 3, Issue 10 https://doi.org/10.1038/s41560-018-0219-8	journal	July 2018
Present status and future prospects of perovskite photovoltaics Snaith, Henry J. Nature Materials, Vol. 17, Issue 5 https://doi.org/10.1038/s41563-018-0071-z	journal	April 2018
The origin of high efficiency in low-temperature solution-processable bilayer organometal halide hybrid solar cells Sun, Shuangyong; Salim, Teddy; Mathews, Nripan Energy Environ. Sci., Vol. 7, Issue 1 https://doi.org/10.1039/C3EE43161D	journal	January 2014
Temperature-dependent excitonic photoluminescence of hybrid organometal halide perovskite films Wu, Kewei; Bera, Ashok; Ma, Chun Phys. Chem. Chem. Phys., Vol. 16, Issue 41 https://doi.org/10.1039/C4CP03573A	journal	January 2014
Intrinsic femtosecond charge generation dynamics in single crystal CH ₃ NH ₃ PbI ₃ Valverde-Chávez, David A.; Ponseca, Carlito S.; Stoumpos, Constantinos C. Energy & Environmental Science, Vol. 8, Issue 12 https://doi.org/10.1039/C5EE02503F	journal	January 2015
When defects become ‘dynamic’: halide perovskites: a new window on materials? Rakita, Yevgeny; Lubomirsky, Igor; Cahen, David Materials Horizons, Vol. 6, Issue 7 https://doi.org/10.1039/C9MH00606K	journal	January 2019
Double peak emission in lead halide perovskites by self-absorption Schötz, Konstantin; Askar, Abdelrahman M.; Peng, Wei Journal of Materials Chemistry C, Vol. 8, Issue 7 https://doi.org/10.1039/C9TC06251C	journal	January 2020
Carrier lifetimes in ion‐damaged GaAs Johnson, M. B.; McGill, T. C.; Paulter, N. G. Applied Physics Letters, Vol. 54, Issue 24 https://doi.org/10.1063/1.101096	journal	June 1989
Picosecond time‐resolved photoluminescence using picosecond excitation correlation spectroscopy Johnson, M. B.; McGill, T. C.; Hunter, A. T. Journal of Applied Physics, Vol. 63, Issue 6 https://doi.org/10.1063/1.341111	journal	March 1988
Excitation correlation photoluminescence in the presence of Shockley-Read-Hall recombination Borgwardt, M.; Sippel, P.; Eichberger, R. Journal of Applied Physics, Vol. 117, Issue 21 https://doi.org/10.1063/1.4921704	journal	June 2015
Temperature-dependent studies of exciton binding energy and phase-transition suppression in (Cs,FA,MA)Pb(I,Br) ₃ perovskites Ruf, Fabian; Aygüler, Meltem F.; Giesbrecht, Nadja APL Materials, Vol. 7, Issue 3 https://doi.org/10.1063/1.5083792	journal	March 2019
Time resolved luminescence of photoexcited p ‐type gallium arsenide by population mixing Rosen, D.; Doukas, A. G.; Budansky, Y. Applied Physics Letters, Vol. 39, Issue 12 https://doi.org/10.1063/1.92617	journal	December 1981
Time‐resolved nonlinear luminescence spectroscopy by picosecond excitation correlation Jo/rgensen, M.; Hvam, J. M. Applied Physics Letters, Vol. 43, Issue 5 https://doi.org/10.1063/1.94388	journal	September 1983
Electron-Hole Recombination in Germanium Hall, R. N. Physical Review, Vol. 87, Issue 2 https://doi.org/10.1103/PhysRev.87.387	journal	July 1952
Statistics of the Recombinations of Holes and Electrons Shockley, W.; Read, W. T. Physical Review, Vol. 87, Issue 5 https://doi.org/10.1103/PhysRev.87.835	journal	September 1952
Recombination Kinetics in Organic-Inorganic Perovskites: Excitons, Free Charge, and Subgap States Stranks, Samuel D.; Burlakov, Victor M.; Leijtens, Tomas Physical Review Applied, Vol. 2, Issue 3 https://doi.org/10.1103/PhysRevApplied.2.034007	journal	September 2014
Application of femtosecond-excitation correlation to the study of emission dynamics in hexagonal GaN Pau, S.; Kuhl, J.; Khan, M. A. Physical Review B, Vol. 58, Issue 19 https://doi.org/10.1103/PhysRevB.58.12916	journal	November 1998
Femtosecond excitation correlation spectroscopy of single-walled carbon nanotubes: Analysis based on nonradiative multiexciton recombination processes Miyauchi, Yuhei; Matsuda, Kazunari; Kanemitsu, Yoshihiko Physical Review B, Vol. 80, Issue 23 https://doi.org/10.1103/PhysRevB.80.235433	journal	December 2009
Exciton Localization of Single-Walled Carbon Nanotubes Revealed by Femtosecond Excitation Correlation Spectroscopy Hirori, Hideki; Matsuda, Kazunari; Miyauchi, Yuhei Physical Review Letters, Vol. 97, Issue 25 https://doi.org/10.1103/PhysRevLett.97.257401	journal	December 2006
Photoelectronic Responses in Solution-Processed Perovskite CH$_{\bf 3}$ NH$_{\bf 3}$PbI $_{\bf 3}$ Solar Cells Studied by Photoluminescence and Photoabsorption Spectroscopy Yamada, Yasuhiro; Nakamura, Toru; Endo, Masaru IEEE Journal of Photovoltaics, Vol. 5, Issue 1 https://doi.org/10.1109/JPHOTOV.2014.2364115	journal	January 2015
Efficient Hybrid Solar Cells Based on Meso-Superstructured Organometal Halide Perovskites Lee, M. M.; Teuscher, J.; Miyasaka, T. Science, Vol. 338, Issue 6107, p. 643-647 https://doi.org/10.1126/science.1228604	journal	October 2012
Low trap-state density and long carrier diffusion in organolead trihalide perovskite single crystals Shi, D.; Adinolfi, V.; Comin, R. Science, Vol. 347, Issue 6221 https://doi.org/10.1126/science.aaa2725	journal	January 2015
Impact of microstructure on local carrier lifetime in perovskite solar cells de Quilettes, D. W.; Vorpahl, S. M.; Stranks, S. D. Science, Vol. 348, Issue 6235 https://doi.org/10.1126/science.aaa5333	journal	April 2015
Promises and challenges of perovskite solar cells Correa-Baena, Juan-Pablo; Saliba, Michael; Buonassisi, Tonio Science, Vol. 358, Issue 6364 https://doi.org/10.1126/science.aam6323	journal	November 2017

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Title: Nonlinear photocarrier dynamics and the role of shallow traps in mixed-halide mixed-cation hybrid perovskites

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