The Transient Covalent Bond in Abiotic Nonequilibrium Systems

Kariyawasam, Lasith S.; Hossain, Mohammad Mosharraf; Hartley, C. Scott

doi:10.1002/anie.202014678

Title: The Transient Covalent Bond in Abiotic Nonequilibrium Systems

Journal Article · 01 December 2020 · Angewandte Chemie (International Edition)

DOI: https://doi.org/10.1002/anie.202014678 · OSTI ID:1806300

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Miami Univ., Oxford, OH (United States); Miami University
Miami Univ., Oxford, OH (United States)

Biochemical systems accomplish many critical functions with by operating out-of-equilibrium using the energy of chemical fuels. The formation of a transient covalent bond is a simple but very effective tool in designing analogous reaction networks. This Minireview focuses on the fuel chemistries that have been used to generate transient bonds in recent demonstrations of abiotic nonequilibrium systems (i.e., systems that do not make use of biological components). Here, fuel reactions are divided into two fundamental classifications depending on whether the fuel contributes structural elements to the activated state, a distinction that dictates how they can be used. Reported systems are further categorized by overall fuel reaction (e.g., hydrolysis of alkylating agents, carbodiimide hydration) and illustrate how similar chemistry can be used to effect a wide range of nonequilibrium behavior, ranging from self-assembly to the operation of molecular machines.

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Research Organization:: Miami Univ., Oxford, OH (United States)

Sponsoring Organization:: USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0018645

OSTI ID:: 1806300

Journal Information:: Angewandte Chemie (International Edition), Journal Name: Angewandte Chemie (International Edition) Journal Issue: 23 Vol. 60; ISSN 1433-7851

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
chemical fuels
dissipative assembly
molecular machines
self-assembly
transient bonding

Title: The Transient Covalent Bond in Abiotic Nonequilibrium Systems

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