The Transient Covalent Bond in Abiotic Nonequilibrium Systems

Kariyawasam, Lasith S.; Hossain, Mohammad Mosharraf; Hartley, C. Scott

doi:10.1002/anie.202014678

Title: The Transient Covalent Bond in Abiotic Nonequilibrium Systems

Journal Article · 02 December 2020 · Angewandte Chemie (International Edition)

DOI: https://doi.org/10.1002/anie.202014678 · OSTI ID:1806300

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Miami Univ., Oxford, OH (United States)

Abstract Biochemical systems accomplish many critical functions with by operating out‐of‐equilibrium using the energy of chemical fuels. The formation of a transient covalent bond is a simple but very effective tool in designing analogous reaction networks. This Minireview focuses on the fuel chemistries that have been used to generate transient bonds in recent demonstrations of abiotic nonequilibrium systems (i.e., systems that do not make use of biological components). Fuel reactions are divided into two fundamental classifications depending on whether the fuel contributes structural elements to the activated state, a distinction that dictates how they can be used. Reported systems are further categorized by overall fuel reaction (e.g., hydrolysis of alkylating agents, carbodiimide hydration) and illustrate how similar chemistry can be used to effect a wide range of nonequilibrium behavior, ranging from self‐assembly to the operation of molecular machines.

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Research Organization:: Miami Univ., Oxford, OH (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE

Grant/Contract Number:: SC0018645

OSTI ID:: 1806300

Alternate ID(s):: OSTI ID: 1784807

Journal Information:: Angewandte Chemie (International Edition), Vol. 60, Issue 23; ISSN 1433-7851

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
dissipative assembly
chemical fuels
transient bonding
molecular machines
self-assembly

Title: The Transient Covalent Bond in Abiotic Nonequilibrium Systems

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