Temperature and processing effects on lithium ion conductivity of solution‐deposited lithium zirconium phosphate (LiZr 2 P 3 O 12 ) thin films

Brummel, Ian A.; Drury, Daniel E.; Kitahara, Andrew R.; El Gabaly, Farid; Ihlefeld, Jon F.

doi:10.1111/jace.17483

Title: Temperature and processing effects on lithium ion conductivity of solution‐deposited lithium zirconium phosphate (LiZr ₂ P ₃ O ₁₂ ) thin films

Abstract

Abstract Lithium zirconium phosphate (LiZr ₂ P ₃ O ₁₂ ) thin films have been prepared on platinized silicon substrates via a chemical solution deposition approach with processing temperatures between 700°C and 775°C. Films that were subject to a single high‐temperature anneal were found to crystallize at temperatures above 725°C. Crystallization was observed in films annealed after each deposited layer at 700°C and above. In both cases, grain size was found to increase with annealing temperature. Ion conductivity was found to increase with annealing temperature in singly annealed films. In per‐layer annealed films ion conductivity was found to initially increase then decrease with increasing annealing temperature. A maximum ion conductivity of 1.6 × 10 ⁻⁶ S/cm was observed for the singly annealed 775°C condition, while a maximum ion conductivity of 5.8 × 10 ⁻⁷ S/cm was observed for the 725°C per‐layer annealed condition. These results are consistent with an increasing influence of cross‐plane, internal interface resistance and vapor phase carrier loss in the per‐layer annealed samples. This work demonstrates that post‐deposition processing methods can strongly affect the ion conducting properties of LiZr ₂ P ₃ O ₁₂ thin films.

Authors:

^[1]; Drury, Daniel E. ^[2]; Kitahara, Andrew R. ^[2]; El Gabaly, Farid ^[3];

^[4]

Department of Materials Science and Engineering University of Virginia Charlottesville VA USA
Sandia National Laboratories Albuquerque NM USA
Sandia National Laboratories Livermore CA USA
Department of Materials Science and Engineering University of Virginia Charlottesville VA USA, Sandia National Laboratories Albuquerque NM USA, Charles L. Brown Department of Electrical and Computer Engineering University of Virginia Charlottesville VA USA

Publication Date:: Mon Sep 28 00:00:00 EDT 2020

Sponsoring Org.:: USDOE

OSTI Identifier:: 1805093

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Journal of the American Ceramic Society

Additional Journal Information:: Journal Name: Journal of the American Ceramic Society Journal Volume: 104 Journal Issue: 2; Journal ID: ISSN 0002-7820

Publisher:: Wiley-Blackwell

Country of Publication:: United States

Language:: English

Citation Formats


                    Brummel, Ian A., Drury, Daniel E., Kitahara, Andrew R., El Gabaly, Farid, and Ihlefeld, Jon F. Temperature and processing effects on lithium ion conductivity of solution‐deposited lithium zirconium phosphate (LiZr 2 P 3 O 12 ) thin films.  United States: N. p., 2020. 
Web.  doi:10.1111/jace.17483.

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                    Brummel, Ian A., Drury, Daniel E., Kitahara, Andrew R., El Gabaly, Farid, & Ihlefeld, Jon F. Temperature and processing effects on lithium ion conductivity of solution‐deposited lithium zirconium phosphate (LiZr 2 P 3 O 12 ) thin films.  United States.  https://doi.org/10.1111/jace.17483

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                    Brummel, Ian A., Drury, Daniel E., Kitahara, Andrew R., El Gabaly, Farid, and Ihlefeld, Jon F. Mon .  
"Temperature and processing effects on lithium ion conductivity of solution‐deposited lithium zirconium phosphate (LiZr 2 P 3 O 12 ) thin films".  United States.  https://doi.org/10.1111/jace.17483.

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@article{osti_1805093,

  title        = {Temperature and processing effects on lithium ion conductivity of solution‐deposited lithium zirconium phosphate (LiZr 2 P 3 O 12 ) thin films},

  author       = {Brummel, Ian A. and Drury, Daniel E. and Kitahara, Andrew R. and El Gabaly, Farid and Ihlefeld, Jon F.},

  abstractNote = {Abstract Lithium zirconium phosphate (LiZr 2 P 3 O 12 ) thin films have been prepared on platinized silicon substrates via a chemical solution deposition approach with processing temperatures between 700°C and 775°C. Films that were subject to a single high‐temperature anneal were found to crystallize at temperatures above 725°C. Crystallization was observed in films annealed after each deposited layer at 700°C and above. In both cases, grain size was found to increase with annealing temperature. Ion conductivity was found to increase with annealing temperature in singly annealed films. In per‐layer annealed films ion conductivity was found to initially increase then decrease with increasing annealing temperature. A maximum ion conductivity of 1.6 × 10 −6  S/cm was observed for the singly annealed 775°C condition, while a maximum ion conductivity of 5.8 × 10 −7  S/cm was observed for the 725°C per‐layer annealed condition. These results are consistent with an increasing influence of cross‐plane, internal interface resistance and vapor phase carrier loss in the per‐layer annealed samples. This work demonstrates that post‐deposition processing methods can strongly affect the ion conducting properties of LiZr 2 P 3 O 12 thin films.},

  doi          = {10.1111/jace.17483},

  journal      = {Journal of the American Ceramic Society},

  number       = 2,

  volume       = 104,

  place        = {United States},

  year         = {Mon Sep 28 00:00:00 EDT 2020},

  month        = {Mon Sep 28 00:00:00 EDT 2020}

}

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Title: Temperature and processing effects on lithium ion conductivity of solution‐deposited lithium zirconium phosphate (LiZr 2 P 3 O 12 ) thin films

Abstract

Citation Formats

Texture Development in Modified Lead Titanate Thin Films Obtained by Chemical Solution Deposition on Silicon-Based Substrates journal, September 2003

Characterization of Sputter-Deposited LiZr 2 (PO 4 ) 3 Thin Film Solid Electrolyte journal, January 2015

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Control of the morphology of CSD-prepared (Ba,Sr)TiO3 thin films journal, June 1999

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Relations between sublattice disorder, phase transitions and conductivity in NASICON journal, December 1983

Lithium ion conductors in the system AB(IV)2(PO4)3 (B = Ti, Zr and Hf) journal, January 1986

Impedance Spectroscopy book, January 2005

NASICON-type La3+substituted LiZr2(PO4)3 with improved ionic conductivity as solid electrolyte journal, May 2018

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Chemically Homogeneous Complex Oxide Thin Films Via Improved Substrate Metallization journal, March 2012

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Title: Temperature and processing effects on lithium ion conductivity of solution‐deposited lithium zirconium phosphate (LiZr ₂ P ₃ O ₁₂ ) thin films

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Impedance Spectroscopy
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Stabilization of the tetragonal structure in zirconia microcrystals
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Room temperature triclinic modification of NASICON-type LiZr2(PO4)3
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Relationship between Activation Energy and Bottleneck Size for Li ⁺ Ion Conduction in NASICON Materials of Composition LiMM‘(PO ₄ ) ₃ ; M, M‘ = Ge, Ti, Sn, Hf
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Mechanical characterization of LiPON films using nanoindentation
journal, October 2011

Preparation and Processing Temperature Effects on Ion Conductivity in Solution Derived Sodium Zirconium Phosphate (NaZr ₂ P ₃ O ₁₂ ) Thin Films
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High ionic conductivity in lithium lanthanum titanate
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Electroceramics: Characterization by Impedance Spectroscopy
journal, March 1990

Enhanced lithium-ion conductivity in a LiZr 2 (PO 4 ) 3 solid electrolyte by Al doping
journal, August 2017

Y-Doped NASICON-type LiZr ₂ (PO ₄ ) ₃ Solid Electrolytes for Lithium-Metal Batteries
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Influence of sputtering conditions on ionic conductivity of LiPON thin films
journal, January 2006

Grain-size effect on structure and phase transformations for barium titanate
journal, August 1996

NIH Image to ImageJ: 25 years of image analysis
journal, June 2012

Dimorphism, phase transitions, and transport properties in LiZr2(PO4)3
journal, November 1989

Anomalies in Li+ ion dynamics observed by impedance spectroscopy and 7Li NMR in the perovskite fast ion conductor (Li3xLa2/3-x□1/3-2x)TiO3
journal, February 2003

High Temperature Vaporization Behavior of Oxides. I. Alkali Metal Binary Oxides
journal, January 1984

Grain size effect on the phase transformation temperature of nanostructured CuFe2O4
journal, January 2011

Texture Development, Microstructure Evolution, and Crystallization of Chemically Derived PZT Thin Films
journal, January 1998

Sol–gel processing of NASICON thin film using aqueous complex precursor
journal, July 2000

Ionic conductivity of the NaZr2(PO4)3 single crystals
journal, September 1997

Grain-boundary ionic conductivity in nominal Li1+x M x Ti2?x (PO4)3 (M=Sc3+ or Y3+) and their zirconium analogues
journal, January 1992