Highly efficient separation membrane based on cellulose acetate/chitosan fibrous composite substrate with activated carbon functional adsorption layer

Zhao, Xiaoyan; Wu, Qian; Huang, Chen; Wei, Huidan; Wang, Ruichen; Wang, Chenyi

doi:10.1002/jctb.6580

Title: Highly efficient separation membrane based on cellulose acetate/chitosan fibrous composite substrate with activated carbon functional adsorption layer

Journal Article · 16 October 2020 · Journal of Chemical Technology and Biotechnology

DOI: https://doi.org/10.1002/jctb.6580 · OSTI ID:1804772

^[1]; Wu, Qian ^[1]; Huang, Chen ^[1]; Wei, Huidan ^[1]; Wang, Ruichen ^[1]; Wang, Chenyi ^[2]

School of Petrochemical Engineering Changzhou University Changzhou China
School of Materials Science and Engineering Changzhou University Changzhou China

Abstract BACKGROUND For improving the permeability and selectivity of adsorption separation membranes, membrane materials, structural morphology and separation technology must continue to be investigated. Development of a membrane that is environmentally friendly, cost‐effective and with high filter precision is an important direction in current research. RESULTS The air pressure spraying method was used to prepare an activated carbon (AC)–cellulose acetate/chitosan (CA/CS) composite membrane. The CA/CS fiber composite membrane was prepared as substrate layer, and AC was loaded on the surface of the CA/CS composite membrane as a functional adsorption layer. When the spraying pressure was 0.01 MPa and the mass ratio of AC/CS was 2:1, a composite membrane with even and compact morphology could be obtained. Both the compact AC functional layer and complete CA/CS substrate layer endowed the AC–CA/CS composite membrane with an excellent water filtration property. At low feeding pressure, the permeate flux and rejection rate of bisphenol A (BPA) could reach 9.27 × 10 ³ L m ⁻² h ⁻¹ and 98.31%, respectively. Meanwhile, the adsorption capacities of the membrane were investigated. It tended to equilibrate quickly in 2 min for dyes and BPA. The equilibrium adsorption capacities of the membrane for acid blue, acid yellow and BPA were 175.80, 164.0815 and 79.58 mg g ⁻¹ , respectively. The adsorption process conformed to pseudo‐second‐order kinetics and the Langmuir monolayer adsorption model. CONCLUSIONS This work could provide a practical and effective feasibility for membrane separation technology. © 2020 Society of Chemical Industry (SCI)

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Sponsoring Organization:: USDOE

OSTI ID:: 1804772

Journal Information:: Journal of Chemical Technology and Biotechnology, Journal Name: Journal of Chemical Technology and Biotechnology Journal Issue: 3 Vol. 96; ISSN 0268-2575

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: United Kingdom

Language:: English

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