Growth of CuFeO2 single crystals by the optical floating-zone technique

Wolff, Nora; Schwaigert, Tobias; Siche, Dietmar; Schlom, Darrell G.; Klimm, Detlef

doi:10.1016/j.jcrysgro.2019.125426

Title: Growth of CuFeO₂ single crystals by the optical floating-zone technique

Journal Article · 17 December 2019 · Journal of Crystal Growth

DOI: https://doi.org/10.1016/j.jcrysgro.2019.125426 · OSTI ID:1801568

Wolff, Nora ^[1]; Schwaigert, Tobias ^[2]; Siche, Dietmar ^[2]; Schlom, Darrell G. ^[3];

^[2]

Leibniz Inst. for Crystal Growth (IKZ), Berlin (Germany); Helmholtz-Zentrum Berlin fur Materialien und Energie (Germany); OSTI
Leibniz Inst. for Crystal Growth (IKZ), Berlin (Germany)
Cornell Univ., Ithaca, NY (United States)

CuFeO₂ single crystals up to 50 mm in length and up to 10 mm in diameter were grown by the optical floating-zone method. Stoichiometric polycrystalline rods with a diameter of 6–12 mm were used as feed materials to produce crystals of sufficient size to be used as substrates for the growth of thin films of delafossites. For stable growth along the c-axis, low growth rates of 0.4 mm/h are necessary. Due to the incongruent melting behavior of CuFeO₂, a stable melt zone requires adjustment of the lamp power during growth. The melting of CuFeO₂ is not simply incongruent because the thermodynamic equilibrium includes more than two solid phases and the melt; the gas phase is also involved. Finaly, the crystals were characterized by X-ray diffraction and X-ray fluorescence measurements.

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Research Organization:: Cornell Univ., Ithaca, NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC); USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division

Grant/Contract Number:: SC0002334

OSTI ID:: 1801568

Journal Information:: Journal of Crystal Growth, Journal Name: Journal of Crystal Growth Journal Issue: C Vol. 532; ISSN 0022-0248

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Related Subjects

36 MATERIALS SCIENCE
crystallography
floating zone technique
materials science
oxides
phase equilibria
physics
substrates

Title: Growth of CuFeO2 single crystals by the optical floating-zone technique

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References (39)

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Title: Growth of CuFeO₂ single crystals by the optical floating-zone technique